Wave packet dynamics of nonlinear Gazeau–Klauder coherent states of a position-dependent mass system in a Coulomb-like potential

AD = 1 position-dependent mass approach to constructing nonlinear quantum states for a modified Coulomb potential is used to generate Gazeau–Klauder coherent states. It appears that their energy eigenvalues are scaled down by the quantum number and the nonlinearity coefficient. We study the basic properties of these states, which are found to be undefined on the whole complex plane, and some details of their revival structure are discussed.     

Solubility and Crystallizability: Facile Access to Functionalized π‐Conjugated Compounds with Chlorendylimide Protecting Groups

Functional π‐conjugated molecules are relevant for the preparation of new organic electronic materials with improved performance. However, their synthesis is often rendered difficult by their inherently low solubility, and the permanent attachment of solubilizing groups may change the properties of the material. Here, we introduced the chlorendylimidyl moiety as a new temporary protecting group for the straightforward large‐scale synthesis of protected quarter‐, sexi‐, octathiophene, and perylene bisimide diamine and dicarboxylic acid derivatives. The obtained chlorendylimides and chlorendylimidyl active esters were highly soluble in organic solvents, and optical spectroscopy confirmed the low tendency of the compounds to aggregate in solution. At the same time, they could be conveniently purified by recrystallization or precipitation. Single‐crystal X‐ray structures obtained for most compounds showed supramolecular motifs highlighting the role of the rigid, polychlorinated chlorendyl moieties in their crystallization. The obtained protected diamine and dicarboxylic acid derivatives were easily deprotected and converted into various amide‐substituted oligothiophenes and perylene bisimides that are of interest as new functional materials for organic electronic thin film or nanowire devices.     

Entanglement Dynamics and Symmetry Breaking in Symmetric four Qubits GHZ- and W-type States Coupled to Classical Random Telegraph Noise in Mixed Environments

A system of three non-interacting qubits is used as a quantum probe to classify three classical non-Gaussian noises namely, the static noise (SN), colored noise (pink and brown spectrum) and random telegraph noise (RTN), according to their detrimental effects on the evolution of entanglement of the latter. The probe system is initially prepared in the GHZ state and coupled to the noises in independent environments. Seven configurations for the qubit-noise coupling (QNC) are considered. To estimate the destructive influence of each kind of noise, the tripartite negativity is employed to compare the evolution of entanglement in these QNC configurations to each other with the same noise parameters. It is shown that the evolution of entanglement is drastically impacted by the QNC configuration considered as well as the properties of the environmental noises and that the SN is more detrimental to the survival of entanglement than the RTN and colored noise, regardless of the Markov or non-Markov character of the RTN and the spectrum of the colored noise. On the other hand, it is shown that pink noise is more fatal to the system than the RTN and that the situation is totally reversed in the case of brown noise. Finally, it is demonstrated that these noises, in descending order of destructive influence, can be classified as follows: SN > pink noise > RTN > brown noise.

     

Kinetic Behavior of Quaternary Ammonium Hydroxides in Mixed Methane and Carbon Dioxide Hydrates

This study evaluates the kinetic hydrate inhibition (KHI) performance of four quaternary ammonium hydroxides (QAH) on mixed CH₄ + CO₂ hydrate systems. The studied QAHs are; tetraethylammonium hydroxide (TEAOH), tetrabutylammonium hydroxide (TBAOH), tetramethylammonium hydroxide (TMAOH), and tetrapropylammonium hydroxide (TPrAOH). The test was performed in a high-pressure hydrate reactor at temperatures of 274.0 K and 277.0 K, and a concentration of 1 wt.% using the isochoric cooling method. The kinetics results suggest that all the QAHs potentially delayed mixed CH₄ + CO₂ hydrates formation due to their steric hindrance abilities. The presence of QAHs reduced hydrate formation risk than the conventional hydrate inhibitor, PVP, at higher subcooling conditions. The findings indicate that increasing QAHs alkyl chain lengths increase their kinetic hydrate inhibition efficacies due to better surface adsorption abilities. QAHs with longer chain lengths have lesser amounts of solute particles to prevent hydrate formation. The outcomes of this study contribute significantly to current efforts to control gas hydrate formation in offshore petroleum pipelines.     

Cavitation for incompressible anisotropic nonlinearly elastic spheres

In this paper, the effect ofmaterial anisotropy on void nucleation and growth inincompressible nonlinearly elastic solids is examined. A bifurcation problem is considered for a solid sphere composed of an incompressible homogeneous nonlinearly elastic material which is transversely isotropic about the radial direction. Under a uniform radial tensile dead-load, a branch of radially symmetric configurations involving a traction-free internal cavity bifurcates from the undeformed configuration at sufficiently large loads. Closed form analytic solutions are obtained for a specific material model, which may be viewed as a generalization of the classic neo-Hookean model to anisotropic materials. In contrast to the situation for a neo-Hookean sphere, bifurcation here may occur locally either to the right (supercritical) or to the left (subcritical), depending on the degree of anisotropy. In the latter case, the cavity has finite radius on first appearance. Such a discontinuous change in stable equilibrium configurations is reminiscent of the snap-through buckling phenomenon of structural mechanics. Such dramatic cavitational instabilities were previously encountered by Antman and Negrón-Marrero [3] for anisotropiccompressible solids and by Horgan and Pence [17] forcomposite incompressible spheres.     

Simple Torsion of Isotropic, Hyperelastic, Incompressible Materials with Limiting Chain Extensibility

The purpose of this research is to investigate the simple torsion problem for a solid circular cylinder composed of isotropic hyperelastic incompressible materials with limiting chain extensibility. Three popular models that account for hardening at large deformations are examined. These models involve a strain-energy density which depends only on the first invariant of the Cauchy–Green tensor. In the limit as a polymeric chain extensibility tends to infinity, all of these models reduce to the classical neo-Hookean form. The main mechanical quantities of interest in the torsion problem are obtained in closed form. In this way, it is shown that the torsional response of all three materials is similar. While the predictions of the models agree qualitatively with experimental data, the quantitative agreement is poor as is the case for the neo-Hookean material. In fact, by using a global universal relation, it is shown that the experimental data cannot be predicted quantitatively by any strain-energy density which depends solely on the first invariant. It is shown that a modification of the strain energies to include a term linear in the second invariant can be used to remedy this defect. Whether the modified strain-energies, which reflect material hardening, are a feasible alternative to the classic Mooney–Rivlin model remains an open question which can be resolved only by large strain experiments. This revised version was published online in August 2006 with corrections to the Cover Date.     

Upper and lower bounds for the shear stress in the Saint-Venant theory of flexure

Upper and lower bounds are derived for the shear stress as it is determined by Saint-Venant's theory of flexure, and used to establish the asymptotic character of the classical Strength of Materials formula in the limit of vanishing thickness.

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Résumé On dérive des limites supérieures et inférieures des contraintes tangentielles suivant la théorie de la flexion de Saint-Venant, que l'on utilise aux fins d'établir le caractère asymptotique de la formule de la Résistance des Matériaux dans le cas limite d'une épaisseur extrêmement petite.

     

Assemblies from metallic and semiconducting nanocrystals

Optical properties of nanomaterials such as semiconductor and metal quantum dots are important for sensors and photovoltaic applications. We report on optical, microscopic, and AFM investigations on bulk and single nanoobjects such as metal and semiconducting nanoparticles. Firstly, of special interest is the investigation of Ag metal nanoaggregates formed in zeolites. Here, the defined structure of the zeolite serves both as size directing and a stabilizing agent. The size selected Ag aggregates fluoresce in the zeolite cages even after storage under ambient conditions for almost one year. In addition, single Ag particles escape the cages and can be investigated by fluorescence microscopy also with respect to sensor applications. Secondly, with respect to photovoltaic applications, energy transfer among organic dye molecules and semiconductor quantum dots is of great importance. We report on the extension of the optical absorption of ZnSe quantum dots into the UV regime and investigate excitation energy transfer within self-assembled nanoaggregates of surface functionalized QDs and fluorescent styrylpyridine dyes.