硼、氮共掺杂多孔碳的制备及其超电容性能

分别以含氮菲咯啉、四硼酸钾和醋酸锌为碳源、活化剂和模板,制备了B、N共掺杂多孔碳(BN-PC),并探究模板质量对BN-PC结构和储电性能的影响。当醋酸锌质量为5 g时,所得BN-PC₅中B、N杂原子含量分别为20.21%、18.29%。电化学测试结果表明,以6 mol·L^-1KOH为电解液,BN-PC₅电极展现出高的比电容(在0.05 A·g^-1电流密度下为255 F·g^-1)、优异的倍率性能(在20 A·g^-1电流密度下为188 F·g^-1)和卓越的循环稳定性(在5 A·g^-1的电流密度下循环10 000次比电容保持率为97%)。以3mol·L^-1ZnSO₄为电解液,在平均功率密度为56 W·kg^-1时,BN-PC₅电容器的能量密度可达27 Wh·kg^-1。     

萘基相互连接的多孔碳纳米囊的制备及超电容性能

以萘为碳源, 采用MgO模板诱导耦合KOH裁剪技术制备了相互连接的多孔碳纳米囊(ICNC). 结果表明所制备的ICNC₂具有大的比表面积(1811 m²/g)、 高的压实密度(1.38 g/cm³)和微孔孔容含量(58.93%). 在对称的超级电容器(SC)中, ICNC₂电极的体积比容在不同电流密度下分别高达420.8 F/cm³(0.069 A/cm³)和315 F/cm³(27.6 A/cm³), 容量保持率为74.82%. 在38 W/L功率密度下, ICNC₂基SC的体积能量密度为14.6 W?h/L. 经过20000次循环后, 其体积比容仅衰减1.4%, 库伦效率为99.1%, 为从萘基小分子制备储能用功能碳材料提供了一种可行的方法.     

硼、氮共掺杂多孔碳的制备及其超电容性能

分别以含氮菲咯啉、四硼酸钾和醋酸锌为碳源、活化剂和模板,制备了B、N共掺杂多孔碳(BN-PC),并探究模板质量对BN-PC结构和储电性能的影响。当醋酸锌质量为5g时,所得BN-PC₅中B、N杂原子含量分别为 20.21%、18.29%。电化学测试结果表明,以6 mol·L^-1 KOH为电解液,BN-PC₅电极展现出高的比电容(在0.05 A·g^-1电流密度下为255 F·g^-1)、优异的倍率性能(在20A·g^-1电流密度下为188F·g^-1)和卓越的循环稳定性(在5 A·g^-1的电流密度下循环10 000次比电容保持率为97%)。以3 mol·L^-1 ZnSO₄为电解液,在平均功率密度为56W·kg^-1时,BN-PC₅电容器的能量密度可达27Wh·kg^-1。     

A Photonic Bandgap Filter Using Metallic Hilbert Curves

We theoretically suggest that a metallic plate with Hilbert curves can possesses multiple resonances in a linear scale, leading to multiple stop bands and pass bands for electromagnetic waves over a wide frequency range.The forward transmission from a line source nearby a small plate covered by four cells with Hilbert curves is checked by a probe at the far field, the results agree well with the multiple resonance frequencies calculated by the plane wave incidence under a periodic boundary condition, the return loss spectra show that radiations of a line antenna working at 4.5 GHz can be greatly enhanced, which results from the interaction of the antenna and the subwavelength metallic plate. This kind of metallic pattern is very practical in multi-frequency functioned wave devices with sub-wavelength sizes.     

光子晶体耦合腔波导的色散特性

理论研究表明，在基于光子晶体的耦合腔波导中，杂质带的色散性质取决于相邻缺陷间局域电磁场的特性，而非缺陷间距离的大小.在第一布里渊区中出现的杂质带的反常色散实际上是能带折叠的结果.通过计算结构的有效折射率，证实了杂质带色散是正常色散. 关键词： 光子晶体 反常色散 耦合腔 杂质带     

利用集总L-C元件构造的一维metamaterials特性的实验研究

在普通微带传输线中周期性地加载集总L C元件能够构造一维特异性材料(metamaterials)，它具有与众不同的特异性质.通过实验证实了波在这种结构中传播具有相速度与群速度方向相反的左手性通带，其折射率为负值，并发现平均折射率为零的能隙.这种结构具有结构紧凑，参数可调，制作简单的优点. 关键词： 负折射率 特异性材料 周期性结构 微带线     

抽运激光在光靶中的局域及其对X射线激光特性的影响

新型X射线靶设计为:由SiO2和TiO2组成具有12个周期的一维光子晶体,在它的中间嵌入光靶材料层作为缺陷层,SiO2,TiO2和光靶层的光学厚度分别为λ4、λ4和λ2,λ为抽运激光波长.与普通平板光靶相比,当抽运光垂直照射到这种光靶时,靶层内部的光强将提高2个数量级,所以抽运激光的阈值强度将降低2个数量级,这有利于X射线激光的小型化.在同样的抽运激光照射下,X射线激光的强度将提高4个数量级,转换效率也将提高约4个数量级.由于平均电离度随抽运激光强度的提高而提高,所以采用这种光靶有利于使X射线激光向短波长推进. 关键词： X射线激光 光子晶体 光波局域     

High-Efficiency Bistable Switching Based on One-Dimensional Photonic Crystals with Single-Negative Materials

We study theoretically the nonlinear responses of one-dimensional photonic crystals （PCs） composed of alternating two kinds of single-negative （permittivity-negative and permeability-negative） materials embedded with a Kerrtype nonlinear defect layer. In conventional PCs, it is difficult to realize a bistable switching with both low threshold and quick response time. However, in PCs with single-negative materials, by changing the ratio of the thicknesses of the two types of layers, with the decreasing size of the structure, the switching response time is shortened and the threshold intensity decreases simultaneously.     

Omnidirectional Gaps of One-Dimensional Photonic Crystals Containing Single-Negative Materials

We show that a one-dimensional photonic crystal containing two kinds of single-negative materials can possess an omnidirectional gap whose edges are insensitive to incident angle and polarization, owing to the unusual field configuration in the structure. In contrast to an omnidirectional gap based on a photonic gap that corresponds to zero averaged refractive index, it can be made very wide by varying the ratio of the thicknesses of two media.Moreover, it is independent of polarization under special parameters. These properties may provide a mechanism to design a broadband omnidirectional reflector with fixed bandwidth.     

Localized Mode Enhanced Coupler Based on Quasi-One-Dimensional Photonic Crystal Microstrip

We propose a novel localized mode enhanced (LME) coupler based on quasi-one-dimensional photonic crystal microstrips, which is promising to be applied in wavelength division multiplexed microwave communication systems. Compared to the traditional microstrip coupler, the LME structure has two advantages: high efficiency and frequency selectivity. Even in a relatively far coupling distance, this structure can still achieve a high efficiency about 50%. The frequency selectivity can be realized by simply tuning the distance between two transmission lines.