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1.
C. Rochester A. Sartor G. Pruessner A. A. Kornyshev 《Russian Journal of Electrochemistry》2017,53(10):1165-1170
We develop a statistical mechanical theory of charge storage in quasi-single-file ionophilic nanopores with pure room temperature ionic liquid cations and anions of different size. The theory is mapped to an extension of the Ising model exploited earlier for the case of cations and anions of the same size. We calculate the differential capacitance and the stored energy density per unit surface area of the pore. Both show asymmetry in the dependence on electrode potential with respect to the potential of zero charge, related to the difference in the size of the ions, which will be interesting to investigate experimentally. It also approves the increase of charge storage capacity via obstructed charging, which in these systems emerges for charging nanopores with smaller ions. 相似文献
2.
Ruoyu Hong * Jianmin Ding Guoliang Zheng College of Chemistry Chemical Engineering Soochow University Suzhou P. R. China Institute of Process Engineering Chinese Academy of Sciences Beijing P. R. China IBM HYDA/- C Highway North Rochester MN USA *Author to whom correspondence should be addressed. E-mail: rhong@suda.edu.cn 《中国颗粒学报》2004,2(5):207-214
1. Introduction1.1 Silica nanoparticles and synthesis methods Silica (SiO2) nanoparticles are widely used in industry asan active filler for polymer reinforcement, a rheologicaladditive in fluids, a free flow agent in powders, and anagent for chemical mechanical polishing during IC (inte-grated circuit) fabrication (Sniegowski & de Boer, 2000).Silica powder is also used for producing silicon carbide(Koc & Cattamanchi, 1998) or opaque silica aerosols (Leeet al., 1995). Many methods can … 相似文献
3.
In this letter, we solve three-dimensional time-dependent Newton equations for atoms interacting with a ten-cycle elliptically polarized laser pulse. The ionized electron momentum distributions show a tilt angle between the distribution density peak and the main polarization axis. The tilt angle’s behavior changes with an increasing laser intensity. We show that this behavior change is directly related to the release time of the electron from the atom. 相似文献
4.
John D. Roehling Christopher W. Rochester Hyun Wook Ro Peng Wang Jaroslaw Majewski K. Joost Batenburg Ilke Arslan Dean M. Delongchamp Adam J. Moulé 《Journal of Polymer Science.Polymer Physics》2014,52(19):1291-1300
The morphology in mixed bulk‐heterojunction films are compared using three different quantitative measurement techniques. We compare the vertical composition changes using high‐angle annular dark‐field scanning transmission electron microscopy with electron tomography and neutron and x‐ray reflectometry. The three measurement techniques yield qualitatively comparable vertical concentration measurements. The presence of a metal cathode during thermal annealing is observed to alter the fullerene concentration throughout the thickness of the film for all measurements. However, the absolute vertical concentration of fullerene is quantitatively different for the three measurements. The origin of the quantitative measurement differences is discussed. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 1291–1300 相似文献
5.
M. Bott-Bodenhausen D. O. Caldwell C. W. Fabjan C. R. Gruhn L. S. Peak L. S. Rochester F. Sauli U. Stierlin R. Tirler B. Winstein D. Zahniser 《Physics letters. [Part B]》1972,40(6):693-698
No quark candidates have been seen among 0.6 × 109 charged particles at the ISR. The corresponding cross-section limit for charge
for quark masses up to 22(13) GeV, assuming PT = 0.4 GeV/c. 相似文献
6.
W.B. Atwood E.D. Bloom R.L.A. Cottrell H. DeStaebler M. Mestayer C.Y. Prescott L.S. Rochester S. Stein R.E. Taylor D. Trines 《Physics letters. [Part B]》1976,64(4):479-482
Inelastic electron scattering cross sections have been measured for four-momentum transfers between 4.1 GeV2 and 30.5 GeV2. At the large scattering angles of this experiment, the dominant contribution to the cross section comes from the W1 structure function. In the conventional scaling variables, x and x′, this structure function does not exhibit scaling behavior, and at fixed x or x′ it is found to decrease with increasing four-momentum transfer. 相似文献
7.
Dines TJ MacGregor LD Rochester CH 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(13):3205-3217
The adsorption of 2-chloropyridine on SiO(2), TiO(2), ZrO(2), SiO(2)-Al(2)O(3) and H-mordenite has been studied by IR spectroscopy. The different modes of interaction with oxide surfaces, i.e. hydrogen-bonding and adsorption at Br?nsted or Lewis acid sites, was modelled by ab initio calculations at the B3LYP/DZ+(d) level. Adsorption on SiO(2) results in hydrogen bonding to surface hydroxyl groups, whereas the spectra obtained following adsorption on TiO(2) and ZrO(2) display evidence for electron transfer at Lewis acidic surface sites. Protonation of 2-chloropyridine at Br?nsted acidic sites was detected only for adsorption on SiO(2)-Al(2)O(3) and H-mordenite, indicating the presence of Br?nsted acidic sites on these oxide surfaces with pK(a) values =0.70. IR studies of 2-chloropyridine adsorption can provide useful information regarding the nature of surface acidity on oxides which is complementary to that obtained from other probe molecules such as NHs and pyridine. 相似文献
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9.
George D. Rochester 《Zeitschrift für Physik A Hadrons and Nuclei》1936,101(11-12):769-784
10.
M. G. Rochester 《Journal of Elasticity》2010,98(1):111-114
The proof that being irrotational/solenoidal is sufficient for a displacement field in a homogeneous isotropic elastic solid to be propagated as a P/S wave is utterly familiar. Because
a proof of the necessity of these conditions seems not to be given in standard texts, we here present a simple argument that this is the case. 相似文献