拉盖尔高斯径向偏振光高数值孔径聚焦特性

光波在高数值孔径聚焦下焦点区域光强分布呈现出的特殊性质已经被应用到光学显微成像、微粒控制、光存储等领域中.本文基于矢量Deby衍射理论研究了TM01模拉盖尔高斯径向偏振光经高数值孔径聚焦下焦点区域光强分布.通过调节入瞳半径与光束束腰之比,发现拉盖尔高斯径向偏振光光斑由明亮尺寸小光斑变化成环形中空光斑,并且通过光瞳滤波器...     

柠檬酸配合法制备CuMnCeOx催化剂及常温催化氧化性能研究

摘要：常温催化氧化是消除室内HCHO污染最可行的方法之一,其中以过渡金属氧化物为代表的催化剂因性能优异、成本低廉而备受广泛关注。采用柠檬酸络合法和水热法制备了一系列CuMnCeOx催化剂,研究考察制备方法及载体对催化剂氧化性能的影响,并利用XRD、SEM、BET、H2-TPR、XPS和IR等对催化剂进行微观表征与分析。研究发现,制备方法及载体类型对催化剂的表面结构形貌、氧化性能产生显著影响,其中采用柠檬酸络合法所制的CuMnCeOx-C催化剂性能最佳,48h的HCHO去除率达98.6%,完全满足GB50325-2001标准要求,其介孔结构,晶体粒径及所形成的铈基铜锰固溶体均利于形成大量氧空位及催化氧化反应,且展示出良好的抗水蒸气和稳定性能,其在常温催化氧化VOCs方面具有重要应用前景。     

匀浆提取-超高效液相色谱-串联质谱法测定烟草中亚硝胺含量

提出了超高效液相色谱-串联质谱法测定烟草中N-亚硝基降烟碱(NNN)、N-亚硝基新烟草碱(NAT)、N-亚硝基假木贼碱(NAB)和4-甲基亚硝基吡啶基丁酮(NNK)等4种亚硝胺含量的方法。烟草样品经0.1mol.L-1乙酸铵溶液匀浆提取,离心分离取上清液过Waters AcquityUPLC BEH C18色谱柱(2.1mm×100mm,1.7μm)分离,以乙腈和0.01mol.L-1乙酸铵溶液按不同体积混合作流动相梯度洗脱。串联质谱测定中采用电喷雾离子源正离子模式和多反应监测模式检测,同位素内标法定量。NNK、NNN、NAB和NAT的检出限(3s)分别为0.06,0.17,0.15,0.053μg.L-1。方法的加标回收率在92.1%～104%之间;日内和日间相对标准偏差(n=7)分别为2.7%～3.3%和3.5%～4.2%。     

基于双模接口的测试系统设计

为了对飞行设备进行各种性能参数的测试,同时避免因环境因素而带来的数据传输不稳定的问题,使用双模接口(以太网接口与USB接口)实现上位机与测试系统的通信,通过对采样电路进行优化产生多路高精度信号并实时监测接收返回的群信号。经实验证明,系统完全可以完成各种环境中的功能测试,并提高了系统测试精度与传输数据的可靠性。     

Bottom-up design and assembly with superatomic building blocks

Constructing specific structures from the bottom up with artificial units is an important interdisciplinary topic involving physics, chemistry, materials, and so on. In this work, we theoretically demonstrated the feasibility of using superatoms as building blocks to assemble a complex at atomic-level precision. By using a series of actinide-based endohedral metallofullerene (EMF) superatoms that can form one, two, three and four chemical bonds, a planar complex with intra- and inter-molecular interactions was assembled on the Au(111) surface. This complex is composed of two parts, containing ten and eight superatoms, respectively. The electronic structure analysis shows that the electron density inside each part is connected and the closed-shell electronic arrangement system is designed. There is also an obvious van der Waals boundary by physical adsorption between the two parts, and a stable complex is formed. Since this complex is realized by the first-principles calculations of quantum mechanics, our results help not only achieve atomic-level precision construction with artificial superatomic units but also maintain atomic-level functional properties.     

内壳层跃迁--实现超短波长激光的途径

内壳层跃迁机制是实现超短波长激光的一种很有潜力的方案，随着近年来超短超强激光技术和X射线激光实验方法的进展，实现内壳层跃迁机制的超短波长硬X射线激光不再是遥不可及的梦想，文章详细介绍了内壳层跃迁机制X射线激光的原理，并讨论了开展内壳层跃迁机制X射线激光实验的一些实际相关问题。     

非线性抛物问题的二重网格混合元算法

针对一类非线性抛物方程的混合元形式,本文提出了二重网格算法.该算法是在网格大小为H的粗网格上求解—个非线性系统,再在网格大小为h的细网格上进行两次线性计算.算法第二步和第三步的误差分别为O(△_t~2 h~(k 1) H~(2K 2)),O(△_t~2 h~(k 1) h~(-d/2)H~(4k 4)),其中k为逼近空间的多项式的次数,d为空间维数.该估计对H的选取起了很大的作用.对于粗网格上的非线性计算,本文给出了L~p(2≤p<∞)模误差估计.     

线聚焦——实现实用X射线激光饱和输出的关键技术

自从X射线激光问世以来，在产生机制从准稳态到瞬态，抽运方式从横向抽运到纵向抽运，再到全新的掠入射抽运方式的过程中，大增益的饱和输出一直是研究的根本目标．线聚焦问题是实现辐照均匀化进而达到饱和输出的关键．伴随着抽运方式的发展，先后出现了一系列对应的线聚焦器件，取得了不错的线聚焦效果．文章对X射线激光发展历史上出现的主要线聚焦器件进行了总结。     

超导环电流的研究

以修正的含时金兹堡-朗道理论去研究超导环的超流特性；计算了涡旋运动方程，理论上得到超导环电流是超流量子的整数倍，并且具有多涡旋跳跃；从理论上得到超导环的磁场是量子化的.一定条件下，超流的符号可以发生反转，并且理论上得到了它的表达式.认为超导环是具有对势的对称. 关键词： 超导环 电流 超导电性     

ION FLUX BEHAVIOR IN HIGH DENSITY PLASMAS

The available electron cyclotron resonance plasma sources have been simulated in two-dimensional configuration space (Z, R) and three-dimensional velocity space (V_z, V_r, V_θ). Using a hybrid model, we treat ions as particles and electrons as fluid. The simulation is specified for plasma parameters of the available apparatus and is focused on the ion flux distributions. For a set of given operating conditions, the spatial distributions of electron temperature, plasma potential, plasma density, ionization rate and the contours map of distributions of particles in different volume cells in velocity space are obtained; statistics on ions that hit the bottom surface are also reported. The distributions of ion flux vectors on different cross-section planes in the plasma are given, and the phenomena of large radial diffusione of ions across magnetic force lines are also demonstrated. Finally, the influences of microwave power and neutral gas pressure on the distributions of ion flux vectors on ZR-plane, ion flux radial distributions and ion currents to all walls have been studied.