Pd催化P-C偶联合成膦配体的进展

本文综述了Pd催化的P-C偶联反应在多种膦化物合成中的应用,以及近年来利用Pd催化的P-C偶联和C-C偶联相结合在合成复杂的手性膦化物和对有机膦功能化研究中的成就。     

双水杨醛亚胺双核镍(Ⅱ)配合物降冰片烯加成聚合的研究

降冰片烯加成均聚产物具有好的热稳定性好和光学透明性,表现了优异的各向同性电性能,对金属具有很好的粘连附着性,可用于微电子器件的封装材料和液晶显示屏的保护涂层等领域,亦可作为耐高温工程材料使用,因而其制备和材料性能的研究备受学术界和企业界的青睐．降冰片烯加成聚合与传统的烯烃聚合具有许多相似     

二(4-溴苯基)氧化膦的改进合成及其在水溶性膦化合物合成中的应用

选择适当的反应条件实现对环境无害的有机及催化反应是 2 1世纪化学家所面临的重要挑战 [1～ 3 ] .Kuntz研究组 1 975年开展民含水两相催化反应的研究 [4 ] ,水溶性膦配体与过渡金属 (如铑、钯和镍等 )所形成的配合物可在水 /有机两相催化体系中实现不对称氢化、烯丙型烷基化、     

Crystal and Molecular Structure of 4-Hydroxy-3-Methoxy-4-N-Methylstilbazonium Iodide C15H16NO2+·I-

The crystal structure of the title compound C15H16NO2+ · I-(Mr=369. 19) has been determined by single crystal X-ray diffraction analysis. The crystal belongs to tbe monoclinic system with space group P21/c, a=8. 957(1), b=21. 8117(2), c=7. 8760(10)A , β=103.94(1)°, V=1493.8(3)A3, Z=4, Dc=1. 642g cm3,μ=2. 141mm-1, F(000)=728, final R=0. 0264, and Rw=0. 0644(I＞2σ(I)) for 2938 independent reflections. The results show that in the crystal structure of the title compound the planar cations have two configurations, and these cations are anti-parallelly packed through the strong π…π interaction.     

Crystal and Molecular Structure of 1-Methyl-4-(2-( 3,4-dimethoxyphenyl) vinyl) pyridinium 4-Tolylsulfonate Dihydrate C_(16)H_(18)NO_2~+·C_7H_7SO_3~-·2H_2O

1 INTRODUCTIONAs a useful nonlinear optical material, the molecule must have a large second-order hyperpolarizability (β), and also must crystallize in a non-centrosymmetric structure to have a large ((2). Organic conjugated molecules with electronic donors and acceptors possibly have quite strong second-order NLO property. However, only a small percentage of the molecules with large β crystal-lize in useful non-centrosymmetric crystals. Marder and his co-worker carried out a simple an…     

自差分交流偏置超导纳米线单光子探测器

超导纳米线单光子探测器(SNSPD)因其优异的综合性能,在量子信息、激光雷达等方面有广泛的应用.通常, SNSPD工作在直流偏置下,在时域上具有自由运行探测的优点.而在卫星激光测距、单光子激光雷达等光信号到达时间有规律的应用场景中,使用交流偏置有望提升器件运行速率、有效抑制背景暗计数,却存在信号读出困难的棘手问题.本文报道了自差分读出的交流偏置SNSPD系统,该系统包含两根并行排布纳米线构成的2-pixel SNSPD器件.给两根纳米线加载相同的100 MHz交流偏置信号,并对两路输出信号差分使噪声信号相抵消,实现光子响应信号的读出.基于该方法测得,响应信号的信噪比相比差分之前提升10倍,在交流偏置下器件的暗计数降低至直流偏置下的约1/4,计数率达到直流偏置下的约1.5倍.本文为交流偏置SNSPD测试提供了一种思路,为其应用提供参考数据.