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Effect of Cu doping on the magnetic and electrical properties of n=2 Ruddlesden-Popper manganates 下载免费PDF全文
A series of polycrystalline Cu-doped n=2 Ruddlesden-Popper manganates La1.2Sr1.8CuzMn(2-x)O7 (x=0, 0.04, 0.13) were synthesized by the solid state reaction method. The effect of Cu doping on the magnetic and transport properties has been studied. It is found that Cu substitution for Mn greatly affects the magnetic and electrical properties of the parent phase La1.2Sr1.8Mn2O7. With the increase of Cu content, the system undergoes a transition from longrange ferromagnetic order to the spin glass state and further to an antiferromagnetic order. A little of Cu dopant can lead to the samples showing semiconductor or insulator behaviour in the whole observed temperature range while the parent phase has a metal-insulator transition. These samples show colossal magnetoresistance at low temperatures and the value of it decreases with increasing Cu content. 相似文献
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The magneto-transport properties are investigated in metamagnetic CoMnSi0.88Ge0.12 alloy.By applying a magnetic field or increasing temperature,a metamagnetic phase transition from antiferromagnetic to ferromagnetic is observed in this alloy.Around the metamagnetic phase transition,CoMnSi0.88Ge0.12 alloy exhibits a large and negative magnetoresistance effect(~32%) under a magnetic field of 20 kOe(1 Oe = 79.5775 A/m),which is ascribed to the spin-dependent scattering of conduction electrons. 相似文献
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采用固相反应烧结法制备了(La1-yTby)0.67Sr0.33MnO3系列样品(y=0,0.05,0.15,0.20,0.25,0.33,0.40,0.50,0.60,1.00).X射线衍射表明,随着y值增大钙钛矿型晶体结构从菱面对称性向正交对称性转变.180K时,μ0H=7T条件下,在y=0.40样品的巨磁电阻可达900%.μ0H=1.7T时,y=0.20样品的室温磁致伸缩为-50×10-6.210K时,y=0.33样品的磁致伸缩可达-130×10-6.
关键词: 相似文献
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用固相烧结的方法成功制备了层状钙钛矿锰氧化物La1.2Sr1.8Cu0.04Mn1.96O7西多晶样品。研究发现,在层状钙钛矿La1.2Sr1.8Mn1.96O7中,用Cu替代Mn对其磁、电的性质影响非常显著。随温度的降低样品表现出从顺磁(PM)到铁磁(FM)及自旋玻璃态(SG)等复杂的磁相变行为。电性测量表明,在整个观察的温区内都表现出绝缘体或半导体的性质。对电阻率.温度曲线进行拟合表明:在低温区采用变程跳跃模型和在高温区采用小极化子模型都得到了较好的线性关系。 相似文献
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磁化水、自来水和蒸馏水的拉曼散射研究 总被引:5,自引:0,他引:5
对自来水、蒸馏水和磁化水进行了拉曼散射研究。发现:水经磁化后水分子结构未变化,氢键未断裂;磁化效果与磁化时间、磁场强度和磁化方式有关;静态磁化同样有效;水中离子在磁化过程中起重要作用。在离子水化理论基础上,对实验结果和磁化机理作了初步的解释和探讨。对磁水器的设计提出了建议。 相似文献
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Effects of the Mn/Co ratio on the magnetic transition and magnetocaloric properties of Mn1+xCo1-xGe alloys 下载免费PDF全文
We have investigated the magnetic transition and magnetocaloric effects of Mn 1+x Co 1 x Ge alloys by tuning the ratio of Mn/Co.With increasing Mn content,a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature.Further increasing the content of Mn (x=0.11) gives rise to a single second-order magnetic transition.Interestingly,large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys.The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper. 相似文献
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Effects of pre-deformation on the martensitic transformation and magnetocaloric property in Ni-Mn-Co-Sn ribbons 下载免费PDF全文
This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co-Sn ribbons.The experimental results show that the reverse martensitic transformation temperature T M increases with the increasing pre-pressure,suggesting that pre-deformation is another effective way to adjust T M in ferromagnetic shape memory alloys.Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well.It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn-Co-Sn ribbons. 相似文献
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