Halogen bond between hypervalent halogens YF3/YF5 (Y=Cl,Br, I) and H2X (X= O,S, Se)

ABSTRACT

The complexes of H₂X (X?=?O, S, Se) with hypervalent halogens YF₃ and YF₅ (Y?=?Cl, Br, I) have been studied. The σ-hole on the Y atom participates in a halogen bond with the lone pair on the chalcogen atom. In addition, some secondary interactions coexist with the halogen bond in most complexes. The interaction energy correlates with the nature of both X and Y atoms. In most cases, the complex is more stable for the heavier Y atom and the lighter X atom. Of course, there are some exceptions in H₂X···YF₃. YF₃ forms a more stable complex with H₂X than does YF₅. These complexes are dominated by electrostatic interaction and the halogen bond involving H₂S and H₂Se exhibits some covalent character.

Halogen bond plays an important role in chemical reactions and multivalent halogens can regulate chemical reactions by participating in a halogen bond. Thus we compare the effect of the chalcogen electron donor on the strength and nature of halogen bonding involving multivalent halogens.     

用于SCA ASIC测试的数字读出模块设计

高速开关电容阵列(SCA)具有高速采样、低功耗的特点,基于SCA的高速波形数字化是目前高精度时间测量的一个重要研究方向。为此,我们开展SCA芯片的研究,目前已设计完成原型ASIC设计,并正在进行后续版本的改进设计。为便于未来多版本ASIC的测试和评估,需设计具有一定通用性的数字读出模块,本论文工作主要介绍此模块的设计工作以及相应的数据读出软件。数字读出模块基于FPGA实现对待测ASIC的控制、配置及数据读出,采用DDR3片外存储芯片,使用USB3.0等接口进行数据传输;上位机软件基于Python3.7设计,实现了数据采集与波形绘制等功能。目前已使用设计完成的数字读出模块对第2版SCA ASIC进行了初步的测试,测试结果表明,此读出模块工作正常,且SCA芯片输出结果符合预期。     

Plasma flow accompanied by blowing and pumping of plasma across electrodes

The article discusses plane stationary slowly varying flows of a nonviscous plasma with good conductivity in a channel in a transverse magnetic field; the flows are accompanied by blowing in and pumping plasma across solid metallic electrodes. The Hall effect is taken into consideration. It is shown that the potential jump near the anode, which appears in an accelerated plasma flow in an ordinary channel with solid electrodes, can be eliminated in flows accompanied by blowing in (pumping) of plasma. It is also shown that flows are possible in which the velocity, density, and the transverse electric field increase in the direction of the accelerator cathode.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 6, pp. 26–34, November–December, 1970.     

Synthesis of New SrPb3Br8 Crystals and Investigation of Their Properties

Crystallography Reports - A new compound, SrPb3Br8, has been synthesized and investigated by X-ray diffraction and spectroscopic methods. Its crystal structure is described as follows: Pnma, a =...     

Quantum-chemical study on adenine nitrosonium complexes

Adenine complexes with nitrosonium ion have been studied by the RI-MP2/L1 quantum-chemical method. Addition of nitrosonium ion to adenine tautomers produces a set of nitrosonium complexes of different types (1??C3??). n-Complexes involving NO⁺ coordination to nitrogen atoms are more energetically favorable than ??-complexes. The global minimum on the potential energy surface is occupied by the complex of 7H-adenine tautomer with nitrosonium ion coordinated at the N³ atom.     

Thermodynamic study on the composition of the gas phase over melts of an aluminum-scandium system

The vapor pressure of the gas phase components over Al-Sc melts was studied. The temperatures and the variation of the enthalpy upon “melt-gas” phase transformations were determined. The simulation was performed in an initial medium of argon at a total pressure of 10⁵ Pa and temperatures T = 1873−4000 K.