有机张力半导体及其光电特性

分子张力作为空间设计的重要组成部分正成为调控有机半导体的重要手段。由于分子内产生的拉伸张力、扭曲/弯曲张力以及空间张力而导致p轨道排布重组和构型构象结构发生变化,最近各种几何与拓扑结构的高张力有机半导体材料相继被报道,这使得高张力有机半导体材料成为有机电子领域研究的焦点。为了进一步梳理分子张力在有机半导体材料中扮演的角色与价值,该综述从分子张力的类型、实验与理论量化以及可视化出发,总结了高张力共轭芳烃的分子设计策略、与其光电性能分子张力之间的关系,以及这类新兴材料在光电领域的应用。最后,对高张力共轭芳烃的研究前景进行了展望,阐述了该类材料所面临的机遇与挑战。     

流动注射-分光光度法测定药物中克林霉素磷酸酯的含量

试验表明:在pH 3.8的乙酸盐缓冲介质中,克林霉素磷酸酯(CLP)能将铁(Ⅲ)还原为铁(Ⅱ),而所生成的铁(Ⅱ)与邻菲啰啉反应生成有色络合物(λmax=508nm),且生成的铁(Ⅱ)量与CLP之间存在定量关系,经换算所测得吸光度与CLP的质量浓度在0.70~140mg·L-1之间呈线性关系。据此并结合流动注射技术(FI)提出了FI-分光光度法间接测定药物中CLP的新方法优化的分析条件如下:①乙酸盐缓冲溶液的加入量:2.5mL;②铁(Ⅲ)溶液质量浓度:10.0mg·L-1;③邻菲啰啉溶液浓度:1.5×10-3 mol·L-1;④反应温度:85℃。该方法的检出限为0.060mg·L-1。应用此方法测定了药物中CLP的含量,测定值与国家药品标准方法的测定值相符。     

Laser Mode-Dependent Size of Plasma Zones Induced by Femtosecond Laser Pulses in Fused Silica

We carry out the numerical simulations of femtosecond laser propagation with TEMoo mode, TEM10 mode and a beam combining both the modes in fused silica. It is found that the transverse size of plasma zones induced by laser pulses with the TEM10 mode is smaller than that induced by the TEM00 mode, while the longitudinal size is almost the same, and the saturated plasma density is higher. The transverse size, the longitudinal size and the ratio of the longitudinal to transverse size, for the beam combining both the modes, all could be reduced at the same time in comparison with the TEM00 mode under the same focusing conditions.     

广西大风子中2个新木脂素的NMR研究

从广西大风子的皮中分离得到两个新木脂素1和2,并通过高分辨质谱和核磁共振确定了其结构. 利用多种二维核磁共振技术,包括HSQC, HMBC, DQF-COSY 和NOESY谱,对其碳氢信号进行了全归属. 毛细管电泳分析显示1和2均为外消旋体.     

Relaxation of Dense Electron Plasma Induced by Femtosecond Laser in Dielectric Materials

Electron plasma induced by a focused femtosecond pulse （130 fs, 800 nm） in dielectric materials （Soda Lime glass, K9 glass, and SiO2 crystal） is investigated by pump-probe shadow imaging technology. The relaxation of the electron plasma in the conduction band is discussed. In SiO2 crystals, a fast self-trapping process with a trapping time of 150fs is observed, which is similar to that in fused silica. However, in Soda Lime glass and K9 glass, no self-trapping occurs, and two decay processes are found： one is the energy relaxation process of conduction electrons within several picoseconds, another is an electron-hole recombination process with a timescale of lOOps. The electron collision time T in the conduction band is also measured to be in the order of 1 fs in all of these materials.     

随机Motsch-Tadmor模型的集群行为研究

将乘性白噪声作为系统的扰动因素,研究随机环境下的Motsch-Tadmor模型的集群行为.在由非对称耦合网络连接各粒子的系统中,给出随机系统发生集群行为的定义,通过对噪声强度和初值的控制使得系统能够以指数收敛的速度达到稳定的平衡状态,并得到发生集群行为的充分条件.     

不同醇对猪心线粒体F_1-ATPase和H~+-ATPase复合体构象的影响——圆二色性光谱研究

本文测定了ATPase复合体和F_1-ATPase在低浓度甲、乙、正丙、异丙、叔丁醇中的远紫外圆二色(CD)谱。结果表明:5—20%甲醇、5—10%乙醇、5%正丙醇、5—10%异丙醇和叔丁醇使F_1—ATPase的CD谱双负峰变大,F_1的α-螺旋量增加,20%乙醇,10—20%正丙醇、20%异丙醇则使F_1的CD双负峰明显变小,F_1的α-螺旋量显著减少。而外加5—20%的醇对ATPase复合体的远紫外CD谱影响不大,计算出的α-螺旋量也无明显变化。显然,与游离的F_1-ATPase相比,ATPase复合体中疏水蛋白(F_0)及部分磷脂的存在,使其构象呈现了醇稳定性。     

采用毛细管电泳方法以凝血酶为靶筛选天然药物提取化合物

采用毛细管电泳(CE)法研究了凝血酶和水蛭素及肝素间的相互作用, 并测定了凝血酶和水蛭素的结合常数. 选择凝血酶为靶点, 建立了快速灵敏的从天然植物提取物中筛选出先导化合物的CE方法. 在接近生理环境的水溶液条件下, 研究了两色金鸡菊、肉苁蓉和黄蜀葵中天然植物提取物与凝血酶之间的相互作用; 与阴性对照和阳性对照相比, 从11个天然化合物中快速筛选出与凝血酶有相互作用的6个化合物, 提高了天然植物提取物药理活性筛选的效率.     

Time-resolved study of the lasing emission from high vibrational levels of N2^+ pumped with circularly polarized femtosecond pulses

We experimentally investigated the forward 353.8 nm radiation from plasma filaments in pure nitrogen gas pumped by intense circularly polarized 800 nm femtosecond laser pulses.This emission line corresponds to the B^2Σu^+(u'=4)-X^2Σg^+(u=3)transition of nitrogen ions.In the presence of an external seeding pulse,the 353.8 nm signal was amplified by 3 orders of magnitude.Thanks to the much enhanced intensity,we performed time-resolved measurement of the amplified 353.8 nm emission based on the sum-frequency generation technique.It was revealed that the built-up time and duration of these emissions are both inversely proportional to the gas pressure,while the radiation peak power grows up nearly quadratically with pressure,indicating that the 353.8 nm radiation is of the nature of superradiance.     

聚合物光纤连接的插入损耗研究

采用光束传播法模拟分析了塑料光纤连接的光传输情况,对倾斜连接、直径失配连接、轴向错位连接这三种产生损耗的主要因素进行了分析.分别对改变倾斜角度(0～0.02 rad)、直径失配(0～30μm)、轴向错位距离(0～30 μm)进行了模拟计算,得到了这三种因素各自产生的损耗情况.这些计算结果对设计和制造塑料光纤连接器有一定的指导作用.