螺吡喃功能化UiO-66光响应吸附剂的制备及其性能

将光响应分子甲基螺吡喃SP-CH₃引入UiO-66的非极性孔笼中,构筑吸附活性位可光控调节的光响应吸附剂。SP-CH₃功能化的吸附剂完好保留了载体UiO-66的骨架和孔道结构。以阴离子染料甲基橙为探针,研究了吸附剂在不同光照条件下的吸附和解吸性能。结果表明,经紫外光照后,吸附剂对甲基橙的吸附量为41.99 mg·g^-1,相较于可见光照后样品的吸附量提升57.56%,吸附作用增强;经可见光照后,甲基橙的脱附量为81.6%。本策略通过光照刺激改变UiO-66孔笼中SP-CH₃的构型及表面电荷性质,即对吸附活性位进行光控调节,在不同光照条件下实现对吸附质的高效吸附和有效脱附。     

Bifurcation of piecewise-linear nonlinear vibration system of vehicle suspension

A kinetic model of the piecewise-linear nonlinear suspension system that consists of a dominant spring and an assistant spring is established. Bifurcation of the resonance solution to a suspension system with two degrees of freedom is investigated with the singularity theory. Transition sets of the system and 40 groups of bifurcation diagrams are obtained. The local bifurcation is found, and shows the overall character- istics of bifurcation. Based on the. relationship between parameters and the topological bifurcation solutions, motion characteristics with different parameters are obtained. The results provides a theoretical basis for the optimal control of vehicle suspension system parameters.     

螺吡喃功能化UiO-66光响应吸附剂的制备及其性能

将光响应分子甲基螺吡喃SP-CH₃引入UiO-66的非极性孔笼中,构筑吸附活性位可光控调节的光响应吸附剂。SP-CH₃功能化的吸附剂完好保留了载体UiO-66的骨架和孔道结构。以阴离子染料甲基橙为探针,研究了吸附剂在不同光照条件下的吸附和解吸性能。结果表明,经紫外光照后,吸附剂对甲基橙的吸附量为41.99 mg·g^-1,相较于可见光照后样品的吸附量提升57.56%,吸附作用增强;经可见光照后,甲基橙的脱附量为81.6%。本策略通过光照刺激改变UiO-66孔笼中SP-CH₃的构型及表面电荷性质,即对吸附活性位进行光控调节,在不同光照条件下实现对吸附质的高效吸附和有效脱附。     

分段线性非线性汽车悬架系统的分岔行为

建立了由主、副簧组成的分段线性非线性悬架系统动力学模型,应用奇异性理论研究了两个自由度汽车悬架系统共振解的分岔,得到系统的转迁集和40组分岔图,发现了非常复杂的局部分岔,分岔图全面展示了这一系统的分岔特性.由系统参数与该系统的拓扑分岔解之间的联系,分析并得到了不同参数下系统的运动特性,为实现悬架参数的优化控制提供了理论依据.     

Bifurcation of elastic tank-liquid coupled sloshing system

The nonlinear equations of an elastic tank-liquid coupling system subjected to the external excitation are established. By means of the multi-scale method and the singularity theory, the bifurcation behaviors of the system are investigated and analyzed. The various nonlinear dynamical behaviors of the coupling system are obtained, which can further explain the relationship between the physical parameters and the bifurcation solutions. The results provide a theoretical basis to the realization of the parameter optimal control.     

Parameter design of a liquid-filled sloshing system

<正>The nonlinear governing equations of the liquid sloshing modals in a cylindrical storage tank are established. Through analytical analysis,the analytical expressions of the solutions of this kind of system are obtained.With different parameters,the dynamical behaviors of the solutions are different from the trivial ones.To prevent system instability,two selection principles that the stiffness equations are positive-definite and the nonlinear terms of the system are not regenerative elements are given.Meanwhile,numerical simulations are also given,which confirm the analytical results.     

螺吡喃功能化UiO-66光响应吸附剂的制备及其性能

将光响应分子甲基螺吡喃SP-CH₃引入UiO-66的非极性孔笼中,构筑吸附活性位可光控调节的光响应吸附剂。SP-CH₃功能化的吸附剂完好保留了载体UiO-66的骨架和孔道结构。以阴离子染料甲基橙为探针,研究了吸附剂在不同光照条件下的吸附和解吸性能。结果表明,经紫外光照后,吸附剂对甲基橙的吸附量为41.99 mg·g^-1,相较于可见光照后样品的吸附量提升57.56%,吸附作用增强;经可见光照后,甲基橙的脱附量为81.6%。本策略通过光照刺激改变UiO-66孔笼中SP-CH₃的构型及表面电荷性质,即对吸附活性位进行光控调节,在不同光照条件下实现对吸附质的高效吸附和有效脱附。     

磁流变阻尼器汽车悬架的非线性振动特性分析

通过对磁流变阻尼器sigmoid模型进行数值计算分析,揭示了各参数对该模型阻尼力的影响,证明了通过合理有效地选择参数可设计出符合工程实际应用的磁流变阻尼器.对确定性激励下磁流变阻尼器的Sigmoid模型进行了理论分析.指出了采用非线性的阻尼器模型能更精确地描述汽车悬架的振动特性.从而证明了磁流变阻尼器有良好的使用价值和Sigmoid模型磁流变阻尼器在汽车控制工程应用中的可行性.     

一类弹性储液箱同液体耦合晃动问题的分岔行为分析

建立了弹性圆柱型储液箱同液体耦合系统在外激励下的非线性振动方程组．采用多尺度法、奇异性理论研究此非线性振动系统共振解的分岔行为,通过对其分岔行为的分析和讨论,得到了这一系统的多种转迁集和分岔图,建立了系统参数与其拓扑分岔解的联系,并且分析了不同参数下系统的分岔特性,为实现储液器参数的优化控制提供了理论依据．