Effect of initial conditions on decaying grid turbulence at low R λ

The transport equations for the second-order velocity structure functions 〈(δu)²〉 and 〈(δq)²〉 are used as a scale-by-scale budget to quantify the effect of initial conditions at low Reynolds numbers, typical of grid turbulence. The validity of these equations is first investigated via hot-wire measurements of velocity and transverse vorticity fluctuations. The transport equation for 〈(δq)²〉 is shown to be balanced at all scales, while anisotropy of the large scales leads to a significant imbalance in the equation for 〈(δu)²〉. The effect of using similarity to evaluate the transport equation is rigorously tested. This approach has the desirable benefit of requiring less extensive measurements to calculate the inhomogeneous term of the transport equation. The similarity form of the 〈(δq)²〉 equation produces nearly identical results as those obtained without the similarity assumption. In the case of the 〈(δu)²〉 equation, the similarity method forces a balance at large separation, although the imbalance due to large scale anisotropy remains. The initial conditions of the turbulence at constant R _M ≃ 10,400 (28≤ R _λ≤ 55) are changed by using three grids of different geometries. Initial conditions affect the shape and magnitude of the second- and third-order structure functions, as well as the anisotropy of the large scales. The effect of initial conditions on the scale-by-scale budget is restricted to the inhomogeneous term of the transport equations, while the dissipation term remains unaffected despite the low R _λ. Scales as small as λ are affected by the changes in initial conditions.     

General perspectives on model construction and evaluation for stochastic estimation,with application to a blunt trailing edge wake

The technique of stochastic estimation is examined as a specific application of linear least squares modelling. Factors that are relevant to the objectives of estimation in fluids, such as the number of sensors, the use of multiple time lags, and the strength of linear correlations, are discussed in the context of a general regression formulation. We consolidate the established findings of several research fields in order to outline clearly the potential pitfalls and reasonable performance expectations of these empirical strategies. Experimental measurements of velocity and fluctuating pressure in the wake of a blunt trailing edge body are used for quantitative illustration of key considerations for model construction and performance evaluation. It is emphasized that estimator accuracy is influenced strongly by the physical relationships among the measured variables, in addition to their correlation with the estimated variable. The evaluation of several performance metrics on an independent test set provides valuable information for the selection of a suitably complex model. In particular, “variance inflation” is interpreted as an indicator of the potential amplification of noise by a stochastic estimator.     

Aerodynamic optimization of the flat-plate leading edge for experimental studies of laminar and transitional boundary layers

This work is concerned with the design of a leading edge for a flat-plate model used to study laminar and transitional boundary layers. For this study, the flow over the complete boundary-layer model, including leading edge, flat section, and trailing-edge flap, is modeled. The effect of important geometrical features of the leading edge on the resulting pressure distribution, starting from the well-known symmetric modified super ellipse, is investigated. A minimal pressure gradient on the measurement side of the plate is achieved using an asymmetrical configuration of modified super ellipses, with a thickness ratio of 7/24. An aerodynamic shape optimization is performed to obtain a novel leading edge shape that greatly reduces the length of the non-zero pressure gradient region and the adverse pressure gradient region compared to geometries defined by ellipses. Wind tunnel testing is used to validate the numerical solutions.     

Acid-Catalyzed E-Ring Expansion and Isomerization of 3-Acetylbetulin: Synthesis of Cytotoxic Anhydrobetulin Saponins

22(17 → 28)abeo-Lupene derivatives 5a and 6a were obtained after the acid-catalyzed E-ring expansion of 3-acetylbetulin (1a). Glycosylation of these dehydrated triterpenoids using Schmidt's trichloroacetimidate sugar donors in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) provided the new anhydrobetulin saponins 7b–7e in which the terminal olefin C-20(29) isomerizes to form a C-19 tetrasubstituted alkene. The preliminary cytotoxic evaluation revealed that saponins 7b–7d exhibited a moderate cytotoxic activity against A549, DLD-1, and WS1 human cell lines with IC₅₀ ranging from 22 to 49 μM.     

Underestimated Color Centers: Defects as Useful Reducing Agents in Lanthanide‐Activated Luminescent Materials

Inorganic hosts, such as SrB₄O₇ or certain nitrides, intrinsically stabilize Eu²⁺ even when the dopant is an Eu³⁺‐based precursor and reducing conditions are not employed in the synthesis. Although this concept is well known in the synthesis of phosphorescent materials, the mechanistic details are scarcely understood. Herein, we demonstrate that trapped charge carriers, such as color centers, can also act as redox partners to stabilize certain oxidation states of activators. Eu‐activated CsMgCl₃ and CsMgBr₃ are used as examples. Upon doping with EuCl₃ and in the absence of reducing conditions during the synthesis, dominant cyan or green luminescence from Eu²⁺ ions was observed. Photoluminescence spectroscopy at 10 K revealed that the reduction is correlated to color centers localized at defects. Although defects are typically undesired in phosphors, we have shown that their role may be underestimated and they could be used on purpose in the preparation of selected inorganic phosphors.     

Thermal and viscosity characterization of two asphalt emulsions

Journal of Thermal Analysis and Calorimetry - Asphalt emulsion is a versatile product that can be used for different waterproofing applications in civil construction and highway constructions....     

Low-loss surface modes and lossy hybrid modes in metamaterial waveguides

We show that waveguides with a dielectric core and a lossy metamaterial cladding (metamaterial-dielectric guides) can support hybrid ordinary-surface modes previously only known for metal-dielectric waveguides. These hybrid modes are potentially useful for frequency filtering applications as sharp changes in field attenuation occur at tailorable frequencies. Our results also show that the surface modes of a metamaterial-dielectric waveguide with comparable electric and magnetic losses can be less lossy than the surface modes of an analogous metal-dielectric waveguide with electric losses alone. Through a characterization of both slab and cylindrical metamaterial-dielectric guides, we find that the surface modes of the cylindrical guides show promise as candidates for all-optical control of low-intensity pulses.     

A PROCEDURE FOR ALIGNING HYDRAULIC TENSILE TEST MACHINES

Misalignment can adversely affect measured material properties like tensile strength, modulus, fatigue life and yield stress, and generally increases data scatter. A convenient, effective alignment procedure for aligning hydraulic tensile test machines was developed and is described. A survey of the misalignment of the fixed grip relative to the actuated grip of four test machines was conducted, and alignments performed, demonstrating the effectiveness of the method.