Growth,characterization, and Raman spectra of the 1T phases of TiTe2, TiSe2, and TiS2

High-quality large 1$T$ phase of Ti$X_2$ ($X ={\rm Te}$, Se, and S) single crystals have been grown by chemical vapor transport using iodine as a transport agent. The samples are characterized by compositional and structural analyses, and their properties are investigated by Raman spectroscopy. Several phonon modes have been observed, including the widely reported $A_{1g}$ and $E_g$ modes, the rarely reported $E_u$ mode ($\sim$183 cm$^{-1}$ for TiTe$_2$, and $\sim$185 cm$^{-1}$ for TiS$_2$), and even the unexpected $K$ mode ($\sim$85 cm$^{-1}$) of TiTe$_2$. Most phonons harden with the decrease of temperature, except that the $K$ mode of TiTe$_2$ and the $E_u$ and "$A_{2u}$/Sh" modes of TiS$_2$ soften with the decrease of temperature. In addition, we also found phonon changes in TiSe$_2$ that may be related to charge density wave phase transition. Our results on Ti$X_2$ phonons will help to understand their charge density wave and superconductivity.     

基于卧式容器的罐容标定和变位识别的系统建模与分析

就一类特殊的卧式容器,建立了在有纵向倾斜和横向偏转等变位时这类卧式容器的变位识别和罐容标定的系统模型并分析研究.通过文献[7]提供的试验数据,对卧式储油罐的变位识别和罐容标定值进行的分析研究表明:所建立的卧式容器的变位识别和罐容标定的系统模型具有较高的精度和良好的稳定性.同时这一系统模型和分析体系也适用于其它类型的液体容器的研究,具有广阔的应用前景.