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In pH 1.0 acidic medium, double-charged triaminotriphenylmethane dyes such as methyl green (MEG) and iodine green (IG) react with potassium ferrocyanide to form 2 : 1 ion-association complexes by virtue of electrostatic forces and hydrophobic interaction. It results in the change of absorption and the great enhancement of resonance Rayleigh scattering (RRS) and the appearance of new RRS spectra. Two systems have similar spectral characteristics and their maximum RRS wavelengths are all located at 276 nm and smaller peaks are located at 332 and 457 nm, respectively. The intensity of RRS is directly proportional to the concentration of [Fe(CN)6]^4- in the range of 0.03-5.7 μg·mL^-1 (MeG system) or 0.04-5.9 μg·mL^-1 (IG system). The RRS method has high sensitivity and the detection limit (3σ) for potassium ferrocyanide is 9.3 ng·mL^-1 (MeG system) or 11.2 ng·mL^-1 (IG system). The optimum conditions, influencing factors and effects of foreign substances are investigated. The method also has a good selectivity. A sensitive, rapid and simple RRS method for the determination of potassium ferrocyanide in salinized food and table salt has been developed. 相似文献
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在pH 1左右的酸性介质中,甲基绿(MeG)和碘绿(IG)双电荷三氨基三苯甲烷染料与亚铁氰根阴离子能借助静电引力和疏水作用而形成2:1的离子缔合物,在引起吸收光谱变化的同时,能导致共振瑞利散射(RRS)的显著增强,并出现新的RRS光谱,两体系有相似的RRS光谱特征,最大RRS波长位于276 nm,并在332 nm,457 nm有强度较低的散射峰,K4[Fe(CN)6]分别为0.03~5.7μg•mL-1(MeG体系)和0.04~5.9μg•mL-1(IG体系)范围内,K4[Fe(CN)6]浓度与散射强度(ΔIRRS)成正比。方法具有高灵敏度,对K4[Fe(CN)6]的检出限(3σ)分别为9.3 ng•mL-1和11.2ng•mL-1。本文实验了适宜的反应条件和影响因素,考察了共存物质的影响,表明方法有较好的选择性,可用于盐渍食品和食盐中痕量亚铁氰化钾的测定。 相似文献
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共振瑞利散射法测定盐渍食品中的亚铁氰化钾 总被引:5,自引:0,他引:5
1引言研究发现,在弱酸性介质中,当Fe(Ⅲ)与亚铁氰化钾反应生成普鲁士蓝时,在引起吸收光谱变化的同时,将导致共振瑞利散射(RRS)的显著增强,其最大散射波长在316nm,它不仅是灵敏度高,检出限达4.36μg/L,远远高于分光光度法(检出限为1mg/L),而且有色盐渍食品本身的颜色不产生共振瑞利散射,因此不干扰测定。从而解决了盐渍食品本身颜色对分光光度法测定亚铁氰化钾的困扰。据此提出了一种灵敏度高、选择性好、而且简便快速的RRS法。2实验部分2.1仪器与试剂F-2500型荧光分光光度计(日本岛津公司),狭缝宽度10nm;UV-8500型紫外-可见分光光度计(… 相似文献
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Dynamical investigation and parameter stability region analysis of a flywheel energy storage system in charging mode 下载免费PDF全文
In this paper, the dynamic behavior analysis of the electromechanical coupling characteristics of a flywheel energy storage system (FESS) with a permanent magnet (PM) brushless direct-current (DC) motor (BLDCM) is studied. The Hopf bifurcation theory and nonlinear methods are used to investigate the generation process and mechanism of the coupled dynamic behavior for the average current controlled FESS in the charging mode. First, the universal nonlinear dynamic model of the FESS based on the BLDCM is derived. Then, for a 0.01 kWh/1.6 kW FESS platform in the Key Laboratory of the Smart Grid at Tianjin University, the phase trajectory of the FESS from a stable state towards chaos is presented using numerical and stroboscopic methods, and all dynamic behaviors of the system in this process are captured. The characteristics of the low-frequency oscillation and the mechanism of the Hopf bifurcation are investigated based on the Routh stability criterion and nonlinear dynamic theory. It is shown that the Hopf bifurcation is directly due to the loss of control over the inductor current, which is caused by the system control parameters exceeding certain ranges. This coupling nonlinear process of the FESS affects the stability of the motor running and the efficiency of energy transfer. In this paper, we investigate into the effects of control parameter change on the stability and the stability regions of these parameters based on the averaged-model approach. Furthermore, the effect of the quantization error in the digital control system is considered to modify the stability regions of the control parameters. Finally, these theoretical results are verified through platform experiments. 相似文献
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