基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

水热条件下,合成了钴(Ⅱ)配位聚合物{[Co(L)(chdc)].2H2O}n(1)(L=1,3-二(苯并咪唑-1-甲基)苯,H2chdc=1,4-环己烷二酸)。结构分析表明,配合物1的晶体属于单斜晶系,C2/c空间群,晶胞参数为a=1.4504(1)nm,b=1.834 9(2)nm,c=2.128 7(2)nm,β=94.325(1)°,V=5.649 2(9)nm3,Z=4。该配合物为一维环状链结构,并进一步通过链间的π-π作用自组装成二维超分子结构。配合物1作为类芬顿反应的催化剂降解刚果红显示较高的活性。     

微晶纤维素电流变液在挤压流中的粘弹性

测量了微晶纤维素/蓖麻油悬浮体构成的电流变液在挤压流中的动态粘弹性.给出了平行于电 场方向的储能模量G′和损耗模量G″对电场和应变幅度的依赖关系.实验显示,当电场超过 临界电场后,随着应变幅度增加, 电流变液的粘弹性从线性变到非线性,电流变液出现了应 变导致的“类固体”和流体之间的转变过程. 还研究了应变幅度和振荡频率对电流变液粘弹性非线性的影响. 关键词： 电流变液 挤压流 粘弹性     

微晶纤维素电流变液压在挤压流的粘弹性

测量了微晶纤维素／蓖麻油悬浮体构成的电流液在挤压流中的动态粘弹性,给出了平行于电场方向的储能模量Ｇ’和损耗模量Ｇ”对电场和就变幅度的依赖关系,实验显示,当电场超过临界电场后,随着应就幅度增加,电流变液的粘生从线性变到非线性,电流变液出现的应变导致的“类固全”和流体之间的转变过程,还研究了应变幅度和振荡频率对电流变液粘生非线性的影响。     

RESONANCE RESPONSE OF ELECTRORHEOLOGICAL FLUIDS IN VERTICAL OSCILLATION SQUEEZE FLOW

The resonance effect of microcrystalline cellulose/castor oil electrorheological (ER) suspensions was studied in a compressed oscillatory squeeze flow under external electric fields. The resonance frequency first increases linearly with increasing external field, and then shift to high-field plateau. The amplitudes of resonance peak increase sharply with the applied fields in the range of 0.17-1.67 kV/mm. The phase difference of the reduced displacement relative to the excitation force inverses in the case of resonance. A viscoelasticity model of the ER suspensions, which offers both the equivalent stiffness and the viscous damping, should be responsible for the appearance of resonance. The influence of the electric field on the resonance frequency and the resonance hump is consistent qualitatively with the interpretation of our proposed model. Storage modulus G' was presented for the purpose of investigating this influence.     

含水层储能影响因素分析

本文建立了热泵耦合含水层储能系统的地下水流动及热质迁移的耦合数学模型,模拟了不同井距和在不同水文地质条件下对井抽灌储能区域的温度场变化.通过分析得出:增大井距可延长发生热突破的时间、提高储能效果,但储能对地下环境的热影响也相应增大;含水层介质的渗透系数(或渗透率)、弥散度以及导热系数越大则储能效果越差,体积比热容越大储能效果越好,且体积比热容对储能效果的影响较显著.     

圆锥曲线中一组漂亮的统一性质

借助《几何画板》,笔者近日在学习和教学中发现了圆锥曲线中一组漂亮的统一性质,现与大家分享.性质1若抛物线y2=2px(p>0)上某点P的法线与x轴交于点G,过点G作焦半径PF的垂线l,垂足为L,则|PL|=p.     

Fabrication and electrical properties of a carbon nanotube quantum dot

Single-walled carbon nanotubes (SWNTs) were synthesized by pyrolyzing methane (CH₄) at a temperature of 900℃ on SiO₂ substrates pre-coated with iron nano-particles. Electrical contacts were fabricated onto one of the SWNTs by using an electron beam lithography process. Coulomb blockade and single-electron tunnelling characters were found at low temperatures, indicating that the SWNT in-between the electrodes forms a quantum dot. It is found that the Coulomb gap of the quantum dot is about 8.57 meV, and the factor \alpha , which converts the gate voltage to the true electrostatic potential shift, is around 200 for this device.     

基于环己二酸和双苯并咪唑配体的一维钴(Ⅱ)配位聚合物的合成、结构和催化性能研究

水热条件下,合成了钴(Ⅱ)配位聚合物{[Co(L)(chdc)]·2H₂O}_n (1) (L=1,3-二(苯并咪唑-1-甲基)苯,H₂chdc=1,4-环己烷二酸)。结构分析表明,配合物1的晶体属于单斜晶系,C2/c空间群,晶胞参数为a=1.4504(1) nm,b=1.834 9(2) nm,c=2.128 7(2) nm,β=94.325(1)°,V=5.649 2(9) nm³,Z=4。该配合物为一维环状链结构,并进一步通过链间的π-π作用自组装成二维超分子结构。配合物1作为类芬顿反应的催化剂降解刚果红显示较高的活性。     

Study of spatial signal transduction in bistable switches

Bistable switch modules are among the most important fundamental motifs in signal-transduction pathways. To better understand their spatial signal transduction, we model the diffusion process in the one-dimensional (1–D) domain. We find that when none of the elements diffuse, the response of the system exhibits a spatial switch–like property. However, when one of the elements is highly diffusible, the response of the system does not show any spatial switching behavior. Furthermore, we observe that the spatial responses of the system are more sensitive to the time constant of the switch when none of the elements are diffusible. Further, a slow loop keeps the system in the high steady state more positions than that in the fast loop. Finally, we consolidate our numerical results analytically by performing a mathematical method.     

YFeO3的电子结构和光学性质的第一性原理研究

稀土正铁氧体YFeO₃呈正交钙钛矿结构,其晶体和纳米晶材料在电极材料、 传感器和光催化领域具有重要的应用价值.用平面波赝势方法,采用广义梯度近似、改进的Perdew-Burke-Emzerhof交换-关联势、 实空间超软赝势计算方案,研究了YFeO₃晶体的几何结构、电子结构和光学性质. 计算得到的晶格参量与报道的实验结果一致.通过对能带结构、态密度、介电函数、吸收系数和光电导率的计算和分析, 确定YFeO₃是直接能隙半导体,能隙E_g约为2.22 eV,阐明了YFeO₃晶体和纳米晶具有较好的可见光催化性能.