Ⅱ型TiO2/g-C3N4异质结的构筑促进高效光催化U(Ⅵ)还原

采用水热法将TiO₂纳米片修饰在中空管状g-C₃N₄上制备了TiO₂/g-C₃N₄(T-CN)复合催化剂。利用扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、紫外可见漫反射光谱(UV-Vis DRS)和光电流响应等对其形貌、结构和光物理性能进行了表征。结果表明,TiO₂纳米片均匀地分散在中空管状g-C₃N₄表面,两者紧密结合形成异质结。TiO₂与g-C₃N₄的质量比为20%时制得的T-CN-20复合催化剂在60 min内对U (Ⅵ)的去除率为85.64%,是纯相g-C₃N₄的6.7倍。在10倍高浓度阳离子共存条件下的去除率仍大于69.8%,且具有优良的结构稳定性。对光催化产物分析可知,T-CN将U (Ⅵ)还原为难溶的U (Ⅳ)(63.68%)以去除铀,可有效解决含铀核废水中的U (Ⅵ)污染问题。根据能带理论分析,提出了复合催化剂异质结的Ⅱ型光催化机理。     

基于高吸水/保水材料的红外隐身复合材料的可行性研究及效能评价

根据战场条件及红外材料的性能要求,在研究高吸水/保水材料特性的基础上对开发基于高吸水/保水材料的红外隐身复合材料的可行性进行研究分析,提出以高吸水/保水材料为基底的红外隐身复合材料的两种设计方案并制备出该红外隐身复合材料样板.通过对其进行红外效果评价,结果表明,该材料若作为军事目标的表面材料能有效改变目标的红外辐射特性...     

基于虚拟仪器的核电站主管道振动监测系统设计

针对主管道振动在线监测的迫切性需要,分析了主管道振动监测的原理;开展了核电站主管道振动监测系统的硬件设计和软件设计;采用LabView为开发平台,集虚拟仪器技术、设备组态图形技术和数据库管理技术于一体,实现了主管道振动的在线实时监测;利用电磁振动台模拟主管道的振动,验证了主管道振动监测系统的性能和基本功能。     

Thickness dependence of the anomalous Hall effect in disordered face-centered cubic FePt alloy filmsThickness dependence of the anomalous Hall effect in disordered face-centered cubic FePt alloy filmsThickness dependence of the anomalous Hall effect in disordered face-centered cubic FePt alloy films

The anomalous Hall effect in disordered face-centered cubic （fcc） FePt alloy films is experimentally studied. The longitudinal resistivity independent term of the anomalous Hall conductivity （AHC） increases and approaches saturation with increasing film thickness. The contribution of side jump scattering is suggested to decrease monotonically with increasing film thickness, which can be ascribed to the variation of the surface scattering with the film thickness. The sign of the skew scattering contribution to the AHC is opposite to that of the intrinsic contribution in the system.     

Spin-Wave Modes in Exchange-Coupled FePt/FeNi Bilayer Films

A simple magnetic modulation structure of the exchange-coupling FePt/FeNi bilayer film is fabricated and studied for its magnetization dynamics using time-resolved magneto-optical polar Kerr spectroscopy. It is found that two spin-wave modes can be excited. One is fixed at -3.2 GHz in frequency for any external field and may serve as a frequency-stabilized spin-wave filter, while the other is external field dependent. In contrast, only the external field-dependent mode is excited in single-layer FeNi, supporting the localized origin of the mode at -3.2 GHz, which is confined to a thin exchange-coupling region. The other external field-dependent mode in frequency is attributed to the Kittel mode.     

Ⅱ型TiO2/g-C3N4异质结的构筑促进高效光催化U(Ⅵ)还原

采用水热法将TiO₂纳米片修饰在中空管状g-C₃N₄上制备了TiO₂/g-C₃N₄(T-CN)复合催化剂。利用扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、紫外可见漫反射光谱(UV-Vis DRS)和光电流响应等对其形貌、结构和光物理性能进行了表征。结果表明,TiO₂纳米片均匀地分散在中空管状g-C₃N₄表面,两者紧密结合形成异质结。TiO₂与g-C₃N₄的质量比为20%时制得的T-CN-20复合催化剂在60 min内对U的去除率为85.64%,是纯相g-C₃N₄的6.7倍。在10倍高浓度阳离子共存条件下的去除率仍大于69.8%,且具有优良的结构稳定性。对光催化产物分析可知,T-CN将U还原为难溶的U(63.68%)以去除铀,可有效解决含铀核废水中的U污染问题。根据能带理论分...     

Thickness dependence of the anomalous Hall effect in disordered face-centered cubic FePt alloy films

The anomalous Hall effect in disordered face-centered cubic(fcc) FePt alloy films is experimentally studied. The longitudinal resistivity independent term of the anomalous Hall conductivity(AHC) increases and approaches saturation with increasing film thickness. The contribution of side jump scattering is suggested to decrease monotonically with increasing film thickness, which can be ascribed to the variation of the surface scattering with the film thickness. The sign of the skew scattering contribution to the AHC is opposite to that of the intrinsic contribution in the system.