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排序方式: 共有332条查询结果,搜索用时 156 毫秒
1.
Yusuke Tanaka Tomotaka Murayama Dr. Atsuya Muranaka Dr. Eiyu Imai Prof. Dr. Masanobu Uchiyama 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(8):1768-1771
We designed and synthesized a new type of small helical molecule exhibiting intense circularly polarized luminescence (CPL) ( 12H ) by modifying a 20π-electron hemiporphyrazine with a large transition magnetic dipole moment. The hemiporphyrazine ring was opened and one additional pyridine unit was introduced, resulting in an overlap of two pyridine rings. X-ray structure analysis confirmed that 12H and its zinc complex ( 1Zn ) adopt a helical geometry. A racemic mixture of 1Zn was resolved into two enantiomers ((P)- and (M)- 1Zn ), which exhibited CPL with a high luminescence dissymmetry factor (glum) value of ±2.1×10−2. The origin of the large glum value was rationalized by means of DFT calculations. Helical structures could be formed in a diastereoselective manner by covalently attaching chiral units to the skeleton ( 1’2H and 1’Zn ). 1Zn was found to possess chiral recognition ability for amines. 相似文献
2.
Fractal analysis of turbulent premixed flame surface 总被引:3,自引:0,他引:3
The fractal-like character of the laminar flamelet surface in turbulent premixed combustion of lean methane/air mixtures was studied by using the laser tomography technique to visualize the instantaneous flame surface in the two-dimensional section cut by the laser sheet. The fractal analysis of the surface revealed that the surface actually exhibits a self-similarity behavior in a narrow range of scale, and the value of fractal dimension can be defined. The inner cutoff scale was the laminar flame thickness, while the outer cutoff scale was the flame size. The fractal dimension was found to depend on the orientation of the section, and to increase towards downstream. It is suggested that the observed fractal-like character is not directly connected to approach flow turbulence, but should represent certain aspects of the flamelet itself. 相似文献
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4.
Daisuke Saito Dr. Tomohiro Ogawa Dr. Masaki Yoshida Junichi Takayama Dr. Satoshi Hiura Prof. Dr. Akihiro Murayama Dr. Atsushi Kobayashi Prof. Dr. Masako Kato 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(42):18882-18889
A series of assembled PtII complexes comprising N-heterocyclic carbene and cyanide ligands was constructed using different substituent groups, [Pt(CN)2(R-impy)] (R-impyH+=1-alkyl-3-(2-pyridyl)-1H-imidazolium, R=Me ( Pt-Me ), Et ( Pt-Et ), iPr ( Pt- i Pr ), and tBu ( Pt- t Bu )). All the complexes exhibited highly efficient photoluminescence with an emission quantum yield of 0.51–0.81 in the solid state at room temperature, originating from the triplet metal-metal-to-ligand charge transfer (3MMLCT) state. Their emission colors cover the entire visible region from red for Pt-Me to blue for Pt- t Bu . Importantly, Pt- t Bu is the first example that exhibits blue 3MMLCT emission. The 3MMLCT emission was proved and characterized based on the temperature dependences of the crystal structures and emission properties. The wide-range color tuning of luminescence using the 3MMLCT emission presents a new strategy of superfine control of the emission color. 相似文献
5.
Yukiko Kamiya Fuminori Sato Keiji Murayama Atsuji Kodama Susumu Uchiyama Hiroyuki Asanuma 《化学:亚洲杂志》2020,15(8):1266-1271
Serinol nucleic acid (SNA) is a promising candidate for nucleic acid‐based molecular probes and drugs due to its high affinity for RNA. Our previous work revealed that incorporation of 2,6‐diaminpurine (D), which can form three hydrogen bonds with uracil, into SNA increases the melting temperature of SNA‐RNA duplexes. However, D incorporation into short self‐complementary regions of SNA promoted self‐dimerization and hindered hybridization with RNA. Here we synthesized a SNA monomer of 2‐thiouracil (sU), which was expected to inhibit base pairing with D by steric hindrance between sulfur and the amino group. To prepare the SNA containing D and sU in high yield, we customized the protecting groups on D and sU monomers that can be readily deprotected under acidic conditions. Incorporation of D and sU into SNA facilitated stable duplex formation with target RNA by suppressing the self‐hybridization of SNA and increasing the stability of the heteroduplex of SNA and its complementary RNA. Our results have important implications for the development of SNA‐based probes and nucleic acid drugs. 相似文献
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7.
Our recent studies of ferroelectric chiral smectic and super-twisted nematic (ST) multiplexed-matrix liquid-crystal displays (LCDs) and a thin-film-transistor (TFT) active-matrix twisted nematic (TN) LCD are presented, mainly in terms of liquid-crystal material and cell optimization. This is based on a consideration of their electro-optical characteristics. In addition the matrix LCD devices developed through these studies are introduced, including a 12-inch-diagonal video-rate multicolour ferroelectric LCD, a highly multiplexed genuine achromatic ST LCD with a single cell and a 4-inch-diagonal full-colour a-Si TFT-addressed TN LCD for a video display. 相似文献
8.
This paper describes the history and scheme of reference materials and standard solutions for titrimetry in Japan. Titrimetry
is one of the most fundamental and precise methods for determination of a constituent, based on the effective purity of reference
materials in stoichiometric analysis. It has wide-ranging applications based on titrimetric reactions such as neutralization,
redox, chelatometric, and precipitation titration processes, which are used in various analytical fields all over the world.
Japanese Industrial Standards (JIS) have played an important role in establishing a stable supply of reference materials for
titrimetry since the 1950s. There are several reports of preparations and their determination, including coulometric studies,
in order to establish highly reliable reference materials. This paper briefly reviews the schemes and studies of standardization
through the provision of reference materials and standard solutions based on JIS, and several applications in other standards.
Presented at Berm-11, October 2007, Tsukuba, Japan. 相似文献
9.
In this study, a cation-exchange resin (CEX) of the K+-form, i.e., an enhancer resin, is used as a postcolumn conductimetric enhancer in the ion-exclusion chromatography of aliphatic carboxylic acids. The enhancer resin is filled in the switching valve of an ion chromatograph; this valve is usually used as a suppressor valve in ion-exchange chromatography. An aliphatic carboxylic acid (e.g., CH3COOH) separated by a weakly acidic CEX column of the H+-form converts into that of the K+-form (e.g., CH3COOK) by passing through the enhancer resin. In contrast, the background conductivity decreases because a strong acid (e.g., HNO3) with a higher conductimetric response in an eluent converts into a salt (e.g., KNO3) with a lower conductimetric response. Since the pH of the eluent containing the resin enhancer increases from 3.27 to 5.85, the enhancer accelerates the dissociations of analyte acids. Consequently, peak heights and peak areas of aliphatic carboxylic acids (e.g., acetic acid, propionic acid, butyric acid, and valeric acid) with the enhancer resin are 6.3-8.0 times higher and 7.2-9.2 times larger, respectively, than those without the enhancer resin. Calibrations of peak areas for injected analytes are linear in the concentration range of 0.01-1.0 mM. The detection limits (signal-to-noise ratio = 3) range from 0.10 μM to 0.39 μM in this system, as opposed to those in the range of 0.24-7.1 μM in the separation column alone. The developed system is successfully applied to the determination of aliphatic carboxylic acids in a chicken droppings sample. 相似文献
10.