[Ni(NN)(SS)]混配配合物的合成与性质

多硫 1,2-二硫醇烯配合物如 [M(dmit)2]n－、 [M(dddt)2]n－、 [M(pddt)2]n－等作为分子导体已有广泛的研究 [1,2]。多硫 1, 2-二硫醇烯 [M(NN)(SS)]型混配配合物,既含有可作为电子给体的 1,2-二硫醇烯配体,又含有可作为电子受体的二亚胺（ diimine）配体,由于分子内的配体到配体的电荷转移（ LLCT）作用,使得电中性的平面型分子中,两种配体处于极化状态,其新奇的分子结构,以及由此而来的光电磁等性质,也格外引人关注 [3]。文献报道这类配合物在适当的激发波长作用下可被光氧化并发出强光 [4]。另一方面,由于配体与配体间的…     

[Ni(dmit)(dmise)]n-混合配体配合物的合成与导电性质

合成了[Ni(dmit)(dmise)]     

耦合液膜传输的研究进展

综述了近年来含流动载体的质子、电子及光耦合液膜传输的研究进展及潜在的应用前景。     

包覆型纳米纤维吸收剂的电磁性能研究

采用化学镀方法制备出纳米磁性金属包覆碳纤维吸收剂, 分析比较了包覆前后纳米纤维长度对吸收剂电磁参数和比饱和磁化强度的影响. 在此基础上优化制备了雷达波吸收涂层样板, 检测结果表明, 制备的样板具有较好的雷达波吸收性能.     

Investigation on the thermal radiation properties of antimony doped tin oxide particles

This paper reports the preparation of antimony doped tin oxide crystalline powders by chemical coprecipitation method. The influence of sintering temperature and the sintering retention time on the thermal infrared emissivity is analysed. The thermal infrared reflectivity is measured and the optimum doping concentration is proposed.     

[Ni(NN)(SS)]混配配合物的合成与性质

Four new complexes of the general formula [Ni(SS)(NN)], Where SSis dddt (5,6-dihydro-1,4-dithiin-2,3-dithiolate) or pddt(6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate) and NNis bpy or phen were prepared. The UV/Vis.Spectra exhibit intense intramolecular ligand-to-ligand charge transfer bands ca.600 nm.Cyclic voltammetry shows a reversible oxidation step assigned to [Ni(SS)(NN)]⁰=[Ni(SS)(NN)]⁺. When the complex [Ni(dddt)(bpy)] was partially oxidized by I₂, a broad ESRsignal at g=2.003 appeared.     

[Ni(dmit)(dmise)]~(n-)混合配体配合物的合成与导电性质

合成了 [Ni( dmit) ( dmise) ]n-( n=2 ,1 ,0 )型混合配体配合物 ,用电结晶法制得 [BEDT-TTF]-[Ni( dmit) ( dmise) ]电荷转移盐 ,并用 EA、IR、ESR对目标产物进行了表征 .2 5℃测得化合物 [Ni( dmit) -( dmise) ]和 [BEDT-TTF][Ni( dmit) ( dmise) ]的电导率分别为 0 .2 9和 5.6× 1 0 -3 Ω-1· cm-1.2 98～ 1 0 3 K温度范围内变温电导曲线显示 :化合物 [Ni( dmit) ( dmise) ]具有典型的半导体性质 .     

Research on factors influencing on the microwave permeability of nanocrystalline FeB alloys

Nanocrystalline FeB alloys have been prepared with optimized grain size and internal stress. Samples prepared under different annealing conditions are analysed by x-ray diffraction, and the permeability $\mu(\omega)$ is measured by HP8510B Vector Network Analyser in the frequency range 2--18GHz. The results show that annealing leads to the growth of the grain size and reduces the internal stress, and smaller grain size and larger internal stress favours the magnetic dissipation.     

Studies on organic binders with high infrared transparency

This paper reports that two kinds of polymers with high infrared transparency and good mechanical and physical properties have been prepared. An internal standard method is used to evaluate the infrared transparency of the binders. The physical and mechanical properties of the binders are measured according to corresponding standards. The results show the absorbance of polymer A in 8--14~μ m range is 26% that of the ethylene-vinyl acetate copolymer (EVA), and polymer B is 9% that of the EVA correspondingly. The film of polymer A shows good flexibility of above 1~mm, a hardness of grade 1, and adhesion of grade 2. The film of polymer B shows good flexibility of above 1~mm, a hardness of grade 1, and adhesion of grade 1.