全文获取类型
收费全文 | 2296篇 |
免费 | 131篇 |
国内免费 | 21篇 |
专业分类
化学 | 1590篇 |
晶体学 | 14篇 |
力学 | 96篇 |
综合类 | 4篇 |
数学 | 363篇 |
物理学 | 381篇 |
出版年
2023年 | 18篇 |
2022年 | 25篇 |
2021年 | 81篇 |
2020年 | 50篇 |
2019年 | 83篇 |
2018年 | 73篇 |
2017年 | 51篇 |
2016年 | 109篇 |
2015年 | 107篇 |
2014年 | 103篇 |
2013年 | 218篇 |
2012年 | 170篇 |
2011年 | 169篇 |
2010年 | 129篇 |
2009年 | 117篇 |
2008年 | 140篇 |
2007年 | 128篇 |
2006年 | 92篇 |
2005年 | 83篇 |
2004年 | 82篇 |
2003年 | 66篇 |
2002年 | 48篇 |
2001年 | 20篇 |
2000年 | 13篇 |
1999年 | 17篇 |
1998年 | 19篇 |
1997年 | 11篇 |
1996年 | 17篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1988年 | 5篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 12篇 |
1978年 | 11篇 |
1977年 | 9篇 |
1976年 | 16篇 |
1975年 | 8篇 |
1974年 | 5篇 |
1973年 | 7篇 |
1970年 | 5篇 |
排序方式: 共有2448条查询结果,搜索用时 849 毫秒
1.
2.
A simple, precise and accurate method is proposed for rapid determination of trace amounts of hydroxylamine based on the reaction of hydroxylamine with iodate in acidic media. The reaction of neutral red by the produced nitrite ion was used to monitor the reaction spectrophotometrically at 525 nm by a fixed time method. Hydroxylamine in the range of 0.0400-1.200 microg mL(-1) could be determined. The relative standard deviation for 10 determinations of 0.500 microg mL(-1) hydroxylamine was 1.81% and the limit of detection was 0.010 microg mL(-1). The proposed method was applied to the determination of hydroxylamine in water samples with satisfactory results. 相似文献
3.
Oracle inequality is a relatively new statistical tool for the analysis of nonparametric adaptive estimates. Oracle is a good pseudo-estimate that is based on both data and an underlying estimated curve. An oracle inequality shows how well an adaptive estimator mimics the oracle for a particular underlying curve. The most advanced oracle inequalities have been recently obtained by Cavalier and Tsybakov (2001) for Stein type blockwise estimates used in filtering a signal from a stationary white Gaussian process. The authors also conjecture that a similar result can be obtained for Efromovich–Pinsker (EP) type blockwise estimators where their approach, based on Stein's formula for risk calculation, does not work. This article proves the conjecture and extends it upon more general models which include not stationary and dependent processes. Other possible extensions, a discussion of practical implications and a numerical study are also presented. 相似文献
4.
Abbas Shockravi Samad Bavili T Esmael Rostami Ali Yousefi Ali Dehjurian Rahim Tohidi 《Journal of inclusion phenomena and macrocyclic chemistry》2004,49(1-2):163-166
Some new dibenzosulfo, dibenzosulfoxo macrocyclic diamides are synthesized. 相似文献
5.
The H-point standard addition method (HPSAM), based on a spectrophotometric measurement for the simultaneous determination of hydrazine and acetylhydrazine, is described. This method is based on the difference between the rates of their reactions with N,N-dimethylaminobenzaldehyde (DAB) in the presence of sodium dodecyl sulfate (SDS) in acidic media. The results showed that hydrazine and acetylhydrazine could be determined simultaneously in the range of 0.020 - 0.70 and 0.20 - 5.0 mg L(-1), respectively. Under the working conditions, the proposed method was successfully applied to the simultaneous determination of hydrazine and acetylhydrazine in several synthetic mixtures and plasma and water samples. 相似文献
6.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007 相似文献
7.
Latifeh Navidpour Leila Karimi Mohsen Amini Mohssen Vosooghi Abbas Shafiee 《Journal of heterocyclic chemistry》2004,41(2):201-204
Arylation of the readily available 3‐alkythio‐5‐aryl‐1,2,4‐triazoles gave 5‐alkylthio‐1,3‐diaryl‐1,2,4‐triazoles in moderate yield. The structures of the latter were confirmed by NOE and 13C‐NMR. 相似文献
8.
In this paper, we prove the Hyers-Ulam-Rassias stability of homomorphisms in quasi-Banach algebras associated to the Pexiderized Cauchy functional equation. This is applied to investigate homomorphisms between quasi-Banach algebras. The concept of Hyers-Ulam-Rassias stability originated from Th.M. Rassias' stability theorem that appeared in his paper [Th.M. Rassias, On the stability of the linear mapping in Banach spaces, Proc. Amer. Math. Soc. 72 (1978) 297-300]. 相似文献
9.
10.
Sam I. Ahonkhai
Andreas N
llePeter Behr
Horst Heydtmann 《Journal of photochemistry and photobiology. A, Chemistry》1994,80(1-3):389-392Experimental results are presented of a Fourier transform IR product study at 298 K of the reaction system CFO+O2 at oxygen pressures between 3 and 250 mbar. Pulsed photolysis of oxalyl fluoride (CFO)2 or formyl fluoride (CHFO) at 193 nm was used to produce CFO. As stable products we detected bis-fluoroformyl peroxide, carbonyl fluoride and carbon dioxide. The yields of the peroxide and of CF2O were measured as a function of [O2]/[precursor] and are discussed qualitatively. 相似文献