酯型十八烷基键合硅胶整体柱的制备、表征及性能评价

将硅烷偶联剂γ-(2,3-环氧丙氧)丙基三甲氧基硅烷与十八酸反应,再键合到硅胶整体柱上,得到了酯型十八烷基键合固定相,并用红外光谱、元素分析对其进行了表征。在以甲醇-水为流动相的反相色谱条件下分离了苯、联苯和蒽的混合样品,评价了该整体柱的色谱性能,考察了该整体柱适用的pH范围,以及柱压降、柱效与流速的关系。结果表明,该硅胶整体柱键合效果良好,具有较好的反相色谱性能,且在pH=2～8时稳定性好,柱压降、柱效受流速影响较小,可有效地用于化合物的快速分离分析。     

关于一道几何题的另一种思考

《中学生数学》2001年5月(上)期刊登的《例谈数学解题中的灵感》中例5:在四面体V-ABC中,三组对棱两两相等,且分别为13、14、15,求其体积. 原文所用方法是利用长方体中平行面的对角线相等这一特点,将四面体放入长方体中求解.笔者还有一种方法. 如图,VA=13,VB=14,VC=15.将棱AB平移,构成棱杆V’C’A- VCB,     

基于PDCA循环理论的完全线上教学模式探索与实践*——以化工原理课程为例

为保障新冠疫情期间“停课不停学”的高质量开展,以化工原理课程教学为例,探讨了PDCA循环理论在“3+1+4+3”完全线上教学模式中的应用,实践教学表明2者的融合能有效保证教学顺利有序开展,对于提高学生学习动力效果显著。     

Influence of Multiple Micro Cracks on the Damage Behavior of a Macro-Crack Tip北大核心CSCD

The solution of an infinite plane containing a macro crack and a cluster of micro cracks under uniaxial tensile load was presented based on Muskhelishvili’s complex function method and the stepwise recursive method. The stress field and stress intensity factor K were obtained. Combined with the damage mechanics, damage parameter D of the macro-crack tip and the micro-crack tip under uniaxial tension was redefined, and the influence of different damage zone forms on the damage of the crack tip was analyzed. The results show that, both the chain-distribution and the reverse-chain-distribution micro cracks have an amplifying effect on the macro crack growth, and the damage parameter increases with the decrease of the inclination angle of the micro crack and the reduction of the distance between the macro crack and the micro cracks. For a relatively small inclination angle of the micro crack, the damage parameters of the macro crack and the micro crack heightens, and the damage parameter of the macro crack increases with the micro-crack length. For evenly distributed micro cracks in the continuous damage zone, the micro cracks have an amplifying effect on the macro-crack growth, and the damage parameter of the macro crack increases with the micro-crack number. © 2022 Editorial Office of Applied Mathematics and Mechanics. All rights reserved.     

Stress mechanism of pulsed laser-driven damage in thin film under nanosecond ultraviolet laser irradiation

An analytical model is derived to describe the stress mechanism in a thin film against the laser-induced damage threshold (LIDT) based on the thermal transfer equation. Different structures of high-reflection films at 355 nm are prepared to validate this model. LIDTs are found to have a linear relationship with stress. Furthermore, predictions from the simple model agree with the experiments.     

采用性别相关的深度神经网络及非负矩阵分解模型用于单通道语音增强

为了从带噪信号中得到纯净的语音信号,提出了一种采用性别相关模型的单通道语音增强算法。具体而言,在训练阶段,分别训练了与性别相关的深度神经网络-非负矩阵分解模型用于估计非负矩阵分解中的权重参数;在测试阶段,提出了一种基于非负矩阵分解和组稀疏惩罚的算法用于判断测试语音中说话人的性别信息,然后再采用对应的模型估计权重,并结合已训练好的字典进行语音增强。实验结果表明所提算法在噪声抑制量及语音质量上,均优于一些基于非负矩阵分解的算法和基于深度神经网络的算法。      

裂纹长度对钢轨裂纹扩展的影响

采用有限元分析软件ANSYS,在纯滚动运行状态下,对实际钢轨裂纹的扩展情况进行了模拟。结果表明:轮轨接触的疲劳裂纹为张开型和滑开型同时存在的复合型裂纹;随裂纹长度的逐渐增加,裂尖有效应力强度因子先减小后增大,裂纹扩展速率会出现先变慢后变快的现象。     

Phase shift of polarized light through sculptured thin films: Experimental measurements and theoretical study

A slanted columnar TiO2 sculptured anisotropic thin film （ATF） is prepared via the glancing angle deposition technique and used as the phase retardation plate. The tilted nanocolumn microstructures of thin film induce the optical anisotropy. With the biaxial birefringent model, the optical constants dispersion equations of TiO2 ATF are derived by fitting the transmittance spectra for s-and p-polarized waves measured at normal and oblique incidence within 400 nm–1200 nm. The phase shift of polarized light after reflection and/or transmission through the TiO2 ATF is analyzed with the characteristic matrix employing the extracted structure parameters. The theoretical studies reasonably well accord with the experimental results measured with spectroscopic ellipsometry. In addition, the dependences of the phase shift on the coating physical thickness and oblique incidence angle are also discussed. Birefringence of the biaxial ATF provides a sophisticated phase modulation by varying incidence angles over a broad range to have a wide-angle phase shift.