Stability and control of radial deployment of electric solar wind sail

Nonlinear Dynamics - The paper studies the stability and control of radial deployment of an electric solar wind sail with the consideration of high-order modes of elastic tethers. The electric...     

Palladium-catalyzed cycloaromatization polymerization of enediynes

Bergman cyclization has shown great promise in constructing conjugated polymers.However,the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers.To this end,the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work,by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes.According to the nuclear magnetic resonance (NMR),Fourier transform infrared (FTIR),ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis,the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(Ⅱ) complexes,giving structurally regulated conjugated polymers in high yields.     

CdS and Cd carboxylate nanoclusters dispersed in polymer matrix produced by a freeze drying method

Cadmium sulfide (CdS) nanoclusters were prepared by a freeze drying method from two types of cadmium carboxylates. One was cadmium methacrylates that were part of poly(methyl methacrylate) (PMMA) ionomer. The other was cadmium acetates that were dispersed in PMMA. X-ray diffraction was mainly used to study the formation and the size of nanoclusters. The size of CdS made from the ionomer was 0.9 nm, whereas that from the composite of cadmium acetate and PMMA was 2 nm. This was consistent with the size difference of the precursors of CdS: i.e., Cd carboxylate nanoclusters (ionic aggregates) were smaller in the ionomer than in the PMMA mixture, because ionic groups in the ionomer were constrained due to their connectivity to backbone chains and thus forming smaller ionic aggregates. Once stabilized, however, CdS nanocluster sizes were unchanged despite thermal treatments at up to 220 °C for 24 h for both systems. Structural transformations from a freeze dried cadmium carboxylate powder, to a CdS-containing powder, and to a heat-treated CdS-containing sample are speculated for both types of systems.     

点阵绝对相位彩色多频光栅傅里叶变换轮廓术

提出一种将三角法测距与多频光栅相结合的方法,充分利用数字投影的RGB通道,将多频光栅与点阵同时投影在物体表面,综合控制受高度调制的相位信息的提取,最终获取物体的三维形貌。仿真结果显示,在高度跳变使高频光栅位移达102量级个周期时,可以准确还原原始形貌。通过实验验证,本方法能够同时复原169mm的陡峭高度跳变以及3mm的微小细节,提高了传统双频光栅的性能,具有处理较大截断面和保证细节部分的测量能力,较好地改善了傅里叶变换轮廓术(FTP)的应用性能。     

电泳中介微分析法测定超氧化物歧化酶

基于超氧化物歧化酶(SOD)对邻苯三酚自氧化的抑制作用和电泳中介微分析(EMMA)技术建立了一种测定SOD的新方法。采用“三明治”式不同pH缓冲液部分填充法,有利于邻苯三酚的自氧化反应,便于观察SOD的抑制作用,有利于反应产物与反应物的分离。对溶液填充模式、反应条件等实验参数进行了优化。在最优条件下,邻苯三酚自氧化反应的抑制率I与SOD浓度C在1.00×102~6.00×102μg/L范围内呈良好的线性关系,回归方程为:I(%)=0.0895C(μg/L) 17.633(r=0.9973)。     

Decoupling correlated and uncorrelated parametric uncertainty contributions for nonlinear models

For models with correlated parameters, the amount of uncertainty (generally measured by variance) in a model output contributed by a specific parameter encompasses two components: (1) the uncertainty contributed by the variations (used to represent uncertainty in the parameter) correlated with other parameters; and (2) the uncertainty contributed by the variations unique to the parameter of interest (i.e., uncorrelated variations or variations that cannot be explained by any other parameters in the model). A regression-based method has been proposed previously by Xu and Gertner (2008) [1] to decouple the correlated and uncorrelated contributions to uncertainties in model outputs by each parameter for linear models. Based on a modified version of the popular Fourier Amplitude Sensitivity Test (FAST), this paper develops a general approach for the quantification of the correlated and uncorrelated parametric uncertainty contributions in linear, nonlinear and non-monotonic models with linear or nonlinear dependence among parameters. The decoupling of correlated and uncorrelated contributions can help us determine if the uncertainty contributed by a specific parameter results from the uncertainty in itself or from its correlations with other parameters. Thus, this decoupling can be very useful in improving the understanding our modeled systems.     

电泳中介微分析法测定铁(Ⅱ)和铜(Ⅱ)

利用电泳中介微分析通过与邻菲罗啉的络合反应完成了对Fe2+与Cu2+的同时测定。在压差作用下,淌度较小的邻菲罗啉在金属离子区带之前首先进样,加高电压后,两区带电泳在磷酸缓冲液中 (pH=4. 5)混合、反应形成络合物并实现电泳分离。研究了缓冲液pH、试剂和样品区带长度对分离效果的影响。对于Fe2+与Cu2+两离子,方法的检出限(S/N=3)分别为 1. 6和 11μmol/L;线性范围分别为 5. 0×10-6 ~3. 0×10-4 mol/L(r=0. 9979)和 8. 0×10-5 ~3. 0×10-4 mol/L(r=0. 9996)。采用标准矿样验证了测定Fe2+的可行性。     

新型吡唑并[3,4-d]嘧啶-4-酮类衍生物的结构表征和镇痛活性

本文以2-氰基-3-乙氧基丙烯酸乙酯与3,4-二甲基苯肼为原料,通过多步反应合成了三种新型吡唑并[3,4-d]嘧啶-4-酮类衍生物（A~C）,通过核磁共振（NMR,包括¹H NMR、¹³C NMR）和液相色谱-质谱联用（LC-MS）技术表征确证了其结构,并完整归属了三种化合物的¹H NMR数据．对所合成的化合物1-(3,4-二甲基苯基)-6-甲基-5-[3-(哌啶-1-基)丙氧基]-1,5-二氢-4H-吡唑并[3,4-d]嘧啶-4-酮（A）,通过小鼠脑部质谱成像和福尔马林实验进行了初步的体内镇痛活性评价,我们发现化合物A能透过血脑屏障,并产生显著且剂量依赖的镇痛活性．本研究为以吡唑并[3,4-d]嘧啶-4-酮为骨架的镇痛药物的研发提供了结构和体内活性的基础研究数据．     

流动注射原子吸收光谱法测定高纯水合锑酸钠中微量钾

本文提出了一种流动注射原子吸收光谱法测定高纯水合锑酸钠中钾的方法，优化了仪器参数，考察了几种可能的干扰成分如Ｎａ＾＋、Ｓｂ（Ｖ）、酒石酸等，并提出了消除干扰的方法。结果表明通过在样品和标准液中加入一定量的Ｎａ＾＋后，匹配二者基体可以应用标准曲线法校正，方法的精密度（ＲＳＤ）为１．５％，回收率为９８．６％。     

The Mediated Electrochemical Method for Rapid Fermentation Ability Assessment

The mediated electrochemical method characterized by the combinational utilization of two double mediator systems was proposed to assess the fermentation efficiency of three yeasts. The mediator systems selected were the menadione/ferricyanide system and the 2,6‐dichlorophenolindophenol (DCPIP)/ferricyanide system. Both the electrochemical responses and succinate dehydrogenase assay suggested that the menadione/ferricyanide system made the yeasts switch to anaerobic respiration and, the DCPIP/ferricyanide system let the yeasts remain in theirs fermentative mode. The ethanol yields (g ethanol/g glucose) and the R_D/R_M (R_D and R_M refer to the electrochemical response from the menadione/ferricyanide system and the DCPIP/ferricyanide system, respectively) values are 0.47 and 0.38, 0.24 and 0.75, 0.23 and 0.81, respectively, for Saccharomyces cerevisiae, Pachysolen tannophilus and Pichia stipitis. The results showed that there was a negative correlation between the ethanol yields and the R_D/R_M values of the three yeasts, which showed the feasibility of the mediated electrochemical method in rapid fermentation ability assay.