基于神经网络和HVS的空域数字水印算法

为了弥补空间域水印算法在提取水印时需要原宿主图像、鲁棒性较差等缺点,提出一种基于BP神经网络和人眼视觉特性(HVS)的空域数字水印算法。先选出原宿主图像对比度函数值最大的前块用于二值水印图像的嵌入,利用神经网络能够逼近任意非线性关系的特点和其自适应性,构建水印信号嵌入前后图像块像素值间的映射关系,实现了水印的盲提取,并将该算法与现有算法进行了对比。实验结果表明,对于JPEG压缩、加噪、剪切和旋转等常见的图像处理攻击,算法具有良好的鲁棒性和不可见性。     

湿法水解制备可见光催化剂N/TiO2

The N/TiO₂ was prepared by wet hydrolyzation method. The photocatalytic decomposition of benzoic acid solution was carried out under simulated sun light; the photocatalytic activity was 2.47 times of TiO₂. The products were characterized by XRD, SPS, EFISPS and XPS, respectively. The results of XRD showed that the N could restrain the crystallization transformation of TiO₂ from anatase to rutile. The N/TiO₂ was still n-type semiconductor, and the absorbance wavelength appeared red-shifted by N-doping. The band gap of N/TiO₂ was decreased to 2.7 eV. The amount of doped-N is about 0.94at.%. The binding energy of N1s are 396.62 eV (Ti-N bonds, β-N) and 400.87 eV (N-N bonds, γ-N₂), respectively, and the photocatalytic activity of N/TiO₂ under visible light is related to the β-N. The N atoms replace the O of the TiO₂ and form the Ti-N bonding.     

有机/无机杂化纳米结构单元的空间构型研究

利用乙烯基三甲氧基硅烷(VMS)水解缩合, 制备了有机/无机杂化纳米结构单元乙烯基倍半硅氧烷(VSSO). 采用FTIR, NMR(¹H, ¹³C和²⁹Si)和MALDI-TOF MS测试, 结合SSO的结构通式T_n(OH)_x(OR′)_y [x, y = 0, 1, 2 …; n = 1, 2 …; T = RSiO_{1.5−(x + y)/2n}]推测出具有固定分子量的水解缩合产物VSSO所对应的多个结构简式. 运用量子力学计算的方法, 以单一VSSO整体分子为模型, 得出了各种结构的几何参数(Si-O和Si-C键长, Si-O-Si和O-Si-O的键角)和分子体系的总能量. 根据计算结果可知, VSSO的梯型结构较笼型结构具有较高的稳定性, 并得出VSSO可能的最合理、最稳定的结构类型是梯型的结论.     

有机/无机杂化纳米结构单元的空间构型研究--Ⅰ.乙烯基倍半硅氧烷梯型结构的量子力学确定

利用乙烯基三甲氧基硅烷(VMS)水解缩合,制备了有机/无机杂化纳米结构单元乙烯基倍半硅氧烷(VSSO).采用FTIR,NMR(1H,13C和29Si)和MALDI-TOF MS测试,结合SSO的结构通式Tn(OH)x(OR')y[x,y=0,1,2…;n=1,2…;T=RSiO1.5-(x+y)/2n]推测出具有固定分子量的水解缩合产物VSSO所对应的多个结构简式.运用量子力学计算的方法,以单一VSSO整体分子为模型,得出了各种结构的几何参数(Si-O和Si-C键长,Si-O-Si和O-Si-O的键角)和分子体系的总能量.根据计算结果可知,VSSO的梯型结构较笼型结构具有较高的稳定性,并得出VSSO可能的最合理、最稳定的结构类型是梯型的结论.     

用离子色谱法测定水中微量氯乙酸

1　引　　言现代医学证明饮用水经氯化消毒产生的氯乙酸具有“三致”性。因此 ,如何快速简便而准确地测定水中微量氯乙酸则至关重要。离子色谱法适用于分析无机阴、阳离子和常见的有机离子 ,但用于分析氯乙酸根离子报道较少 ,一些文献中仅仅说明离子色谱可用于氯乙酸的测定 ,但未作详细描述。本文在前人研究工作的基础上 ,研究了用离子色谱分析水中一氯乙酸和三氯乙酸的分析方法 ,并用于实际水样的分析 ,结果表明 ,该方法具有简便、快速和准确的特点。2　实验部分2 .1　仪器与试剂　Ｄｉｏｎｅｘ 2 0 10Ｉ型离子色谱仪 (美国Ｄｉｏｎｅｘ公…     

可见光催化剂S/TiO2的制备与表征

The sulfur-doped titanium dioxide (S/TiO₂) was prepared by calcinations. The photocatalytic decomposition of benzoic acid solution was carried out under simulated sun light; the photocatalytic activity is 2.7 times of TiO₂. The results of XRD show that the sulfur can restrain the crystallization transformation of TiO₂ from anatase to rutile, although the calcinations temperature has attained 500 ℃, the crystallization still is anatase entirely. The responsive wavelength range of S/TiO₂ was shifted; it has obvious absorption in the region from 320 to 550 nm. The S (S⁶⁺) substituted for some of the lattice titanium atoms in S/TiO₂. At the same time the XRF also prove the formation of S⁶⁺ and the atomic content is 2.13%.