全文获取类型
收费全文 | 244篇 |
免费 | 8篇 |
国内免费 | 3篇 |
专业分类
化学 | 139篇 |
力学 | 4篇 |
数学 | 83篇 |
物理学 | 29篇 |
出版年
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 7篇 |
2008年 | 4篇 |
2007年 | 11篇 |
2006年 | 5篇 |
2005年 | 8篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 4篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1997年 | 3篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1990年 | 2篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 11篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 8篇 |
1973年 | 2篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1965年 | 2篇 |
1963年 | 2篇 |
1961年 | 2篇 |
1960年 | 3篇 |
1959年 | 6篇 |
1958年 | 3篇 |
1957年 | 3篇 |
1914年 | 2篇 |
1913年 | 2篇 |
1901年 | 2篇 |
排序方式: 共有255条查询结果,搜索用时 15 毫秒
1.
Amira Mahmoud Mosaab Echabaane Karim Omri Julien Boudon Lucien Saviot Nadine Millot Rafik Ben Chaabane 《Molecules (Basel, Switzerland)》2021,26(4)
Copper-doped zinc oxide nanoparticles (NPs) CuxZn1−xO (x = 0, 0.01, 0.02, 0.03, and 0.04) were synthesized via a sol-gel process and used as an active electrode material to fabricate a non-enzymatic electrochemical sensor for the detection of glucose. Their structure, composition, and chemical properties were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) and Raman spectroscopies, and zeta potential measurements. The electrochemical characterization of the sensors was studied using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). Cu doping was shown to improve the electrocatalytic activity for the oxidation of glucose, which resulted from the accelerated electron transfer and greatly improved electrochemical conductivity. The experimental conditions for the detection of glucose were optimized: a linear dependence between the glucose concentration and current intensity was established in the range from 1 nM to 100 μM with a limit of detection of 0.7 nM. The proposed sensor exhibited high selectivity for glucose in the presence of various interfering species. The developed sensor was also successfully tested for the detection of glucose in human serum samples. 相似文献
2.
Lucien Eisenburger Prof. Dr. Oliver Oeckler Prof. Dr. Wolfgang Schnick 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(13):4461-4465
Tetrahedra-based nitrides with network structures have emerged as versatile materials with a broad spectrum of properties and applications. Both nitridosilicates and nitridophosphates are well-known examples of such nitrides that upon doping with Eu2+ exhibit intriguing luminescence properties, which makes them attractive for applications. Nitridosilicates and nitridophosphates show manifold structural variability; however, no mixed nitridosilicatephosphates except SiPN3 and SiP2N4NH have been described so far. The compounds AESiP3N7 (AE=Sr, Ba) were synthesized by a high-pressure high-temperature approach using the multianvil technique (8 GPa, 1400–1700 °C) starting from the respective alkaline earth azides and the binary nitrides P3N5 and Si3N4. The latter were activated by NH4F, probably acting as a mineralizing agent. SrSiP3N7 and BaSiP3N7 were obtained as single crystals. They crystallized in the barylite-1O (M=Sr) and barylite-2O structure types (M=Ba), respectively, with P and Si being occupationally disordered. Cation disorder was further supported by solid-state NMR spectroscopy and energy-dispersive X-ray spectroscopy (EDX) mapping of BaSiP3N7 with atomic resolution. Upon doping with Eu2+, both compounds showed blue emission under UV excitation. 相似文献
3.
Flow-induced residual stresses that arise during the injection moulding of amorphous thermoplastic polymers are calculated in both the filling and post-filling stage. To achieve this a compressible version of the Leonov model is employed. Two techniques are investigated. First a direct approach is used where the pressure problem is formulated using the viscoelastic material model. Secondly, generalized Newtonian material behaviour is assumed, and the resulting flow kinematics is used to calculate normal stresses employing the compressible Leonov model. The latter technique gives comparable results, while reducing the computational cost significantly. 相似文献
4.
The Sequential dialkylation of dimethylaminoacetonitrile with first methallylchloride and then prenylbromide is performed at room temperature using K2CO3 in DMF. Subsequent hudrolysis and isomerisation offord artemisia ketone in 77% overall yield. 相似文献
5.
The reaction of chloroacetyl chloride and triethylamine with a chiral imine derived from the combination of methyl glyoxylate and protected L-threonine gave two optically active α-amino acid derivatives with a cis-substituted β-lactam skeleton in a 72:28 ratio. The major product is obtained in 59% yield by simple crystallisation. 相似文献
6.
The ferroelectric compounds Pb2Na1−xLaxNb5−xFexO15 and Pb0.5(5−x)LaxNb5−xFexO15 (0≤x≤1) with the tungsten bronze type structure have been investigated using Raman spectroscopy. The evolution of the spectra as a function of composition at room temperature is reported. In the frequency range 200-1000 cm−1 three main A1 phonons around 240 (υ1), 630 (υ2) and 816 (υ3) cm−1 were observed. The broadening of the Raman lines for high values of x originates from a significant structural disorder. This is in good agreement with the relaxor character of these compositions. The lowest-frequency part of the spectra, below 180 cm−1, reveals a structural change in the studied solid solutions. The behaviour of the Raman shift of the υ1 mode confirms that in Pb2Na1−xLaxNb5−xFexO15, a clear anomaly occurs in the vicinity of x=0.4. 相似文献
7.
Mouhssin Oufir Nadine Schulz Patan Shaik Sha Vallikhan Eva Wilhelm Kornel Burg Jean-Francois Hausman Lucien Hoffmann Cedric Guignard 《Journal of chromatography. A》2009,1216(7):1094-1099
A mass spectrometer was coupled to high-performance ligand-exchange liquid chromatography (HPLEC) for simultaneous analysis of stress associated solutes such as proline, hydroxyproline, methylproline, glycine betaine and trigonelline extracted from leaves of drought stressed oaks and an internal standard namely N-acetylproline. Methanol/chloroform/water extracts were analyzed using an Aminex HPX-87C column and specifically quantified by the positive ion mode of an electrospray ionisation-mass spectrometry (ESI-MS) in single ion monitoring (SIM) mode. The recovery of N-acetyl proline added to oak leaf extracts ranged from 85.2 to 122.1% for an intra-day study. Standard calibration curves showed good linearity in the measured range from 0.3125 to 10 μmol L−1 with the lowest correlation coefficient of 0.99961 for trigonelline. The advantages of this alternative procedure, compared to previously published methods using fluorescence or amperometric detections, are the simultaneous and direct detection of osmoprotectants in a single chromatographic run, a minimal sample preparation, a good specificity and reduced limits of quantification, ranging from 0.1 to 0.6 μmol L−1. Fifty-six days of water deficit exposure resulted in increased foliar free proline levels (2.4-fold, P < 0.001, 155 μmol g−1 FW) and glycine betaine contents (2.5-fold, P < 0.05, 175 μmol g−1 FW) of drought stressed oak compared to control. 相似文献
8.
2D difference gel electrophoresis reference map of a Fusarium graminearum nivalenol producing strain
Matias Pasquali Tommaso Serchi Jenny Renaut Lucien Hoffmann Torsten Bohn 《Electrophoresis》2013,34(4):505-509
Fusarium graminearum is widely studied as a model for toxin production among plant pathogenic fungi. A 2D DIGE reference map for the nivalenol‐producing strain 453 was established. Based on a whole protein extract, all reproducible spots were systematically picked and analyzed by MALDI‐TOF/TOF, leading to the identification of 1102 protein species. The obtained map contributes to the annotation of the genome by identifying previously nondescribed hypothetical proteins and will serve as a reference for future studies aiming at deciphering F. graminearum biology and chemotype diversity. 相似文献
9.
Heinrich Haas und Lucien Lévy 《Fresenius' Journal of Analytical Chemistry》1890,29(1):600-604
Ohne Zusammenfassung 相似文献
10.
The dispersion curves and attenuation factors of the Bloch eigenwaves in heiicoidal liquid crystals (chiral smectic C and cholesterics) are calculated using the 4 × 4 characteristic matrix method. Four possible types of eigenmodes are seen to exist in the medium. The reflection peaks, which correspond to odd parts of the full pitch, are total reflection peaks, while those corresponding to even parts of the full pitch are composed of three branches at high incidence angles, where the outer branches are selective reflection and the central one is a total reflection peak. Selective reflection regions occur only at the edges of the Brillouin zones, while total reflections can occur anywhere inside the zones. The former are interpreted according to the coupled mode theory as resonant Bragg reflections, with the latter as exchange Bragg reflections. When the tilt direction exceeds the propagation direction, the central branch of the even sequence of peaks starts to be due to resonant Bragg reflections. The first order peak for cholesterics becomes strongly structured at large incidence angles. 相似文献