α-氧化铁介孔纳米材料的制备及其在锂/钠离子电池中的电化学性能

采用硬模板法合成了具有六方排列的平行圆柱形有序孔道介孔α-氧化铁(α-Fe_2O_3),并将其用作锂离子、钠离子电池的负极材料。所制备的介孔α-Fe_2O_3凭借其独特的有序介孔结构,有效缓解电极在充放电过程中的体积效应,提高了电解液浸润性,促进锂/钠离子的转移和传输,从而在锂离子及钠离子电池中均表现出优异的电化学性能。作为锂离子电池负极时,其首圈放电比容量为983.9 mAh·g~(-1)。经过100次循环后,其放电比容量为1 188.0 mAh·g~(-1)。在钠离子电池中,其首圈放电比容量为687.7mAh·g~(-1)。经过50次循环后,仍有316.9 mAh·g~(-1)的放电比容量。     

浙江长兴煤山二叠-三叠系界线剖面磁性地层特征

煤山二叠-三叠系剖面(31.1°N,119.7°E)包括晚二叠世长兴组和早三叠世青龙组,厚约60m,共采集古地磁样品111块。测量结果表明该剖面存在6个正、反极性带,它们都属于Illawarra混合极性间隔。二叠-三叠系界线位于正极性带V底界以上1.2(2.7)m,实验证明,长兴组下段岩石中磁性矿物主要为针铁矿、赤铁矿和含钛磁铁矿;上段岩石中以含钛磁铁矿和磁铁矿为主,部分岩石也含较多的针铁矿。青龙组灰岩和泥灰岩中主要含磁铁矿和赤铁矿。根据磁性稳定样品结果,获得三叠纪初期古地磁极位于50.7°N,230.3°E,采样地区古纬度为12.3°N。     

Low Threshold Distributed Feedback Quantum Cascade Lasers with Widely Spaced Emission Wavelengths

We report lasing properties of distributed feedback quantum cascade lasers （DFB QCLs） including a doublephonon-resonance active region, at wavelength of about 8.4 μm. A broad gain spectrum is generated due to the coupling between the lower laser level in the active region and the levels in the injector, and is demonstrated by the lasing spectrum of the corresponding Fabry-Perot QCLs whose width is 0.5 μm at 1.5 times of the threshold current. As a result, the DFB QCLs employing different grating periods exhibit a wavelength span of 0.18μm at room temperature and total wavelength coverage of 0.28μm at various heat sink temperatures. A high side mode suppression ratio of about 30dB and a low threshold current density of 1.78kA/cm^2 are achieved as the lasers operate at room temperature in pulsed mode.     

脉冲电容器用细电滞回线铁电陶瓷材料的研究

采用低锆区的Pb(Zr_0.42Sn_0.40Ti_0.18)O₃(PZST42/40/18)铁电陶瓷为基, 通过少量La和Ba取代Pb同时Nb取代(Zr, Sn, Ti)复合取代的方法得到掺杂PZST42/40/18细电滞回线铁电陶瓷, 其最大极化强度P_max≈20.66μC/cm², 剩余极化强度P_r≈0.55μC/cm^{关键词： 细电滞回线 铁电陶瓷 PZST 脉冲电容器}     

广东沿海陆地地质环境质量定量评价研究

广东沿海陆地不仅是我国经济较为发达的地区 ,而且也是地震、水土流失、崩塌、滑坡、地裂缝、地面沉降、岩溶塌陷、软土地基形变等地质灾害较为频发的地区。基于对广东沿海陆地主要物理地质灾害形成条件与影响因素调查、统计与分析 ,将广东沿海陆地地质环境质量划分 :构造稳定性、斜坡稳定性和地基稳定性三个质量层面 ,进而构造了隶属三个层面的指标体系 ,该指标体系包括活动断裂、地震活动、地形起伏度、斜坡坡地、冲沟切割密度、水土流失程度、崩滑面密度、土体承载力和地裂缝面密度 9个指标。基于地质环境质量五值逻辑等级取值 :优等、良好、中等、较差和差等 ,对评价指标进行了相应地量化分级取值和标准化处理 ,在建立指标专家权重体系和线性隶属函数的基础上 ,构造了模糊数学综合评价模型。基于 Fortran程序对 190个剖分单元指标数据进行了模型运算 ,将广东沿海陆地地质环境划分为五个质量级共 17个地质环境质量单元。     

MAGNETOSTRATIGRAPHY OF PERMO-TRIASSIC BOUNDARY SECTION OF MEISHAN OF CHANGXING,ZHEJIANG

A hundred and eleven samples were collected from the Permian-Triassic boundarysection of Meishan (31.1°N, 119.7°E) which includes the Changxing Formation of thelate Permian and the Qinglong Formation of early Triassic. The thickness of the sectionis about 60 m. Paleomagnetic results indicate that six normal and reversed polarity zoneswere recorded in the section which all belong to the Illawarra mixed interval. Theboundary of Permo-Triassic lies at 1.2 m (or 2.7 m) above the bottom of normal polarityzone V. The magnetic minerals in the rocks of the lower part of the Changxing Forma-tion mainly are goethite, haematite and titaniferous magnetite while in the upper part ofthe formation are chiefly titanomagnetite and magnetite, goethite is secondary. Magne-tite and haematite as the main magnetic minerals were included in marl and mudstone ofthe Qinglong Formation. Based on the results of the magnetically stable samples thepaleopole position of 50.7°N, 230.3°E was obtained, meanwhile, the paleolatitude