堆浸浸出率灰色动态GDM(1,1)预测研究

基于灰色系统理论扩展了GM(1,1)模型建模方法.给出了一些既改善原始数据列的光滑度,又减少还原误差的变换函数构造条件.首次将灰色动态模型结合变换函数应用于堆浸过程浸出率的预测.结果表明:该方法预测精度高,为实现浸出动力学未来行为的预测和控制提供了一种新的方法.     

堆浸工艺中流动-反应-变形-传质耦合过程数值模拟及应用

基于堆浸过程中的孔隙变形,发展了一孔隙发育模型,并建立了堆浸工艺中流动-反应-变形-传质全耦合模型控制方程组,在喷淋强度不变和常水头的的情况下,给出了方程的数值解.数值结果描述了浸出过程矿堆中溶浸液饱和度的分布、溶浸剂浓度和浸出矿石浓度的分布,拟合结果表明:有用矿物浸出百分比与浸出时间之间呈3次关系,这一关系可用来预测堆浸中的有用金属的浸出回收率.     

细菌堆浸中流动反应传热耦合过程数值模拟分析

针对辉铜矿微生物浸出过程进行数学建模,利用ComsolMultiphysics软件对浸堆中热量传递、氧气流动、目的金属离子分布以及氧化转化率等进行数值模拟分析．结果表明:沿堆体斜坡边界处氧的浓度较大,而在堆的中央部分,氧气的浓度非常小,导致这部分区域浸出反应缓慢;沿浸堆边坡处的温度偏低,温度最高的部分在底部区域附近靠近边坡位置处,且温度升高值超过6℃;矿堆底部靠近边坡区域目的金属离子浓度最高;靠近底部和斜坡部分,浸出反应速率快、氧化转化率高．矿堆的其余部分,因氧浓度低,导致浸出反应速率缓慢、氧化转化率低．     

Prediction of leaching rate in heap leaching process by grey dynamic model GDM（1,1）

The method of developing GM（1,1） model is extended on the basis of grey system theory. Conditions for the transfer function that improve smoothness of original data sequence and decrease the revert error are given. The grey dynamic model is first combined with the transfer function to predict the leaching rate in heap leaching process. The results show that high prediction accuracy can be expected by using the proposed method. This provides a new approach to realize prediction and control of the future behavior of leaching kinetics.     

Analysis of coupled flow-reaction with heat transfer in heap bioleaching processes

A mathematical model for heap bioleaching is developed to analyze heat transfer, oxygen flow, target ion distribution and oxidation leaching rate in the heap. The model equations are solved with Comsol Multiphysics software. Numerical simulation results show the following facts： Concentration of oxygen is relatively high along the boundary of the slope, and low in the center part where leaching rate is slow. Temper- ature is relatively low along the slope and reaches the highest along the bottom region near the slope, with difference being more than 6℃. Concentration of target mental ions is the highest in the bottom region near the slope. Oxidation leaching rate is relatively large in the bottom and slope part with a fast reaction rate, and small in the other part with low oxygen concentration.     

Simulation of coupled flowing-reaction-deformation with mass transfer in heap leaching processes

Governing equations for a fully coupled flowing-reaction-deformation behavior with mass transfer in heap leaching are developed. The model equations are solved using an explicit finite difference method under the conditions of invariable application rate and constant hydraulic head. The distribution of the degree of the saturation, as well as the distributions of the concentration of the reagent and the solute is given. A cubic relationship between the mineral recovery and the leaching duration is obtained based on the numerical results. The relationship can be used to predict the recovery percentage of the valuable metal.