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E,E-1,4-Bis(4'-N,N-diphenylaminostyryl)-2,5-dimethoxybenzene (DPAMOB) has been synthesized by a simple and effective solid phase Wittig reaction and characterized by 1^H NMR spectra and elemental analysis, Linear absorption, single-photon induced fluorescence and two-photon induced fluorescence spectra were experimentally studied. The new dye has a large two-photon absorption (TPA) cross-section of σr= 1007,2 GM [1 GM= 1 × 10^-50 cm^4·s/(photon molecule)] at 800 nm measured by the two-photon induced fluorescence method. The experimental results confirm that DPAMOB is a good TPA chromophore and can successfully initiate two-photon photopolymerization of ethoxylated trimethylolpropane triacrylate esters (SR454). Finally, a microstructure has been fabricated by use of DPAMOB as initiator. 相似文献
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