堵塞效应与“全同带”的微观机制

利用处理推转壳模型的改进了的粒子数守恒方法(严格计及堵塞效应),对原子核的转动惯量进行了计算,计算中无任何自由参数,所得转动惯量(包括¹⁷⁰Yb,¹⁷¹Lu¹⁷¹Yb各转动带)及其奇偶差,与实验非常符合,转动惯量的奇偶差灵敏地依赖于被堵塞的能级位置及其对Coriolis力的响应。     

催化增强化学蒸气沉积法在聚酰亚胺上沉积钯-铂合金薄层

以N₂，O₂作载气，通过催化增强化学蒸气沉积(CECVD)分别制得在聚酰亚胺上的金属铂、钯及其合金薄层。铂、钯配合物的共同沉积可生成Pt-Pd合金薄膜。在Pd-Pt合金的沉积过程中，Pd/Pt的原子数比率随共同沉积的条件改变而变化。O₂为载气、300 ℃条件下,用Pd(η³-allyl)(hfac)和Pt(COD)Me₂作前驱体共沉积制备Pd-Pt合金，得到含Pd 37.2%，Pt 62.8%且不     

A sensitive sensor with a double U-shaped ring-based metamaterial

We design a double U-shaped ring-based metamaterial, which has a good capability of the realization of sense of refractive indexes. The metamaterial consists of two regularly spaced parallel arrays of U-shaped rings with 90° rotation embedded in a medium, in the top of which an array of holes are dug for sensing unknown materials. Our simulations demonstrate that the structure can recognize subtle changes in refractive indexes of the unknown materials by special resonance frequencies, and it can thus be regarded as a highly sensitive sensor. Furthermore, it could also be integrated into other electronic devices because of its tiny size.     

宽光谱平像场全息凹面光栅的优化研究

基于凹面光栅的几何理论,推导了子午、弧矢聚焦曲线的数学表达式和全息平像场凹面光栅制作参数的计算关系式.提出了一种新的在整个使用波长范围内同时消除子午和弧矢像差的最佳优化设计方法.这种方法不同于以光线追迹技术为基础的标准光学设计软件如CODEV或ZEMAX的优化设计方法,而是从数学表达式出发,采用光栅优化因子,对凹面光栅的子午聚焦曲线和弧矢聚焦曲线进行拟合,从理论上找到最佳的能够使子午和弧矢像差同时趋于零的像平面,然后再根据拟合参数设计制作光栅.用Matlab软件解决了子午聚焦曲线超越方程无法解的困难;讨论了不同光栅常数和入射角度时对两聚焦曲线拟合程度的影响.提出了在宽光谱使用条件下,可以通过减小入射角度和光栅刻线数来提高光谱像质.     

Microscopic Mechanism of the Variation of the Ground Band Moments of Inertia with Neutron Numbers in 166—176Yb

Using the particle-number-conserving (PNC) method,the microscopic mechanism of the variation of the ground band moments of inertia with neutron numbers in ^166—176Yb is investigated in the cranked shell model (CSM).The K-structure and seniority structure of the PNC CSM wave function are analyzed carefully.The distribution of the low-lying high-j intruder pair-broken (v=2)K^π=1⁺ configurationsplays a crucial role for the magnitude of the ground band moments of inertia.     

对TiO2亲水特性有决定性影响的物理因素

影响TiO2薄膜亲水性的三种物理特性有——表面形貌、表面粗糙度、表面颗粒大小。本文中使用电子束蒸发法制备TiO2薄膜,使用AFM、静态接触角检测对不同厚度的TiO2薄膜的物理特性以及亲水特性进行了分析。结果显示,相较于薄膜表面的颗粒尺寸及表面粗糙度,薄膜表面形貌对TiO2薄膜亲水特性有着更重要的影响。     

配合物[Cd(C_9H_8O_3N)_2(2,2′-bipy)(H_2O)]_2·(H_2O)_3的合成、结构及荧光和电化学性质(英文)

以对乙酰氨基苯甲酸和2,2′-联吡啶为配体合成了一个新配合物[Cd(C9H8O3N)2(2,2′-bipy)(H2O)]2·(H2O)3。该配合物晶体属三斜晶系,空间群P1,晶胞参数:a=1.2559(3)nm,b=1.5068(3)nm,c=1.6507(3)nm,α=112.14(3)°,β=101.83(3)°,γ=93.84(3)°,V=2.7959(10)nm3,Dc=1.592g·cm-3,Z=4,μ(MoKα)=0.840mm-1,F(000)=1364,最终偏离因子R1=0.0276,wR2=0.0683。标题配合物的不对称单元由2个独立的单核结构Cd(C9H8O3N)2(2,2′-bipy)(H2O)和3个晶格水分子组成。中心镉髤离子处于六配位的变形八面体环境中。本工作测定了配合物的荧光和电化学性能。     

Hydrothermal syntheses,crystal structures and properties of two cobalt(II) complexes constructed from 5-(isonicotinamido)isophthalic acid

Two Co(II) complexes, [Co(INAIP)(dib)]·4H₂O and [Co(INAIP)(phen)(H₂O)]·H₂O have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H₂INAIP) and CoSO₄·7H₂O, as well as N-donor ligands, namely 1,4-di(1-imidazolyl)benzene (dib) and 1,10-phenanthroline (phen) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that [Co(INAIP)(dib)]·4H₂O has a two-dimensional (2D) double-layer network structure with a (4, 4) topology, while [Co(INAIP)(phen)(H₂O)]·H₂O displays a one-dimensional chain structure, extending to a 2D net through the π–π interactions. In addition, the photoluminescence and degradation of methyl orange in a Fenton-like process using the complexes as catalysts were investigated.     

镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质

The complex {[Cd₂(C₉H₈O₃N)₂(CH₃COO)₂(4,4′-bipy)₂]·(4,4′-bipy)·(H₂O)₄}_n with 4-acetamidobenzoic acid and 4,4′-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals, forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4′-bipy molecules and the complex molecule forms an one-dimensional double-chain structure. The luminescent properties of the complex were studied. CCDC: 734878.     

间氯苯甲酸构筑的双核铽(Ⅲ)配合物的水热合成、晶体结构及荧光性质(英文)

<正>The complex[Tb_2(ClC_6H_4COO)_6(2,2'-bipy)_2]·(ClC_6H_4COOH)·(H_2O)with m-chlorobenzoic acid and 2,2'-bipy -ridine as ligands has been synthesized by means of hydrothermal way.Crystal data for this complex are as follows: monoclinic,space group P1,a=1.143 9(4) nm,6=1.211 6(4) nm,c=1.419 9(5) nm,α= 103.600(6)°,β=95.382(3)°,γ= 99.506(4)°,V=1.8684(10)nm~3,D_c=1.692 g·cm~(-3),Z=2,μ(Mo Kα)=2.236 mm~(-1),F(000)=943,final discrepancy factors R_1=0.052 0,wR_2=0.118 6.In the crystal,two neighboring Tb(Ⅲ) ions are bridged by four m-chlorobenzoic acid anions,and their end positions coordinate with one 2,2'-bipyridine molecule and one m-chlorobenzoic acid anions, respectively,giving a binuclear cage structure,of which the spacing between Tb(Ⅲ)…Tb(Ⅲ) is 0.408 1 nm.Each Tb(Ⅲ) ion coordinates with two nitrogen atoms and six oxygen atoms,giving an eight-coordinated distorted square antiprism geometry.The luminescent property of the complex is also studied.