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1.
AbstractModified and eco-friendly oxidation of phosphorane ylides to the corresponding vicinal tricarbonyls (VTC) using unsupported moist Oxone in dichloromethane at room temperature is described. This green oxidation protocol is simple, mild, and highly efficient to operate, and allowing a chemoselective preparation of VTC from various phosphorane ylides without tedious workup procedures of extraction/drying process in excellent yields. 相似文献
2.
This study investigates the baroclinic instability of a two-layer rotating fluid system. The instability is generated by releasing a cylinder of buoyant fluid at the surface of ambient fluid. The buoyant fluid is dyed so that its depth may be determined from its optical thickness. The system first adjusts until the horizontal density gradient is balanced by a flow along the front, and the adjusted state is then unstable to azimuthal waves. Contours of constant upper layer depth are examined, and the perturbation at each azimuthal wavenumber is determined. The initial wavenumber is well modelled by simple quasi-geostrophic theory. There is a clear high wavenumber cutoff, and a transfer of energy to larger scales with time. 相似文献
3.
J. Sarah Caygill Stuart D. Collyer Joanne L. Holmes Frank Davis Séamus P. J. Higson 《Electroanalysis》2013,25(11):2445-2452
We describe the use of cobalt phthalocyanine as a mediator to improve the sensitivity for the electrochemical detection of TNT. Commercial screen‐printed electrodes containing cobalt phthalocyanine were employed for determination of TNT. Improved sensitivities compared to screen‐printed carbon electrodes without phthalocyanine were observed, current response for cyclic voltammetric measurements at modified electrodes being at least double that of unmodified electrodes. A synergistic effect between oxygen and TNT reduction was also observed. Correlation between TNT concentrations and sensor output was observed between 0–200 µM TNT. Initial proof‐of‐concept experiments combining electrochemical determinations, with the use of an air‐sampling cyclone, are also reported. 相似文献
4.
5.
A convenient, single-step, efficient synthesis of benzimidazoles from esters and diamines is reported. The methodology uses an air stable form of trimethylaluminum referred to as DABAL-Me3 and is compatible with a wide range of functional groups, including acid-sensitive protecting groups. 相似文献
6.
7.
Joanne Dombrowski 《Journal of Mathematical Analysis and Applications》2011,378(1):133-139
This paper uses commutator equations to study the absolute continuity of spectral measures associated with certain subclasses of unbounded self-adjoint Jacobi matrix operators determined by properties of the diagonal and subdiagonal sequences. If the diagonal sequence is the zero sequence, properties of the difference sequence of the subdiagonal determine the choice of a bounded operator for the commutator equation. The structure of the resulting commutator leads to results on absolute continuity. 相似文献
8.
İbrahim Muter Ş. İlker BirbilKerem Bülbül Güvenç Şahin 《European Journal of Operational Research》2012
In their paper, Avella et al. (2006) investigate a time-constrained routing problem. The core of the proposed solution approach is a large-scale linear program that grows both row- and column-wise when new variables are introduced. Thus, a column-and-row generation algorithm is proposed to solve this linear program optimally, and an optimality condition is presented to terminate the column-and-row generation algorithm. We demonstrate by using Lagrangian duality that this optimality condition is incorrect and may lead to a suboptimal solution at termination. 相似文献
9.
Stephen Brown Ronald Grigg Joanne Hinsley Stewart Korn Visuvanathar Sridharan Michael D. Uttley 《Tetrahedron》2001,57(52):809-10355
A wide variety of aryl/heteroaryl iodides undergo an intermolecular Heck reaction with alkylallenes to furnish 1,3-dienes. These subsequently react in situ with various dienophiles to give Diels–Alder adducts. The chemistry has been extended to incorporate cyclisation-anion capture methodology and the stereochemistry of the products has been determined. 相似文献
10.
Joanne E. Stanley Anthony C. Swain Kieran C. Molloy David W. H. Rankin Heather E. Robertson Blair F. Johnston 《应用有机金属化学》2005,19(5):644-657
Perfluoroalkytin compounds R(4−n)Sn(Rf)n (R = Me, Et, Bu, Rf = C4F9, n = 1; R = Bu, Rf = C4F9, n = 2, 3; R = Bu, Rf = C6F13, n = 1) have been synthesized, characterized by 1H, 13C, 19F and 119Sn NMR, and evaluated as precursors for the atmospheric pressure chemical vapour deposition of fluorine‐doped SnO2 thin films. All precursors were sufficiently volatile in the range 84–136 °C and glass substrate temperatures of ca 550 °C to yield high‐quality films with ca 0.79–2.02% fluorine incorporation, save for Bu3SnC6F13, which incorporated <0.05% fluorine. Films were characterized by X‐ray diffraction, scanning electron microscopy, thickness, haze, emissivity, and sheet resistance. The fastest growth rates and highest quality films were obtained from Et3SnC4F9. An electron diffraction study of Me3SnC4F9 revealed four conformations, of which only the two of lowest abundance showed close F Sn contacts that could plausibly be associated with halogen transfer to tin, and in each case it was fluorine attached to either the γ‐ or δ‐carbon atoms of the Rf chain. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献