首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2816篇
  免费   410篇
  国内免费   281篇
化学   1914篇
晶体学   37篇
力学   218篇
综合类   25篇
数学   308篇
物理学   1005篇
  2024年   2篇
  2023年   50篇
  2022年   58篇
  2021年   88篇
  2020年   100篇
  2019年   93篇
  2018年   95篇
  2017年   81篇
  2016年   123篇
  2015年   161篇
  2014年   179篇
  2013年   210篇
  2012年   260篇
  2011年   279篇
  2010年   176篇
  2009年   196篇
  2008年   188篇
  2007年   181篇
  2006年   143篇
  2005年   119篇
  2004年   72篇
  2003年   61篇
  2002年   58篇
  2001年   43篇
  2000年   49篇
  1999年   64篇
  1998年   48篇
  1997年   42篇
  1996年   53篇
  1995年   36篇
  1994年   29篇
  1993年   19篇
  1992年   15篇
  1991年   21篇
  1990年   31篇
  1989年   18篇
  1988年   14篇
  1987年   17篇
  1986年   11篇
  1985年   5篇
  1981年   2篇
  1979年   2篇
  1976年   2篇
  1942年   1篇
  1941年   1篇
  1936年   4篇
  1930年   2篇
  1929年   1篇
  1927年   1篇
  1923年   1篇
排序方式: 共有3507条查询结果,搜索用时 218 毫秒
1.
Yang  Ruizhi  Nie  Chenxuan  Jin  Dan 《Nonlinear dynamics》2022,110(1):879-900
Nonlinear Dynamics - In this paper, we study a delayed diffusive predator–prey model with nonlocal competition in prey and habitat complexity. The local stability of coexisting equilibrium is...  相似文献   
2.
Lin  Shuyi  Zhang  Weidong 《Nonlinear dynamics》2018,93(4):2273-2282
Nonlinear Dynamics - This paper presents a sliding mode control scheme for chaotic systems. Finite time stability of the system states is realized by implementing the proposed controller, which is...  相似文献   
3.
In this study, we investigate the modulation of energy band in 3D self-assembled nanomembranes containing GaAs/Al0.26Ga0.74As quantum wells (QWs). Photoluminescence (PL) characterizations demonstrate that the self-assembled structures have different optical transition properties and the modulation of the energy band is thus realized. Detailed spectral analyses disclose that the small strain change in structures with different curvatures cannot cause remarkable change in energy bands in Al0.26Ga0.74As layer. On the other hand, the optical transitions of GaAs QW layer is influenced by the strain evolution in term of light emission intensity. We also find the first order Stark effect in rolled-up nanomembrane with diameter of 150 μm, which is closely connected with the coupling effect between the deformation potential and the piezoelectric potential. Our work may pave a way for the fabrication of high performance rolled-QW infrared photo-detectors.  相似文献   
4.
A highly selective and efficient LC–MS/MS method was developed to determine the plasma concentration of magnolol, hesperidin, neohesperidin and geniposide following oral administration of Zhi‐Zi‐Hou‐Po decoction in normal and depressed rats. Plasma samples were pretreated by protein precipitation with methanol. Chromatographic separation was performed on an XTerra® MS C18 column using a gradient elution with a mobile phase composed of acetonitrile–0.1% aqueous formic acid. The proposed method was validated to be specific, accurate and precise for the analytes determination in plasma samples. The calibration curves displayed good linearity over definite concentration ranges for the analytes. The intra‐ and inter‐day precision of the proposed method at three different levels were all within <11.13% and the relative errors ranged from ?8.46 to 8.93%. The recovery of the four compounds ranged from 82.72 to 89.08% and no apparent matrix effect was observed during sample analysis. After full validation, the established method was successfully applied for comparing the pharmacokinetics of four components between normal and depressed rats. The results showed that the AUC and Cmax of four analytes in depressed rats were significantly different from those in normal rats and might provide helpful information to guide the clinical use of Zhi‐Zi‐Hou‐Po to treat depression.  相似文献   
5.
聂红 《物理化学学报》2022,38(8):2012005-11
<正>绿色化工技术是实现化工行业可持续发展的关键~1。作为一种先进高效的低碳能源转化技术,化学链工艺在节能和减排等方面具有诸多优势~2。在化学链工艺中,氧化还原催化剂作为氧载体,实现不同反应器之间的晶格氧和热量传递。载氧体的晶格氧释放动力学是决定其反应性能的关键因素~3。ABO3钙钛矿型复合金属氧化物由于其优良的结构循环稳定性和氧离子迁移能力,是一类具有潜在应用价值的催化材料,被广泛研究用于化学链、  相似文献   
6.
We consider the following system with critical exponent in RN:{?Δu=K1(y)u2??1+p2?V(y)up?1vq in RN,?Δv=K2(y)v2??1+q2?V(y)upvq?1 in RN,u,v>0,yRN, where N5, p,q>1 and p+q=2?=2NN?2. Using finite dimensional reduction method, we prove the existence of multi-bump solutions. Their bumps can be placed on arbitrarily many or even infinitely many lattice points in RN. Since p<2 or q<2, we introduce two new norms to avoid singularity.  相似文献   
7.
8.
9.
In this paper,a statistical second-order twoscale(SSOTS) method is developed to simulate the dynamic thcrmo-mechanical performances of the statistically inhomogeneous materials.For this kind of composite material,the random distribution characteristics of particles,including the shape,size,orientation,spatial location,and volume fractions,are all considered.Firstly,the repre.sentation for the microscopic configuration of the statistically inhomogeneous materials is described.Secondly,the SSOTS formulation for the dynamic thermo-mechanical coupled problem is proposed in a constructive way,including the cell problems,effective thermal and mechanical parameters,homogenized problems,and the SSOTS formulas of the temperatures,displacements,heat flux densities and stresses.And then the algorithm procedure corresponding to the SSOTS method is brought forward.The numerical results obtained by using the SSOTS algorithm are compared with those by classical methods.In addition,the thermo-mechanical coupling effect is studied by comparing the results of coupled case with those of uncoupled case.It demonstrates that the coupling effect on the temperatures,heat flux densities,displacements,and stresses is very distinct.The results show that the SSOTS method is valid to predict the dynamic thermo-mechanical coupled performances of statistically inhomogeneous materials.  相似文献   
10.
Based on the lead compound 1 reported in literature, a series of novel BACE1 inhibitors were designed and synthesized, among which compound 11 exhibited a 14-fold improvement in potency over the lead compound 1. This represents a good lead for the discovery of more promising BACE1 inhibitors for the potential treatment of AD.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号