基质辅助激光解吸附飞行时间质谱分析缩合单宁的阳离子化问题

以单价金属离子Cs 和Na 作为离子化试剂,对3种缩合单宁进行基质辅助激光解吸附飞行时间(MALD I-TOF)质谱分析。加入Na 作为阳离子化试剂,能得到较高质量的质谱图。但由于实验通道中几乎不可能完全去除的K 的干扰而会高估棓儿茶酚/表棓儿茶酚单元的组成比例,从而影响对棓儿茶酚/表棓儿茶酚单元存在与否的判断;选择Cs 作为阳离子化试剂可以避免此问题,但在复杂的缩合单宁分析中,同样因为杂质离子Na 和K 的干扰而使得质谱图变得更复杂;未去离子处理直接对缩合单宁进行MALD I-TOF质谱分析与去离子并加入Cs 的处理比去离子并加入Na 能检测到更高聚合度的高聚物,检测到离子峰强度最高的聚合物随离子不同而不同。     

Alternative non-Gaussianity measures for quantum states based on quantum fidelity

We propose three alternative measures for non-Gaussianity of quantum states: sine distance, Bures angle, and Bures distance, which are based on quantum fidelity introduced by Wang [Phys. Lett. A 373 58 (2008)]. Using them, we evaluate the non-Gaussianity of some relevant single-mode and two-mode non-Gaussian states and find a good consistency of the three examined measures. In addition, we show that such metrics can exactly quantify the degree of Gaussianity of even Schrödinger-cat-like states of small amplitudes that can not be measured by other known non-Gaussianity measures such as the Hilbert—Schmidt metric and the relative entropy metric. We make a comparative study between all existing non-Gaussianity measures according to the metric axioms and point out that the sine distance is the best candidate among them.