排序方式: 共有9条查询结果,搜索用时 109 毫秒
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通过IR方法,观测并讨论了在不同条件下制备的超高分子量PE(WHMPE)凝胶膜中旁式(G构象)构象与超拉伸性的关系,提出了G构象浓度及分布对UHMPE凝胶膜超拉伸性影响的新概念,同时也讨论了它与链缠结之间的联系,发现:反映G构象的相对浓度的比值σ=I1303I1352随制膜浓度的增大而增加,在临界浓度C0(0.4~0.5g@100ml)附近所形成的膜,具有超高拉伸性(λ=200),其G构象的变化与Matsuo由比浓粘度提出的缠结链改变相对应;热处理温度比热处理时间对σ值的影响更显著,在一定温度下约4分钟后σ值基本不变;在σ值最低的温度范围拉伸,凝胶膜具有良好的超高拉伸性. 相似文献
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超高分子量聚乙烯和聚丙烯共混体系自由体积的研究 总被引:1,自引:0,他引:1
正电子湮灭研究结果发现,常温下超高分子量聚乙烯和低乙烯含量嵌段聚烯熔融共混体系自由体积含随组分呈非单调度化,与线加和关系相比发生了正偏离,意味养界面相区域堆砌密度低,导致了过量的自由体积。 相似文献
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预热处理对超高分子量聚乙烯层积状片晶凝胶膜结构的影响 总被引:3,自引:0,他引:3
由准稀溶液速冷制备的超高分子量聚乙烯(UHMWPE)凝胶膜,具有片晶(Lamella)取向平行于膜面的层积状结构,在129—134℃的温度范围内拉伸,可获得超高拉伸比(λ>200).通过IR及X-ray衍射等方法研究发现,拉伸前用不同温度退火处理后,凝胶膜的片晶微结构产生明显变化,在对应于超高拉伸温度范围内,其结晶度增加,微晶的c和b轴方向尺寸变大,而a轴方向的尺寸减小,从理论上对这一变化过程作了考察,并讨论了超高拉伸取向性与这些结构变化的关系以及可超拉伸取向性的最佳温度范围. 相似文献
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用茂钛配合物高效、高选择性催化4-乙烯基环己烯的异构化 总被引:1,自引:0,他引:1
The catalytic species [Cp2TiH], formed in situ from the reaction of titanocene dichloride with Grignard reagents having a β-H, was found to be a very effective catalytic system for isomerization of diolefin[1~3]. Based on our previous work[3], the titanium-catalyzed isomerization of 4-vinyl-cyclohexene (VCH) was studied in some detail. In this communication, we report the use of various substituted titanocene and polymer-supported titanocene complexes with Grignard reagents as catalyst for the isomerization of VCH. It was reported that base-catalyzed isomerization of VCH formed a very complicated mixture with 60 % conversion[4]. 相似文献
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In the present work, the structure and impact properties of copolymers of polypropylenewith low ethylene contents have been investigated. Based on the results of ~(13)C--NMR, FTIR,WAXD, DSC, PLM and SEM, the relationship between impact properties and morphology of thecopolymers has been discussed. The high impact properties of copolymer ICP2 may attribute tothe relatively higher ethylene content and homogeneous ethylene unit distribution. The size andits distribution of spherulite in the copolymers and cycloid cavities dispersed in polypropylenecontinue phase may also be two important factors which affect the impact properties of these materials. 相似文献
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