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1.
Zourob M Mohr S Mayes AG Macaskill A Pérez-Moral N Fielden PR Goddard NJ 《Lab on a chip》2006,6(2):296-301
In this study, uniform spherical molecularly imprinted polymer beads were prepared via controlled suspension polymerization in a spiral-shaped microchannel using mineral oil and perfluorocarbon liquid as continuous phases. Monodisperse droplets containing the monomers, template, initiator, and porogenic solvent were introduced into the microchannel, and particles of uniform size were produced by subsequent UV polymerization, quickly and without wasting polymer materials. The droplet/particle size was varied by changing the flow conditions in the microfluidic device. The diameter of the resulting products typically had a coefficient of variation (CV) below 2%. The specific binding sites that were created during the imprinting process were analysed via radioligand binding analysis. The molecularly imprinted microspheres produced in the liquid perfluorocarbon continuous phase had a higher binding capacity compared with the particles produced in the mineral oil continuous phase, though it should be noted that the aim of this study was not to optimize or maximize imprinting performance, but rather to demonstrate broad applicability and compatibility with known MIP production methods. The successful imprinting against a model compound using two very different continuous phases (one requiring a surfactant to stabilize the droplets the other not) demonstrates the generality of this current simple approach. 相似文献
2.
The formation of the 28-membered ring cyclo[(6-amino-6-deoxy-d-galactonic acid)4] by cyclisation of a protected open chain fully hydroxylated nylon 6 linear tetramer in modest yield provides the first example of a new class of carbopeptoid-cyclodextrin. 相似文献
3.
4.
K.R. Hogstrom B.W. Mayes L.Y. Lee J.C. Allred Clark Goodman G.S. Mutchler C.R. Fletcher G.C. Phillips 《Nuclear Physics A》1973,215(3):598-604
Reaction cross sections for 12C(π+, πN)11C at 134, 161, 177, and 200 MeV and for 19F(π+,πN) at 161, 177, and 200 MeV were measured by activation methods. 相似文献
5.
R.D. Felder T.M. Williams G.S. Mutchler I. Duck J. Hudomalj-Gabitzsch M. Furic D. Mann N.D. Gabitzsch J.M. Clement G.C. Phillips T.R. Witten E.V. Hungerford M. Warneke B.W. Mayes L.Y. Lee J.C. Allred 《Nuclear Physics A》1977,280(2):308-324
Neutron-proton final state interactions (FSI) were observed in the deuteron breakup reaction 2H(p, 2p)n-via a kinematically complete experiment at incident proton energies of 585 and 800 MeV. Kinematic conditions were chosen which allowed the final state proton and neutron to have small relative energies; data were taken at four proton c.m. scattering angles at 800 MeV, ranging from 71° to 119° and at 94° and 106° at 585 MeV. The data are analyzed in terms of the Goldberger-Watson formalism for final state interactions, and the individual contributions of the 1S0 and 3S1 np states are determined. The ratio is large, as expected from some reaction models. The ratio of 3S1 (almost elastic) to pd elastic cross sections is in good agreement with FSI analysis. 相似文献
6.
Alt C Anticic T Baatar B Barna D Bartke J Betev L Białkowska H Billmeier A Blume C Boimska B Botje M Bracinik J Bramm R Brun R Buncić P Cerny V Christakoglou P Chvala O Cramer JG Csató P Darmenov N Dimitrov A Dinkelaker P Eckardt V Farantatos G Flierl D Fodor Z Foka P Freund P Friese V Gál J Gaździcki M Georgopoulos G Gładysz E Grebieszkow K Hegyi S Höhne C Kadija K Karev A Kliemant M Kniege S Kolesnikov VI Kollegger T Kornas E Korus R Kowalski M Kraus I Kreps M van Leeuwen M Lévai P Litov L 《Physical review letters》2005,94(19):192301
Results are presented on Omega production in central Pb+Pb collisions at 40 and 158A GeV beam energy. For the first time in heavy ion reactions, rapidity distributions and total yields were measured for the sum Omega(-) + Omega(+) at 40A GeV and for Omega(-) and Omega(+) separately at 158A GeV. The yields are strongly underpredicted by the string-hadronic UrQMD model but agree better with predictions from hadron gas models. 相似文献
7.
Mesoporous carbon catalyst supports are attractive due to their wide chemical stability while potentially increasing mass-transport through and providing a path for larger molecules to access catalytic sites. Herein we report the synthesis of a phosphorylated mesoporous carbon solid-acid catalyst characterized by NH(3)-TPD and isopropanol dehydration. 相似文献
8.
Gates AJ Kemp GL To CY Mann J Marritt SJ Mayes AG Richardson DJ Butt JN 《Physical chemistry chemical physics : PCCP》2011,13(17):7720-7731
In protein film electrochemistry a redox protein of interest is studied as an electroactive film adsorbed on an electrode surface. For redox enzymes this configuration allows quantification of the relationship between catalytic activity and electrochemical potential. Considered as a function of enzyme environment, i.e., pH, substrate concentration etc., the activity-potential relationship provides a fingerprint of activity unique to a given enzyme. Here we consider the nature of the activity-potential relationship in terms of both its cellular impact and its origin in the structure and catalytic mechanism of the enzyme. We propose that the activity-potential relationship of a redox enzyme is tuned to facilitate cellular function and highlight opportunities to test this hypothesis through computational, structural, biochemical and cellular studies. 相似文献
9.
Hardy JC Iacob VE Sanchez-Vega M Neilson RG Azhari A Gagliardi CA Mayes VE Tang X Trache L Tribble RE 《Physical review letters》2003,91(8):082501
The half-life, 3.8755(12) s, and superallowed branching ratio, 0.5315(12), for 22Mg beta decay have been measured with high precision. The latter depended on gamma-ray intensities being measured with an HPGe detector calibrated for relative efficiencies to an unprecedented 0.15%. Previous precise measurements of 0+ --> 0+ transitions have been restricted to the nine that populate stable daughter nuclei. No more such cases exist, and any improvement in a critical Cabibbo-Kobayashi-Maskawa unitarity test must depend on precise measurements of more exotic nuclei. With this branching-ratio measurement, we show those to be possible for T(z)=-1 parents. We obtain a corrected Ft value of 3071(9) s, in good agreement with expectations. 相似文献
10.