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A true single-step process suitable for fabrication of micro-periodic structure in polymer films by two- photon initiated photopolymerization and laser ablation is presented.By the right choice of the irradiation energy,the irradiated zone is modified or ablated in the 1.44-μm-thick film.The mechanism of grating generation and the potential application of the gratings in integrated optics are discussed. 相似文献
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利用内耗和DSC的方法研究了不同纳米粒子含量PET/SiO2纳米复合材料和纯PET弛豫性能的变化,并计算出次级弛豫峰的激活能和峰高以及主级弛豫的激活参数和峰高.结果发现内耗峰的峰高和主弛豫的激活参数以及次级弛豫的激活能随纳米SiO2的增加而减小.一方面内耗峰的峰高主要是PET的非晶区的分子链或基团运动产生,因此纳米粒子的高效成核效应,促进PET结晶成核,非晶区减小,导致内耗峰减小.另一方面由于纳米粒子与PET产生化学接枝以及氢键等作用,对链段的运动起到了一定的限制作用,导致主弛豫的激活参数和次级弛豫的激活能的增加.因此纳米SiO2颗粒与PET基体之间的化学和物理相互作用导致了PET链段的弛豫特性的变化. 相似文献
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E,E-1,4-Bis(4'-N,N-diphenylaminostyryl)-2,5-dimethoxybenzene (DPAMOB) has been synthesized by a simple and effective solid phase Wittig reaction and characterized by 1^H NMR spectra and elemental analysis, Linear absorption, single-photon induced fluorescence and two-photon induced fluorescence spectra were experimentally studied. The new dye has a large two-photon absorption (TPA) cross-section of σr= 1007,2 GM [1 GM= 1 × 10^-50 cm^4·s/(photon molecule)] at 800 nm measured by the two-photon induced fluorescence method. The experimental results confirm that DPAMOB is a good TPA chromophore and can successfully initiate two-photon photopolymerization of ethoxylated trimethylolpropane triacrylate esters (SR454). Finally, a microstructure has been fabricated by use of DPAMOB as initiator. 相似文献
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提出了一种在第三类边界条件下,根据LED灯瞬态温度场的变化规律,通过对其表面温度的实际数值测定来推算LED灯表面对流换热系数的快速测定方法。基于对流热平衡理论,设计了一种可以在较高表面换热强度条件下进行测试的装置,通过实验测定LED灯上下表面的温度,结合曲线拟合对实测数据进行数理分析,得到较宽范围内的表面对流换热系数。实验结果表明:该测试方法简单、实用,测试时间较短(实验准备与数据测定大约需要30 min),测试精度较高(数据拟合误差不高于0.2%),可靠性强,可以用于工程热设计等多种相关发热体表面对流换热系数的测定。 相似文献
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The title compound 4-(N,N-diphenylamino)styrene-4′-N-methylpyridinium iodine (abbreviated to PASMPI) was synthesized by a facile condensation reaction with a high yield. The red crystal including a molecule of CHCl3 was obtained by recrystallization in chloroform/ethanol. Its crystal structure was determined by a four-circle diffractometer. The crystal data: C26H23N2ICHCl3, Mr = 609.73, orthorhombic, space group Pbca, a = 15.422(5), b = 14.042(5), c = 24.693(5) , V = 5347(3) 3, Z = 8, Dc = 1.515 g/cm3, F(000) = 2432, μ(MoKa) = 0.057 mm-1, the final R = 0.0439 and wR = 0.0772. The results reveal that the molecule is a completely reverse system. The molecular rotation from non-coplanar to coplanar may play an important role in increasing the fluorescence intensity under the condition of staining DNA. 相似文献
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在HF水平上,利用解析响应函数方法,研究了1,4_二甲氧基_2,5_二乙烯基苯系列衍生物 分子的单光子和双光子吸收特性. 实验测量了反,反_2,5_双(4′_N,N_二丁胺基苯乙烯)_1 ,4_二甲氧基苯分子的单光子和双光子荧光谱. 研究结果表明该系列分子具有较强的双光子 吸收特性. 在低能量范围内,对于D_π-A型分子,分子的单光子吸收强度和双光子吸收截面 最大值都发生在分子的第一激发态. 对于D_π_D型分子,单光子吸收强度最大值出现在分子 的第一激发态,而最大双光子吸收值则对应于分子的第二激发态. 分子的单和双光子吸收强 度和分子官能团的电性有关. 对于由该类π中心部分构成的分子,其对称型不一定比不对称型更有利于提高双光子吸收截面. 分子基态与电荷转移态的电荷转移过程定性地解释了双光 子聚合反应的聚合机理.
关键词:
双光子吸收
响应函数方法
非线性光学 相似文献
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