4-乙烯基吡啶-镍(钴)及丙烯酰胺-镍(钴)的制备、结构、聚合及聚合物的催化性能

制备了4-乙烯基吡啶-镍(钴)和丙烯酰胺-镍(钴)络合物并研究了它们的结构。在自由基引发剂的作用下,4-乙烯基吡啶-镍可进行溶液聚合,也可与苯乙烯共聚合,测定了单体的竞聚率。所得的聚(4-乙烯基吡啶-镍)及聚(4-乙烯基吡啶-钴)以NaBH_4还原后可作为一些有机化合物的加氢催化剂。由IR及XPS分析说明在丙烯酰胺-镍络合物中,与镍离子发生了络合作用的是羧基上的氧原子。     

Influences of finite gain bandwidth on pulse propagation in parabolic fiber amplifiers with distributed gain profiles

The evolutions of the pulses propagating in decreasing and increasing gain distributed fiber amplifiers with finite gain bandwidths are investigated by simulations with the nonlinear Schr¨odinger equation. The results show that the parabolic pulse propagations in both the decreasing and the increasing gain amplifiers are restricted by the finite gain bandwidth. For a given input pulse, by choosing a small initial gain coefficient and gain variation rate, the whole gain for the pulse amplification limited by the gain bandwidth may be higher, which is helpful for the enhancement of the output linearly chirped pulse energy. Compared to the decreasing gain distributed fiber amplifier, the increasing gain distributed amplifier may be more conducive to suppress the pulse spectral broadening and increase the critical amplifier length for achieving a larger output linearly chirped pulse energy.     

Influences of finite gain bandwidth on pulse propagating in parabolic fiber amplifiers with distributed gain profiles

The evolutions of the pulses propagating in decreasing and increasing gain distributed fiber amplifiers with finite gain bandwidths are investigated by simulating with the nonlinear Schrödinger equation. The results show that the parabolic pulse propagations in both the decreasing and the increasing gain amplifiers are restricted by the finite gain bandwidth. For a given input pulse, by choosing small initial gain coefficient and gain variation rate, the whole gain for the pulse amplification limited by the gain bandwidth may be higher, which is helpful to the enhancement of the output linearly chirped pulse energy. Compared to the decreasing gain distributed fiber amplifier, the increasing gain distributed amplifier may be more conducive to suppress the pulse spectral broadening and increase the critical amplifier length for achieving a larger output linearly chirped pulse energy.     

312 MHz,compact all-normal-dispersion Yb:fiber ring laser with an integrated WDM-ISO

A compact and stable all-normal-dispersion mode-locked ring fiber laser with the repetition rate of 312 MHz is obtained with a wavelength-division multiplexing isolator. The compressed pulse is nearly transform-limited and the pulse width is 118 fs. It exhibits an optical efficiency of 50% and the maximum output power is about 205 m W with a 410 m W pump.     

耦合广义非线性薛定谔方程的相互作用表象龙格库塔算法及其误差分析

本文通过表象变换, 将耦合广义非线性薛定谔方程 (C-GNLSE) 变换成相互作用表象中的向量方程, 再利用向量形式的4阶龙格-库塔迭代格式, 建立了一种在频域内求解C-GNLSE的同步更新迭代算法. 通过将该向量形式的相互作用表象中的4阶龙格-库塔 (V-JH-RK4IP) 算法应用于高双折射光子晶体光纤中超连续谱产生的数值模拟, 验证了算法的有效性, 通过与现有其他典型算法的比较, 表明以V-JH-RK4IP算法求解C-GNLSE具有最高的计算精度和计算效率. 关键词： 耦合广义非线性薛定谔方程(C-GNLSE) 相互作用表象 4阶龙格-库塔算法 超连续谱产生     

Supercontinuum generated in all-normal dispersion photonic crystal fibers with picosecond pump pulses

The supercontinuum (SC) generation in all-normal dispersion (ANDi) photonic-crystal fiber (PCF) pumped by high power picosecond pulses are investigated in this paper. Our results show that an octave SC may be achieved by pumping the ANDi PCF with picosecond pump pulses. However, the PCF length required may have to be lengthened to several tens of centimeters, which is much longer than that with femtosecond pump pulses. The relatively long PCF gives rise to much higher Raman gain and stronger Raman frequency shift compared to those with femtosecond pump pulses, which in turn not only cause a distorted temporal waveform and an un-flattened spectrum, but also severely degrade the coherence of the generated SC.     

4—乙烯基吡啶—镍（钴）及丙烯酰胺—镍（钴）的制备、结构、聚合及聚合物

制备了4－乙烯基吡啶－镍（钴）和丙烯酰胺－镍（钴）络合物并研究了它们的结构。在自由基引发剂的作用下，4－乙烯基吡啶－镍可进行溶液聚合，也可与苯乙烯共聚合，测定了单体的竞聚率。所得的聚（4－乙烯基吡啶－镍）及聚（4－乙烯基吡啶－钴）以NαBH4还原后可作为一些有机化合物的加氢催化剂。由IR及XPS分析说明在丙烯酰胺－镍 合物中，与镍离子发生了络合作用的是碳基上的氧原子。