排序方式: 共有87条查询结果,搜索用时 78 毫秒
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研究了雌马酚在不同pH条件下的紫外-可见吸收光谱和荧光光谱,从分子结构的角度解释了两种光谱在不同pH条件下发生光谱变化的原因。在中性条件下,雌马酚分子型体的最大吸收峰为280 nm;而在弱碱环境中,7位-OH质子发生电离,电离常数pKa_1=10.08±0.05,出现两个吸收峰(240 nm,294 nm),7位-OH质子电离使吸收峰发生红移;当溶液变为强碱性时,4’位-OH质子电离,电离常数为pKa_2=13.50±0.22,240 nm吸收峰的强度发生变化。在中性条件下,雌马酚的分子型体具有强荧光,最大激发波长和发射波长λ_(ex)/λ_(em)分别为278 nm/316 nm,荧光量子产率为0.11;在弱碱性溶液中,雌马酚的7位-OH质子电离,荧光光谱没有变化,但荧光强度迅速下降;在强碱性条件下,4’位-OH质子电离,导致雌马酚的荧光几乎消失。雌马酚的紫外-可见吸收光谱和荧光光谱的特征与分子结构中羟基的电离具有直接关系,雌马酚的7位-OH电离后的离子型体具有强吸收,它的分子型体具有强荧光。这些光谱特性可为雌马酚的光谱分析方法研究提供依据。 相似文献
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We investigate the third-order optical nonlinearities in four novel porphyrin dimers (dimers A to D) and a monomeric porphyrin H2 CPTPP measured by using the single-beam z-scan technique with a pulsed Q-switched Nd:YAG nanosecond laser at 532nm. All the samples show strong excited state absorption (ESA) and high value of Х^(3) in the ns domain at this wavelength. We perform a comparison between dimer A and its monomer H2 CPTPP in their third-order optical nonlinearity, and discuss the relationships between the values of Х^(3) and the different bridging groups for all the dimers. 相似文献
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Theoretical analysis of nanosecond crystallization kinetics of phase-change optical recording films 下载免费PDF全文
A theoretical investigation of nanosecond crystallization kinetics of the phase-change optical recording films is presented. An extended Kissinger equation for the square-root heating is
derived, which properly describes the temperature evolution of the films by nanosecond laser heating. The extended Kissinger equation was used to explain our previous experimental results. 相似文献
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C60/PMMA复合材料的反饱和吸收与光限幅特性研究 总被引:1,自引:0,他引:1
本文报导C60/PMMA复合材料的制备方法,并采用调QNd:YAG倍频脉冲激光照射C60/PMMA夏合材料,研究了其反饱和吸收与光限幅将性。在线性透射率为46%条件下,光限幅阈值能量密度为65mJ/cm2,材料破坏能量密度阈值为600mJ/cm2.与C60甲苯溶液相比具有一定的优点。 相似文献
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固体C60/PMMA的激发态吸收光限幅研究 总被引:1,自引:1,他引:0
应用五能级模型计算了C60/PMMA的激发态吸收光限幅特性;采用调Q倍频Nd:YAG脉冲激光测量了C60/PMMA的激发态吸收光限幅效应。理论和实验结果基本符合。 相似文献
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This paper reports the theoretical study of combining Z-scan technique with Gauss-Bessel (GB) beams beside a phase object (PO) to measure the third-order nonlinear susceptibility components.By using this method,the sign of refractive index which depends on the shape of the close aperture Z-scan curve can be easily determined.Meanwhile,the magnitude of nonlinear coefficients can also be deduced by theoretical fit.The proposed method is advantageous for high sensitivity and imposes a lower stress in the cases of fragile materials,since small pulse energy is enough for the measurement of nonlinear coefficients.Predictions of the models are compared with Gaussian Z-scan measurement and GB Z-scan measurement.By using GB beams with a PO,the sensitivity of Z-scan measurements is found to be a factor of over 60 times greater than for Gaussian beams and 2 times greater than for Gaussian-Bessel beams. 相似文献
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萘酞菁铅化合物的光限幅特性研究 总被引:6,自引:0,他引:6
应用调Q倍频ns/ps Nd:YAG脉冲激光,在波长为532nm,脉冲宽度为8ns,重复频率为1Hz的条件下,研究了溶于二甲基亚砜(DMSO)中的萘酞菁铅溶液的反饱和吸收和光限幅特性。实验表明,萘酞菁铅具有良好的光限幅特性,它的有效激发态吸收截面与基态吸收截面的比值约为15.21,大于萘酞菁铜。研究结果表明,萘酞菁铅的光限幅特性优于C60,激发态吸收是其主要的光限幅机理。实验结果证实了重原子效应可以通过增强系际跃迁而使三重态的反饱和吸收增强,从而提高光限幅的能力。 相似文献
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