污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能研究

亚甲基蓝和环丙沙星是水体中2种污染物, 对生态环境有潜在危害. 本文以市政剩余活性污泥为原料, 氯化锌为活化剂热解制备污泥基吸附剂, 研究盐酸酸洗浓度、氯化锌浓度、热解温度、热解时间等对污泥基吸附剂吸附水中亚甲基蓝和环丙沙星性能的影响. 结果表明 (1)污泥基吸附剂对亚甲基蓝的吸附性能随盐酸酸洗浓度的增大而增加, 对环丙沙星的吸附性能则随盐酸酸洗浓度的增大呈先降后增趋势, 两者均在1.500mol·L-1盐酸浓度下取得最优值. (2)污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能随氯化锌浓度和热解温度的增加呈先升后降趋势, 在氯化锌浓度为4.0mol·L-1、热解温度为500℃时有最优值; 随着热解时间的延长, 污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能分别在500℃热解70min和80min时有最优值. (3)污泥基吸附剂的最佳制备条件为 氯化锌4.0mol·L-1活化2h、500℃热解70min和80min、1.500mol·L-1盐酸酸洗; 以此制得的污泥基吸附剂对亚甲基蓝和环丙沙星的去除率分别为97.7%和96.4%, 平衡吸附量分别为97.9mg·g-1和3.9mg·g-1, 且污泥基吸附剂对亚甲基蓝和环丙沙星的吸附过程均符合准二级动力学方程.     

高岭土催化剂中铝的测定

高岭土催化剂是目前石油化工工业中生产和使用的一种无机催化剂,它以高岭土和分子筛为主要原料,经加工而成.铝的含量(通常以Al_2O_ 3计)是该产品的必测项目之一.鉴于目前尚未制订出标准测定方法,现有文献资料也未找到一种能完全套用的方法,我们借鉴其它样品的试样分解方法和铝的测定方法,经试验提出了一个完整的铝含量的测定方法.1 试验部分1.1 主要试剂乙酸:50%过氧化氢:3?TA溶液:0.05mol·L~(-1)六次甲基四胺:30%二甲酚橙指示剂:0.2%     

Synthetical optimization of the structure dimension for the thermoacoustic regenerator

The quantitative investigation of parameters in the renegerator is essential for the optimization of thermoacoustic devices, while the majority of the previous research only considered parameters of the working field, working gas and the hydraulic radius. Based on the linear thermoacoustic theory, this paper extracts a normalized parameter for low-amplitude conditions, which is called the regenerator operation factor. By extracting the regenerator operation factor and relative hydraulic radius, the influence of frequency on the efficiency can be controlled and offset. It can be found that thermoacoustic devices with different frequencies can perform the same efficiency by adjusting the radius in proportion to the axial length. Finally, this paper synthetically optimizes the dimension of the thermoacoustic regenerator by taking the regenerator operation factor, relative hydraulic radius and acoustic field parameter as variables. Conclusions in this paper are of great significance for explaining the best working conditions of engines and directing the miniaturization and optimal design of thermoacoustic devices.