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Stabilization variation of organic conductor surfaces induced by π-π stacking interactions 下载免费PDF全文
The structures and stabilization of three crystal surfaces of TCNQ-based charge transfer complexes(CTCs) including PrQ(TCNQ) 2,MPM(TCNQ) 2,and MEM(TCNQ) 2,have been investigated by scanning tunneling microscopy(STM).The three bulk-truncated surfaces are all ac-surface,which are terminated with TCNQ molecular arrays.On the ac-surface of PrQ(TCNQ) 2,the TCNQ molecules form a tetramer structure with a wavelike row behavior and a γ angle of about 18° between adjacent molecules.Moreover,the dimer structures are resolved on both ac-surfaces of MPM(TCNQ) 2 and MEM(TCNQ) 2.In addition,the tetramer structure is the most stable structure,while the dimer structures are unstable and easily subject to the STM tip disturbance,which results in changeable unit cells.The main reasons for the surface stabilization variation among the three ac-surfaces are provided by using the ’π-atom model’. 相似文献
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In this review, we present a summary of some recent experiments on topological insulators (TIs) and superconducting nanowires and fihns. Electron electron interaction (EEI), weak anti-localization (WAL) and anisotropic magneto-resistance (AMR) effect fbund in topological insulator fihns by transport measurements are reported. Then, transport properties of superconducting films, bridges and nanowires and proximity effect in non-superconducting nanowires are described. Finally, the interplay between topological insulators and superconductors (SCs) is also discussed. 相似文献
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