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The photoluminescence of Eu^3 -doped yttrium oxide chloride embedded in nanoporous glass has been observed.In comparison with those in the powder phosphor,the emission lines of Eu^3 ions becom much broader and lueshift was observed in the lines due to ^5D0→^7F2 transitions and the Eu-O charge transfer excitation band.The ratio intensities of the ^5D0→^7F1 transitions to the ^5D0→^7F2 transitions of Eu^3 ion become higher and change at different excitation excitation wavelengths,such as 393nm and 254nm.The two excitation wavelengths belong to the 4f→4f transition of the Eu^3 ion and the Eu-O charge transfer,respectively,This material may be developed into a new luminescent glass. 相似文献
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Photoluminescent properties of a metal-organic complex, di(8-hydroxyquinolato) zinc, impregnated in nanoporous glass were investigated. In comparison with those in the normal organic fluorescent material,the emission band of the impregnated organic phosphor became wider. Blueshift (14 nm) was observed due to π* → n emission transition. The excitation band of the embedded organic phosphor had a larger blueshift and was divided into several sub-bands. The intensity in the short wavelength end of the embedded organic fluorescent material became much stronger. 相似文献
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Photoluminescent properties of a metal-organic complex, di(8-hydroxyquinolato) zinc, impregnated in nanoporous glass were investigated. In comparison with those in the normal organic fluorescent material, the emission band of the impregnated organic phosphor became wider. Blueshift (14 nm) was observed due to π*→n emission transition. The excitation band of the embedded organic phosphor had a larger blueshift and was divided into several sub-bands. The intensity in the short wavelength end of the embedded organic fluorescent material became much stronger. 相似文献
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