四川泸定县泥石流灾害成因、特征与防治建议

泸定县地处川西高原与四川盆地的过渡地带,地质环境条件复杂,分布泥石流沟127条,发育密度054条·10km-2。在遥感解译和地面调查基础上,论述了泸定县泥石流灾害成因、发生特征、危害和发展趋势,提出了相关防治建议。(1)成因表现为复杂的断裂构造导致流域内松散物源丰富,较大的相对高差提供了良好势能条件,而汛期集中强降雨则提供了动能条件,且雨量条件中当日雨量与前期有效降雨量之间具有幂函数关系; (2)发生特征表现出典型的空间群发性(包括2005-06-30群发性泥石流、2005-08-11群发性泥石流和2006-07-14群发性泥石流)与时间的夜发性; (3)危害方式主要包括淤埋、冲毁、侵蚀、堵河4种,泥石流已造成74人死亡; (4)发展趋势表现为泥石流沟多处于形成期和发展期(113条,占89%),发生的年际准周期由20a缩短至不足10a,且发生条(次)由4条(次)增加至44条次(2005年); (5)泸定县泥石流防治的突出问题表现为城镇泥石流问题、泥石流堵塞主河问题、风景区泥石流问题与冲沟泥石流问题,建议通过科学规划、风险防御体系构建、土木工程治理、监测预警等措施予以防御。     

汶川震区北川9.24暴雨泥石流特征研究

2008年9月24日汶川震区的北川县暴雨导致区域性泥石流发生,这次9.24暴雨泥石流灾害导致了42人死亡,对公路和其他基础设施造成严重损毁。本研究采用地面调查和遥感解译方法分析地震与暴雨共同作用下的泥石流特征,获取的气象数据用于分析泥石流起动的临界雨量条件。本文探讨了研究区泥石流起动和输移过程,并根据野外调查,分析了泥石流形成的降雨、岩石和断层作用,特别是强降雨过程与物源区对泥石流发生的作用。根据应急调查发现北川县境内暴雨诱发的泥石流72处,其分布受岩石类型、发震断层和河流等因素控制。根据对研究区震前和震后泥石流发生的临界雨量和雨强的初步分析,汶川地震后,该区域泥石流起动的前期累积雨量降低了14.8%～22.1%,小时雨强降低25.4 %～31.6%。震区泥石流起动方式主要有二种,一是由于暴雨过程形成的斜坡表层径流导致悬挂于斜坡上的滑坡体表面和前缘松散物质向下输移,进入沟道后转为泥石流过程;二是"消防水管效应"使沟道水流快速集中,并强烈冲刷沟床中松散固体物质,导致沟床物质起动并形成泥石流过程。调查和分析发现沟内堆积的滑坡坝对泥石流的阻塞明显,溃决后可导致瞬时洪峰流量特别大。研究结果表明了汶川震区已进入一个新的活跃期。因此,应该开展对汶川地震区的泥石流风险评估和监测、早期预警,采取有效的工程措施控制泥石流的发生和危害。     

Reliability of flexible electrically conductive adhesives

Based on our previous work about electrically conductive adhesives (ECAs), a flexibilizer named 1,3‐propanediol bis (4‐aminobenzoate) was used to fabricate flexible ECAs (FECAs). ECAs, FECAs, and electronic devices connected by them were carried out the hot and humid aging test under constant humidity level of 85% relative humidity at 85 °C for 600 h. After aging, the bulk resistance change of ECAs was about 26%, that of FECAs was a little higher, about 29%. The contact resistance change of devices connected by ECAs and FECAs was very great, about 450% and 410%, respectively. The bonding area at connection interface between colloids and devices had delamination, even cracks. The delamination of ECAs was calculated about 60%, the average shear strength of ECAs was reduced about 45%, and those of FECAs were about 50% and 30%, respectively, so FECAs had a higher bonding stability in hot and humid environment. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of substituent groups at the 3‐position on the mass spectral fragmentation pathways of cephalosporins

The structural fragment ions of nine cephalosporins were studied by electrospray ionization quadrapole trap mass spectrometry (Q‐Trap MSⁿ) in positive mode. The influence of substituent groups in the 3‐position on fragmentation pathway B, an α‐cleavage between the C7? C8 single bond, coupled with a [2,4]‐trans‐Diels‐Alder cleavage simultaneously within the six‐membered heterocyclic ring, was also investigated. It was found that when the substituent groups were methyl, chloride, vinyl, or propenyl, fragmentations belonging to pathway B were detected; however, when the substituents were heteroatoms such as O, N, or S, pathway B fragmentation was not detected. This suggested that the [M–R₃]⁺ ion, which was produced by the bond cleavage within the substituent group at the 3‐position, had a key influence on fragmentation pathway B. This could be attributed to the strong electronegativity of the heteroatoms (O, N, S) that favors the production of the [M–R₃]⁺ ion. Moreover, having the positive charge of the [M–R₃]⁺ ion localized on the nitrogen atom in the 1‐position changed the electron density distribution of the heterocyclic structure, which prohibits a [2,4]‐reverse‐Diels‐Alder fragmentation and as a result fragmentation pathway B could not occur. The influence of the substituent group in the 3‐position was determined by the intensity ratio (e/d) of ions produced by fragmentation pathway A, a [2,2]‐trans‐Diels‐Alder cleavage within the quaternary lactam ring, including the breaking of the amide bond and the C6? C7 single bond (ion d), and fragmentation pathway B (ion e). The results indicate that the electronegativity of the substituent group was a key influencing factor of pathway B fragmentation intensity, because the intensity ratio (e/d) is higher for a chlorine atom, a vinyl, or a propenyl group than that of a methyl group. This study provided some theoretical basis for the identification of cephalosporin antibiotics and structural analysis of related substances in drugs. Copyright © 2010 John Wiley & Sons, Ltd.     

BZ反应的滴定量热研究

用滴定热量计考察丙二酸(以下简称MA)-溴酸钾-硝酸铈铵-硫酸振荡体系在不同反应物浓度下周期、诱导期、诱导期放热的变化情况. 发现反应物浓度与周期、诱导期的倒数之间存在着线性关系,并观测到溴酸钾与丙二酸的浓度固定在不同的值时,随着Ce4 浓度的逐渐变稀,振荡周期变短,从动力学理论角度对上述现象进行了分析.     

流动注射分光光度法间接测定利血生制剂中利血生的含量

提出了利血生的流动注射分光光度间接分析方法。以水作载液，可间接测定利血生的含量。测定的线性范围0．01－0．2mg/mL。回收率为100．0％－102．0％。     

Microcalorimetric Character of Inhibition of Salicylaldehyde Glucosamine Schiff Base SG on Bacterial Metabolism

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滑坡滑面(带)的辩识

在实验室无风条件下对马蹄波进行了实验研究. 得到了L2型的马蹄波,也发现了两种 新的类似马蹄波的波型,给出了马蹄波的横向波长和波高参数的几何特征,分析了马蹄波演 化的过程中波面时间历程和振幅谱特征,讨论了马蹄波产生的机理和条件.