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1.
Xinjiang Chen Goh Matsuo Bunsho Ohtani Kaoru Tsujii 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4891-4900
A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H2O2 is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H2O2 is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H2O2 is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007 相似文献
2.
R. Bairava Ganesh Hitoshi Matsuo Takahiro Kawamura Yoshihiro Kangawa Koji Arafune Yoshio Ohshita Masafumi Yamaguchi Koichi Kakimoto 《Journal of Crystal Growth》2008,310(11):2697-2701
Multicrystalline silicon was grown by unidirectional solidification method using the accelerated crucible rotation technique. The application of the accelerated crucible rotation technique in unidirectional solidification method induced growth striations across the axial direction of the grown crystal. This striation pattern was observed from carbon concentration distribution, obtained by using Fourier transform infrared spectroscopy. The generated striation pattern was found to be weak and discontinuous. Some striations were absent, probably due to back melting, caused during each crucible rotation. From the growth striations and applied time period in crucible rotation, the growth rate was estimated by using Fourier transformation analysis. 相似文献
3.
Cellulose derivative resin (CDR) suspensions containing resin particles of cellulose nitrate (CDR(CN)), cellulose acetate (CDR(CA)), or cellulose triacetate (CDR(CTA)) were prepared as the sorbent for resin suspension injection (RSI) electrothermal atomic absorption spectrometry (ETAAS), in which fine resin particles holding a desired trace element were directly injected into the graphite tube as the suspension. To compare the sorption ability, the distribution ratios of the Mo(VI)-phenylfluorone complex were measured between the aqueous phase and the sorbents, including the CDRs mentioned above and the finely divided anion exchange resin (AR). The results showed that the sorption ability decreases in the following order: CDR(CN) > or = AR > CDR(CA) > or = CDR(CTA). It was concluded that CDR(CN) was able to extract more than 98% of Mo(VI), and was suitable for RSI-ETAAS as well as AR. CDR(CN) was used for the determination of Mo in NIES certified reference materials, No. 10 Rice flour-unpolished; the results showed fairly good agreements between the analytical values and the certified values. 相似文献
4.
We develop a production policy that controls work-in-process (WIP) levels and satisfies demand in a multistage manufacturing system with significant uncertainty in yield, rework, and demand. The problem addressed in this paper is more general than those in the literature in three aspects: (i) multiple products are processed at multiple workstations, and the capacity of each workstation is limited and shared by multiple operations; (ii) the behavior of a production policy is investigated over an infinite-time horizon, and thus the system stability can be evaluated; (iii) the representation of yield and rework uncertainty is generalized. Generalizing both the system structure and the nature of uncertainty requires a new mathematical development in the theory of infinite-horizon stochastic dynamic programming. The theoretical contributions of this paper are the existence proofs of the optimal stationary control for a stochastic dynamic programming problem and the finite covariances of WIP and production levels under the general expression of uncertainty. We develop a simple and explicit sufficient condition that guarantees the existence of both the optimal stationary control and the system stability. We describe how a production policy can be constructed for the manufacturing system based on the propositions derived. 相似文献
5.
Hirohisa Yokota Kenji Kamoto Jun-ichi Igarashi Norihiko Mouri Yutaka Sasaki 《Optical Review》2002,9(1):9-12
A new configuration for an ASE reduction filter in EDFA repeaters for WDM optical transmission systems using optical fiber grating couplers (FGCs) was proposed and first demonstrated. The filtering characteristics of the proposed filter for amplified single wavelength signal and 2-channel WDM signals using EDFA were identified. It was found that the filter was effective to improve SNR in optical domain by reducing ASE noise. The required FGC characteristics for the filter were theoretically predicted under the condition that the total filter loss did not exceed 3 dB. More than 70% of drop efficiency was required in each FGC for the application of the proposed filter to an 8-channel WDM system using EDFA repeaters. 相似文献
6.
Yasumitsu Matsuo Takehiko Ijichi Hironori Yamada Junko Hatori Seiichiro Ikehata 《Central European Journal of Physics》2004,2(2):357-366
We have fabricated a field effect transistor (FET) based on an organic ferroelectric insulator and molecular conductor, and
investigated the electrical properties and memory effects on the PEN-FET. We have observed a drastic change in the drain current
at around the coercive electric fieldE
c
of the organic ferroelectric insulator in not only a FET (PEN-FET) based on a pentacene (PEN) film but also a FET (IPEN-FET)
based on an iodine doped PEN film. The magnitude of the change of the drain current for the IPEN-FET is 200 times larger than
that for the PEN-FET. It is expected from these results that the PEN-FET (especially the IPEN-FET) is an improvement in such
devices, since it operates at a low gate electric field accompanied by the appearance of the spontaneous polarization in the
organic ferroelectric insulator. In addition, we have found that the drain current for the PEN-FET does not return to the
initial drain current ofE
G
=0 V/cm for more than one week, even if the gate electric field is changed to 0 V/cm from 500 V/cm(>E
c
). From these results, it is suggested that the PEN-FET becomes a memory device. 相似文献
7.
Deependra Das Mulmi Nozomi Kamiya Yutaka Murakami 《Journal of Physics and Chemistry of Solids》2004,65(6):1181-1185
Nb-doped anatase TiO2 single crystal has been grown by chemical vapour transport method. Raman spectra shows that the obtained crystal with Nb of 0.08 wt% has typical anatase structure. An absorption band was observed at around 2.2 eV, which seems to be due to the d-d transition in the conduction band. The electron paramagnetic resonance and electric resistivity measurements show that the doped niobium makes quite shallow donor level whose orbital is dxy-like centered at the titanium position of anatase. 相似文献
8.
S. Juodkazis A.V. Rode E.G. Gamaly S. Matsuo H. Misawa 《Applied physics. B, Lasers and optics》2003,77(2-3):361-368
We report on three-dimensional (3D) optical memory recording and reading in glass by femtosecond pulses. Optically induced dielectric breakdown of glass is a mechanism of recording. The formulae of dielectric breakdown presented are applicable, in principle, for any crystalline or amorphous dielectric material. Scaling dependences of the probabilities of multi-photon and impact ionization are given. The measured threshold of an in-bulk dielectric breakdown of silica was reproduced numerically by implementing the ionization potential of Si (8.15 eV) for calculations. Exact measures of focal spot size and pulse duration at the focus allowed us to evaluate the intensity of a pulse during recording of 3D optical memory bits with high accuracy. The readout of the 3D optical memory was carried out by the white-light continuum generated from the previously damaged sites (recorded memory bits). The mechanism of the readout was a four-photon parametric interaction. PACS 42.65.Jx; 42.65.Ky; 42.70.Ce; 42.79.Vb 相似文献
9.
Takaaki Kakitsuka Shinji Matsuo Seok–Hwan Jeong Toru Segawa Hiroshi Okamoto Yoshihiro Kawaguchi Yasuhiro Kondo Yuzo Yoshikuni Hiroyuki Suzuki 《Optical and Quantum Electronics》2006,38(12-14):1053-1060
We theoretically investigated a digitally tunable laser with a chirped ladder filter and a ring resonator to obtain a wide wavelength tuning range covering the whole C- or L- band. The clear relation between the tuning range and laser structure, especially the ladder filter, is described analytically. The introduction of a chirped structure into a ladder filter is effective in achieving both wide tunability and a stable lasing mode. A numerical simulation based on multimode rate equations shows that a tuning range of over 40 nm and a mode suppression ratio over 40 dB can be achieved by introducing a chirped ladder filter. 相似文献
10.
N. Matsuo 《Zeitschrift fur Physik C Particles and Fields》1987,36(2):289-304
The thermodynamics of superstring theories (SST-I, SST-II and heterotic string theory) and its application to the cosmology are studied. The free energy of superstring gas is calculated in the one-loop approximation and the stability of the extra torus dimensions is discussed. Assuming that the Einstein equation dictates the evolution of the universe, we show that matter dominated universe filled with massive particles would never be realized at the beginning of the universe, contrary to the naive expectation in the superstring cosmology. 相似文献