1H和19F NMR研究镍系催化丁二烯聚合中醇类对BF3·Oet2的增溶作用

The solubility of BF₃OEt₂ in hydrogenated gasoline was improved greatly by means of premixing BF₃OEt₂ with C₃H₁₇OH in nickel catalyst system, so that the effeciency of fluorine in the system was increased markedly. It is confirmed that there was a intermolecular hydrogen bond between alcohol and BF₃OEt₂ molecules by using ¹H NMR, which was a vital factor to lead the solubilization of BF₃OEt₂ in hydrogenated gasoline. Otherwise, the caculation formula of the chemical shift ofproton in hydroxy, ¹H = xipi,was suggested in hydrogen bond system.     

Soliton structures in the (1+1)-dimensional Ginzburg–Landau equation with a parity-time-symmetric potential in ultrafast optics

In this paper, the(1+1)-dimensional variable-coefficient complex Ginzburg–Landau(CGL) equation with a paritytime(PT) symmetric potential U(x) is investigated. Although the CGL equations with a PT-symmetric potential are less reported analytically, the analytic solutions for the CGL equation are obtained with the bilinear method in this paper. Via the derived solutions, some soliton structures are presented with corresponding parameters, and the influences of them are analyzed and studied. The single-soliton structure is numerically verified, and its stability is analyzed against additive and multiplicative noises. In particular, we study the soliton dynamics under the impact of the PT-symmetric potential. Results show that the PT-symmetric potential plays an important role for obtaining soliton structures in ultrafast optics, and we can design fiber lasers and all-optical switches depending on the different amplitudes of soliton-like structures.     

单片双波长输出垂直外腔面发射激光器EI北大核心CSCD

报道了利用垂直外腔面发射激光器(Vertical external cavity surface emitting laser,VECSEL)的增益谱与腔模的大失配设计实现VECSEL双波长同时激射的方法,设计了稳定的振荡腔结构,理论预测了这种VECSEL的三种工作状态并进行了实验验证。随着VECSEL泵浦功率增加,增益芯片内部工作温度逐步升高,VECSEL依次出现带边波长激射、双波长激射及腔模波长激射三种工作状态。最初VECSEL的激射波长位于带边模式决定的激光波长(952.7 nm),随着泵浦功率增加,增益芯片热效应增强,腔模波长与带边波长出现模式竞争,此后出现双波长激射现象。双波长峰值强度接近时VECSEL激光输出功率达到359 mW,激光波长分别位于954.2 nm和1001.2 nm,在该位置附近VECSEL的输出功率曲线呈现明显的二次阈值现象。当泵浦功率持续增加,激光输出波长变为腔模波长激射,激光波长位于1002.4 nm。在单波长及双波长工作状态下VECSEL的光斑形貌均为高斯形貌的圆形对称激光光束,激光光束发散角半角由5.7°增加到7.9°。这种单芯片双波长输出VECSEL方案未来在抗干扰激光雷达以及频率转换太赫兹激光等方面有着很好的应用潜力。     

~1H和~(19)F NMR研究镍系催化丁二烯聚合中醇类对BF_3·OEt_2的增溶作用

<正> 在镍系催化丁二烯聚合中,助催化剂BF_3·OEt_2在加氢汽油中溶解性差,往往形成非均相体系,因而降低了催化剂体系的稳定性和氟的利用率。我们曾研究了A1(i-Bu)_3分别与丙醇、丁醇、戊醇,己醇、辛醇、壬醇、癸醇和十六醇按等摩尔交换,制得A1(i-Bu)_2OR作助催化剂,观察Al/B与催化活性的关系,发现以十六醇为最好,Al/B在0.25—0.95聚合活性较高,超出此限活性迅速下降。为了进一步提高Al/B,采用了向镍催化体系添加醇的方法。聚合实验证实了该法可提高氟的利用率。测定醇-硼体系的~1HNMR,证实了醇-硼分子间形成了氟-氢氢键。     

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介绍了类Be的ArⅩⅤ最低40个能级的能级精细结构.利用基于多组态Dirac-Fock方程,给出了类Be的ArⅩⅤ的Kα跃迁的能级、波长、振子强度和能级寿命.研究表明,当前所得的理论计算结果与实验值以及其它理论值符合很好,同时对于分析已有的实验结果和指导拟开展的实验也有一定的意义.