排序方式: 共有11条查询结果,搜索用时 15 毫秒
1.
Gubanova G. N. Timpu D. Cristea M. Kononova S. V. Korytkova E. N. Sapegin D. A. Saprykina N. N. Volkov A. Ya. Klechkovskaya V. V. 《Crystallography Reports》2021,66(7):1185-1199
Crystallography Reports - A new polymer-inorganic nanocomposite composed of fibrous Na–Mg triple chain hydrosilicate with a poly(amide-imide) matrix was developed. Its structure, morphology,... 相似文献
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Alexander Safrygin Dmitry Darin Alexei Lukin Anna Bakholdina Alexander Sapegin Mikhail Krasavin 《Tetrahedron letters》2019,60(11):777-779
The versatile conversion of propargylic amides to the respective 2-substituted 5-methyloxazoles was efficiently catalyzed by Zn(OTf)2 (5?mol%) under microwave irradiation in toluene. The method was applicable to a wide range of aliphatic, aromatic and heteroaromatic propargylic amides and thus represents a useful method which is complementary to the existing metal-catalyzed protocols, considering the ready availability of Zn(OTf)2. 相似文献
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N. V. Afanas’eva G. N. Gubanova K. A. Romashkova D. A. Sapegin S. V. Kononova 《Polymer Science Series A》2016,58(6):956-967
Features of the relaxation behavior of an aromatic polyamide-imide and a composite with nanotubes of magnesium silicate with the structure of chrysotile have been studied by dynamic mechanical analysis, dielectric spectroscopy, and differential scanning calorimetry. Two secondary relaxation (β1 and β2) transitions have been found, the activation energies of these processes have been determined, and the solvent effect on the cooperativeness degree has been studied. Changes in the value of the apparent activation energy of the β1-process caused by the subsequent heating of polymeric and composite samples have been analyzed according to the Starkweather procedure. It has been shown that, as the solvent is released from the polyamide-imide film, the polymer exhibits increasing local mobility, which are predetermined by the structure of the molecular unit. Using the GAMESS software, we have assumed the most probable dimer conformations that correspond to two repeating units of the polyamide-imide molecule. 相似文献
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We have developed an expeditious and atom-economic synthesis of lead-like, privileged 4,5-dihydropyrazolo[1,5-a]pyrazin-6-ones, which is based on Sonogashira coupling and a two-step condensation with hydrazine hydrate leading to two ring-forming events, with full control over the two elements of diversity present. 相似文献
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Sergey Grintsevich Alexander Sapegin Elena Reutskaya Mikhail Krasavin 《Tetrahedron letters》2019,60(1):20-22
The tricyclic ring system of the antiviral drug nevirapine has been employed to test the workability of the hydrated imidazoline ring expansion (HIRE) reaction which was previously exemplified for [1.4]oxazepine and [1.4]thiazepine counterparts. The imidazoline nucleus was grafted onto the lactam moiety of nevirapine in two high-yielding steps. Subsequent N-alkylation and the HIRE reaction proceeded as envisioned and delivered rare ring-expanded diarene-fused 1,4,7-triazecines with a diversity of alkyl substituents at the lactam nitrogen atom. These findings extend the scope of the HIRE reaction to the medicinally prominent [1.4]diazepine chemical space. 相似文献
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Russian Journal of Organic Chemistry - 相似文献
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Alexander V. Sapegin Stanislav A. Kalinin Alexey V. Smirnov Mikhail V. Dorogov Mikhail Krasavin 《Tetrahedron》2014
A streamlined synthetic methodology towards novel tetracyclic 1,4-oxazepines from readily available precursors is described. The compounds, designed as more soluble version of the earlier described, poorly soluble dibenzo[b,f][1,4]oxazepines, were obtained in high yields and as a single regioisomer as a result of three tandem chemical events—nucleophilic aromatic substitution, Smiles rearrangement and denitrocyclization. 相似文献
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Sapegin A. V. Khristolyubova T. A. Smirnov A. V. Dorogov M. V. Ivashchenko A. V. 《Russian Chemical Bulletin》2009,58(7):1542-1545
A new approach to the synthesis of N-substituted pyrido[3,2-b][1,4]benzothiazepin-10(11H)-one derivatives from 2-chloro-3-nitropyridine and thiosalicylic acid using denitrocyclisation reaction for the tricycle-system
formation is proposed. 相似文献