全文获取类型
收费全文 | 70篇 |
免费 | 2篇 |
专业分类
化学 | 48篇 |
晶体学 | 1篇 |
数学 | 7篇 |
物理学 | 16篇 |
出版年
2023年 | 2篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 1篇 |
2016年 | 7篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 3篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 5篇 |
2007年 | 1篇 |
2006年 | 3篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2000年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有72条查询结果,搜索用时 156 毫秒
1.
Jadriane A. Xavier Thaissa L. Silva Eduardo Caio Torres-Santos Camila Calado de Vasconcelos Anastacio Boane Ricardo Alexandre dos Santos Andre Felippe A. Xavier Marília O.F. Goulart 《Current Opinion in Electrochemistry》2021
This review discusses the state of the art, challenges, and perspectives in recent applications of nitroaromatics and nitroheteroaromatics, which are redox-bio-activated drugs or leads, in Medicinal Chemistry. It deals mainly with the electrochemical approach toward the electron transfer-based molecular mechanisms of drug action, drug design, estimation and measurement of redox potentials, correlation of physicochemical and pharmacological data, and electrochemical studies of the main representatives of nitro-containing prodrugs, along with approaches to combat their toxicity issues, aiming at a better therapeutic profile. Electrochemical investigation plays essential roles, being strategic in the design and discovery of potential medicines. 相似文献
2.
Antônio Gomes dos Santos Neto Franciele de Matos Morawski Ana Caroline Ferreira Santos Cláudia Quintino da Rocha Roberto Batista de Lima Marília Oliveira Fonseca Goulart Clenilton Costa dos Santos Flávio Colmati Antônio Euzébio Goulart Santana Marco Aurélio Suller Garcia Auro Atsushi Tanaka 《Electroanalysis》2023,35(5):e202200390
Here, we report multiwalled carbon nanotubes (MWCNTs) functionalized with γ-cyclodextrins (γCD) as a novel electrochemical strategy for Rutin determination, showing superior performance than β-cyclodextrins (βCD) modified MWCNTs, suggesting an adequate environment for host-guest interactions. Under optimized conditions, the sensor showed a linear range of 39–975 nmol L−1 and a limit of detection of 7 nmol L−1. When tested with quercetin, catechin, and caffeine, the platform presented high selectivity with an interference response <10 %. The method was employed to quantify Rutin in spiked pharmaceutical and herbal extracts, providing recovery of 93–98.4 %. Also, HPLC-PDA confirmed the method‘s accuracy. 相似文献
3.
Felix Duensing Elisabeth Gruber Paul Martini Marcelo Goulart Michael Gatchell Bilal Rasul Olof Echt Fabio Zappa Masoomeh Mahmoodi-Darian Paul Scheier 《Molecules (Basel, Switzerland)》2021,26(12)
Complexes of atomic gold with a variety of ligands have been formed by passing helium nanodroplets (HNDs) through two pickup cells containing gold vapor and the vapor of another dopant, namely a rare gas, a diatomic molecule (H2, N2, O2, I2, P2), or various polyatomic molecules (H2O, CO2, SF6, C6H6, adamantane, imidazole, dicyclopentadiene, and fullerene). The doped HNDs were irradiated by electrons; ensuing cations were identified in a high-resolution mass spectrometer. Anions were detected for benzene, dicyclopentadiene, and fullerene. For most ligands L, the abundance distribution of AuLn+ versus size n displays a remarkable enhancement at n = 2. The propensity towards bis-ligand formation is attributed to the formation of covalent bonds in Au+L2 which adopt a dumbbell structure, L-Au+-L, as previously found for L = Xe and C60. Another interesting observation is the effect of gold on the degree of ionization-induced intramolecular fragmentation. For most systems gold enhances the fragmentation, i.e., intramolecular fragmentation in AuLn+ is larger than in pure Ln+. Hydrogen, on the other hand, behaves differently, as intramolecular fragmentation in Au(H2)n+ is weaker than in pure (H2)n+ by an order of magnitude. 相似文献
4.
Deshan Liu Soshian Sarrafpour Wen Guo Brian Goulart 《Journal of carbohydrate chemistry》2014,33(7-8):423-434
The stereochemical outcome of glycosylation reactions of 2-deoxy-sugar trichloroacetimidates promoted by chiral Brønsted acids is shown to be dependent on both the chirality of the catalyst and the configuration of the leaving group. High levels of selectivity (1:16 α:β) can be obtained with (S)-catalysts and an α-trichloroacetimidate donor. Conversely, (R)-catalysts require longer reaction times and provide the product in much lower selectivity (6.6:1 α:β). These observations demonstrate that stereochemical “match” and “mismatch” between donor and acceptor are important factors in chiral Brønsted acid-promoted glycosylations. 相似文献
5.
Phabyanno Rodrigues Lima Paulo Rogério Barbosa de Miranda Adriano Bof de Oliveira Marília Oliveira Fonseca Goulart Lauro Tatsuo Kubota 《Electroanalysis》2009,21(21):2311-2320
The present work explores, for the first time, the electrocatalytic oxidation of ascorbic acid (AscH2) and its determination in the presence of uric acid (UA) on the in situ activated 4‐nitrophthalonitrile modified carbon paste electrode. The kinetic constant κ for the catalytic reaction for the electrocatalytic oxidation of ascorbic acid, evaluated by cyclic voltammetry, chronoamperometry and RDE voltammetry provided values around 106 L mol?1 s?1. The sensor provided a linear response range for AscH2 and UA from 5.0 up to 120.0 μmol L?1 with detection limits of 1.6 μmol L?1and 1.3 μmol L?1, respectively. The sensor was applied for the simultaneous determination of AscH2 and UA in urine samples and the average recoveries for these samples were 99.8 (±3.1)% and 99.9 (±2.1)%, respectively . 相似文献
6.
do Nascimento Ticiano Gomes Borges Arthur Luy Tavares Ferreira de Almeida Lara Mendes Ribeiro Êurica Adélia Nogueira Silva Fernanda Geny Calheiros da Costa Silva Valdemir do Nascimento Prata Ana Paula Basílio-Júnior Irinaldo Diniz Goulart Marília Oliveira Fonseca Morilla Demetrius Peireira de Freitas Johnnatan Duarte Aragão Cícero Flávio Soares 《Journal of Thermal Analysis and Calorimetry》2022,147(21):11949-11963
Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT... 相似文献
7.
Goulart MO Machado Reys JR Emery FS Pinto AV de Souza Filho JD 《Magnetic resonance in chemistry : MRC》2004,42(7):663-665
Peroxidation of the phenazine of beta-lapachone using m-ClC6H4CO3H-CH2Cl2 furnished a macrolactone with a rigid 10-membered ring, and the corresponding N-oxide, along with a dihydrobenzophenazine-5-one. All of the new compounds were fully characterized by spectroscopic methods, with the unambiguous assignment of the hydrogens and carbon NMR signals for the N-oxide, with the aid of 2-D NMR, mainly COSY, HMQC, HSQC and HMBC. For the other two compounds some signals could not be assigned owing to their own intrinsic features. 相似文献
8.
Perin Gelson Silva Cristian M. Borges Elton L. Duarte José E. G. Goulart Helen A. Silva Rafaela B. Schumacher Ricardo F. 《Research on Chemical Intermediates》2016,42(6):5873-5885
Research on Chemical Intermediates - We describe a simple and rapid method for selective synthesis of 4-thiomethyl-1,3-dioxolan-2-ones promoted by KF/Al2O3 using PEG-400 as solvent under microwave... 相似文献
9.
F. S. de Aguiar L. B. Bernardes S. Goulart Rosa Jr. 《Journal of statistical physics》1991,64(3-4):673-682
Metastability in the ferromagneticp-state Potts model defined on the Cayley tree is discussed. It is shown that the sign of the boundary fieldH
s
determines the order of the transition as well as the stability of the low-temperature phase. Lowering the temperature withH
s
>0, a system withp<2 (p>2) will display a second (first)-order transition to a metastable (stable) phase. ForH
s
>0 a second (first)-order transition to a metastable (stable) phase occurs ifp>2 (p<2). In this case the system also has a residual entropy which is negative forp<2. 相似文献
10.
Wislei?R.?Osório Noé?Cheung José?E.?Spinelli Pedro?R.?Goulart Amauri?GarciaEmail author 《Journal of Solid State Electrochemistry》2007,11(10):1421-1427
Hypoeutectic aluminum–silicon alloys can have significant improvements in mechanical properties by inducing structural modification
in the normally occurring eutectic. The eutectic modification may affect not only the mechanical properties but also the corrosion
resistance of such alloys. It is well known that structural parameters such as grain size and interdendritic spacing can significantly
affect corrosion resistance of alloys. However, to date, few researches have been performed to experimentally evaluate the
effects of an effective modification of eutectic morphology on surface corrosion behavior of Al–Si alloys. In the present
study, modified and unmodified samples of an Al 9 wt.% Si alloy were solidified under similar solidification conditions, and
after metallographic procedures, the corrosion resistance was analyzed by both the electrochemical impedance spectroscopy
technique and the Tafel extrapolation method carried out in a 0.5 M NaCl test solution at 25 °C. The impedance parameters
and corrosion rate were obtained from an equivalent circuit analysis. It was found that the Al-9 wt.% Si alloy casting in
the modified condition tends to have its corrosion resistance decreased when compared to the unmodified alloy. 相似文献