超导相Tl2Ba2CuO6的制备和晶体结构研究

The superconducting phase Tl_2Ba_2CuO_6 with onset T_C 85 K and zero resistivity at 61 K has been prepared. The unit cell is body-centred tetragonal, space group I_4/mmm, lattice parametrs a=0.3866(1) nm, c=2.3180(3) nm. The relation between structural features and its superconductivity was discussed.     

超导相(Bi1.7Pb0.2In0.1)Sr2Ca2Cu3O10的制备和晶体结构研究

The superconducting phase(Bi_(1.7)Pb_(0.2)In_(0.1))Sr_2Ca_2Cu_3O_(10) with on-set T_c near 112K and zero resistivity at 95K has been prepared. The Unit cell is. body-centered tetragonal, space group I4/mmm, a=0.3.817(1) nm, c=3.704(1) nm. Chemical substitution of Pb and In in Bi—Sr—Ca—Cu—O series results in the growth of 2223 phase. The superconductivity and the formation mechanism are associated with the structural features.     

超导相Tl_2Ba_2CuO_6的制备和晶体结构研究

Tl_2 Ba_2 Ca_(n-1) Cu_n O_(2n 4)(n=1,2,3,4)体系中以Tl_2 Ba_2 CuO_6 T_c最低。我们得到此单相,测定了晶体结构,以了解结构因素和超导性、生成机理的关系。制备与表征由BaO_2和CuO按1∶1混合,在880℃长时间加热,使之充分反应制得BaCuO_2,再加Tl_2O_3按1∶1计量比混合、研磨、压片,然后放入预热到850℃的管式炉内,在氧气氛中加热,约30-40分钟后取出,在空气中快速冷却,然后按计量比补充因挥发损失的Tl_2O_3,重新研磨、     

超导相Tl2Ca3Ba2Cu4O12的制备与结构研究

我们已制备出Tl_2 Ca Ba_2 Cu_2O_8(2122)和Tl_2Ca_2 Ba_2 Cu_3 O_(10)(2223)两个纯相,并对它们的晶体结构和性质进行了研究。现在我们又制备出一种新的超导相,它的组成为Tl_2 Ca_3 Ba_2 Cu_4 O_(120(2324),并进一步研究了它的超导性质和晶体结构。     

超导相(Bi_(1.7)Pb_(0.2)In_(0.1))Sr_2Ca_2Cu_3O_(10)的制备和晶体结构研究

Bi-Sr-Ca-Cu-O体系的掺杂可以改善超导性能和消除堆垛层错。由于铋氧双层的作用还未能很好地了解,我们合成X_2Sr_2Ca_2Cu_3O_(10)的纯相,[X为(Bi_(0.85)Ph_(0.1)In_(0.05)]以确定其是(XOXO)还是(XO_2X),以及如何影响晶体结构,超导性质和生成机理。合成和鉴定CaCO_3、SrO、CuO的混合物于900℃烧结20hr得到Sr_2Ca_2Cu_3O_7,然后与Bi_2O_3、PbO按摩尔比1∶0.87∶0.3混匀,压片,于870℃加热20hr,重新研磨,在880℃加热30hr,再加0.6%mol In_2O_3,于890℃烧结20hr,然后在空气中淬火,样品表面部分微熔。     

掺杂对超导体(Tl1-x-yPbxMy)Sr2(Ca0.8Ln0.2)Cu2O7-δ(M=Sn4+或Sb5+, Ln=Y,La, Nd或Pr)性能的影响

Subramanian et al. found superconductivity at 80 K in Tl_(0.5)Pb_(0.5)Sr_2CaCu_2O_y sample with YBa_2 Cu_3 O_(7-δ)-like structure. However, there is unstable factor in the structure of the superconductor. Total plus valence is 12.5, and total minus valence is 14. The structure was further stabilized by partial substitution of Y, La, Nd orPr for Ca and Sn~(4+) or Sb~(5+) for (Tl, Pb), so that T_c was achieved above 100 K. For example, T_c is about 103 K in a sample with nominal composition (Tl_(0.4) Pb_(0.5)Sn_(0.2))Sr_2(Ca_(0.8)Y_(0.2))Cu_2O_(7-δ). During the preparation of superconductors, the temperature of samples was very slowly down after sintering, or samples were annealed at 500—700 ℃. The samples absorbed the oxygen during cooling, but no phase change occured. Appropriate amount of the oxygen made T_e higher.     

掺杂对超导体(Tl_(1-x-y)Pb_xM_y)Sr_2(Ca_(0.8)Ln_(0.2))Cu_2O_(7-δ)(M=Sn~(4+)或Sb~(5+),Ln=Y,La,Nd或Pr)性能的影响

自1988年初Bi-Sr-Ca-Cu-O和Tl-Ba-Ca-Cu-O两个高T_c氧化物超导体问世以后,人们就想了解Tl-Sr-Ca-Cu-O和Bi-Ba-Ca-Cu-O两个体系的超导性能,但后者至今尚未制备成功.Sheng等人报导了Tl-Sr-Ca-Cu-O的超导性能,T_c约为20K,获得的材料的Meissner效应小于1%.Subramanian等人通过Pb部分取代Tl,获得了(Tl_(0.5)Pb_(0.5) Sr_2CaCu_2O_y和     

Tl系列超导体中掺F研究

Ｔｌ系列超导体中掺Ｆ研究周鼎元（上海闸北教育学院，上海２０００７０）徐昌华（上海工业大学，上海２０００７２）陈敏（上海市长城电子工业公司，上海）关键词％Ｔｌ系超导体，掺Ｆ在ＲＢａ。Ｃｕ。Ｏｘ中掺加Ｆ的研究已有不少报逍（”．本文研究在ＴＩ系列超导体中掺...