2-Chloroanthraquinone-catalyzed aerobic photo-oxidative synthesis of diacylamines from benzylamides

In this Letter, we report the aerobic photo-oxidative synthesis of diacylamines from benzylamides in the presence of molecular oxygen and catalytic amounts of 2-chloroanthraquinones under visible light irradiation from a fluorescent lamp.     

Ultrasonic-Combined Plasma Bubbling for Adherent Bacteria Disinfection on Medical Equipment

Plasma Chemistry and Plasma Processing - Atmospheric low-temperature plasma has received attention for application in disinfection methods. In this study, we develop a plasma bubbling method as a...     

Regio- and stereoselective preparation of dienylcarboxylic acids and dienylphosphonic esters using a (Z)-alkenyl sulfone-titanocene(II) system

Titanocene(II)-promoted alkenylation of functionalized alkynes with (Z)-alkenyl sulfones proceeded with high regio- and stereoselectivity to produce functionalized dienes. Conjugated dienylcarboxylic acids and dienylphosphonic esters were obtained using acetylenic lithium carboxylates and dialkyl phosphonates as starting materials.     

Development of sulfide glass-ceramic electrolytes for all-solid-state lithium rechargeable batteries

Development of Li₂S–P₂S₅-based glass-ceramic electrolytes is reviewed. Superionic crystals of Li₇P₃S₁₁ and Li_3.25P_0.95S₄ were precipitated from the Li₂S–P₂S₅ glasses at the selected compositions. These high temperature or metastable phases enhanced conductivity of glass ceramics up to over 10⁻³ S cm⁻¹ at room temperature. The original (or mother) glass electrolytes itself showed somewhat lower conductivity of 10⁻⁴ S cm⁻¹ and have important role as a precursor for obtaining the superionic crystals, which were not synthesized by a conventional solid-state reaction. The substitution of P₂O₅ for P₂S₅ at the composition 70Li₂S·30P₂S₅ (mol%) improved both conductivity and electrochemical stability of glass-ceramic electrolytes. The all-solid-state In/LiCoO₂ cell using the 70Li₂S·27P₂S₅·3P₂O₅ (mol%) glass-ceramic electrolyte showed initial capacity of 105 mAh g⁻¹ (gram of LiCoO₂) at the current density of 0.13 mA cm⁻² and exhibited higher electrochemical performance than that using the 70Li₂S·30P₂S₅ glass-ceramic electrolyte.     

Zone diagrams in Euclidean spaces and in other normed spaces

Zone diagrams are a variation on the classical concept of Voronoi diagrams. Given n sites in a metric space that compete for territory, the zone diagram is an equilibrium state in the competition. Formally it is defined as a fixed point of a certain “dominance” map. Asano, Matou?ek, and Tokuyama proved the existence and uniqueness of a zone diagram for point sites in the Euclidean plane, and Reem and Reich showed existence for two arbitrary sites in an arbitrary metric space. We establish existence and uniqueness for n disjoint compact sites in a Euclidean space of arbitrary (finite) dimension, and more generally, in a finite-dimensional normed space with a smooth and rotund norm. The proof is considerably simpler than that of Asano et?al. We also provide an example of non-uniqueness for a norm that is rotund but not smooth. Finally, we prove existence and uniqueness for two point sites in the plane with a smooth (but not necessarily rotund) norm.     

Experimental study on effect of relative humidity on heat transfer of an evaporating water droplet in air flow

Dispersed water droplets are often seen in environmental air flows in rain, cloud, mist, sea spray and so on. It is therefore of great importance to precisely estimate heat transfer between water droplets and atmospheric air in developing a reliable climate model. The purpose of this study is to fabricate the measurement system for the temperature of a small water droplet in air flow under the controlled relative humidity condition and to investigate the effect of relative humidity on heat transfer across the surface of an evaporating water droplet in air flow. The results show that the droplet temperature decreases in the low-relative-humidity condition, whereas it increases in the high-relative-humidity condition. Nusselt number on the droplet surface is not affected by the relative humidity.     

All-solid-state rechargeable lithium batteries using SnX-P2X5 (X = S and O) amorphous negative electrodes

SnS-P₂S₅ and SnO-P₂O₅ amorphous materials were prepared by a mechanical milling technique. The SnO-P₂O₅ milled materials worked as a reversible electrode with higher capacity than SnO crystal in rechargeable lithium cells with conventional liquid electrolytes. All-solid-state cells with a SnX-P₂X₅ (X = S and O) amorphous electrode and the Li₂S-P₂S₅ glass-ceramic electrolyte were charged and discharged at room temperature. The sulfide electrodes exhibited better charge-discharge performance than the oxide electrodes, suggesting that SnS-P₂S₅ electrodes are more compatible with Li₂S-P₂S₅ sulfide solid electrolytes. All-solid state batteries 80SnS·20P₂S₅/LiCoO₂ showed a charge-discharge plateau of about 3.4 V and high reversible capacity of over 400 mAh/g, even after 50 cycles. The SnX (X = S and O)-based amorphous materials are promising negative electrode materials with high capacity for rechargeable lithium batteries using not only liquid electrolytes but solid electrolytes.     

Fabrication of convex-shaped polybenzylsilsesquioxane micropatterns by the electrophoretic sol–gel deposition process using indium tin oxide substrates with a hydrophobic-hydrophilic-patterned surface

Polybenzylsilsesquioxane (BnSiO_3/2) particles become a supercooled liquid through a heat treatment above the glass transition temperature (T _g) of the particles. Micropatterns of BnSiO_3/2 thick films with high transparency were obtained by the electrophoretic deposition of the BnSiO_3/2 particles on indium tin oxide (ITO)-coated substrates with a hydrophobic-hydrophilic-patterned surface and subsequent heating above T _g of the particles. It was found that the control of electrophoretic deposition conditions, in which the amounts of the particles deposited on the substrates were changed, led to two types of micropatterning processes of the BnSiO_3/2 thick films. In the first process, the particles were selectively deposited on the hydrophilic areas after the electrophoretic deposition. In the second process, the particles were deposited on the whole area of the ITO-coated substrate with hydrophobic-hydrophilic patterns after the electrophoretic deposition. Due to the difference in wettability of BnSiO_3/2 molten liquids between hydrophobic and hydrophilic surfaces, the molten liquids on the hydrophobic areas, which were obtained by heating above T _g of the particles, migrated toward the hydrophilic areas. In both the processes, convex-shaped BnSiO_3/2 micropatterns with high transparency were fabricated only on the hydrophilic areas after a heat treatment above T _g of the particles.     

Inorganic-organic hybrid membranes with anhydrous proton conduction prepared from 3-aminopropyltriethoxysilane and sulfuric acid by the sol-gel method

Inorganic-organic hybrid membranes with anhydrous proton conduction were prepared from 3-aminopropyltriethoxysilane and H2SO4 by the sol-gel method. The membrane has a unique structure: a hexagonal phase formed by the stacking of rodlike polysiloxanes with ion complexes of ammonium groups and HSO4- extruded outside. The membranes showed high conductivity of 2 x 10-3 S cm-1 at 200 degrees C under dry atmosphere. In the membrane, protons probably migrate through the outside of the rodlike polysiloxanes along hydrogen-bond chains formed among HSO4- anions.