Titanium carbonitride films on cemented carbide cutting tool prepared by pulsed high energy density plasma

Hard films prepared by pulsed high energy density plasma (PHEDP) are characterized by high film/substrate adhesive strength, and high wear resistance. Titanium carbonitride (TiCN) films were deposited onto YG11C (ISO G20) cemented carbide cutting tool substrates by PHEDP at room temperature. XRD, XPS, SEM, AES, etc. were adopted to analyze the phases (elements) composition, microstructure and the interface of the films, respectively. The results show that, the uniform dense films are composed of grains ranging from 70 to 90 nm. According to the AES result, there is a broad transition layer between the film and the substrate, due to the ion implantation effect of the PHEDP. The transition layer is favorable for the film/substrate adhesion.     

库仑滴定法测定有机硅样品中的氮含量

本文利用库仑滴定法研究了高分子和低分子硅氮化合物及含氮有机硅样品中氮含量的测定,并研究和讨论了影响测定结果准确性的因素。     

Hydroxyl radical formation upon dark oxidation of reduced iron minerals: Effects of iron species and environmental factors

Dark formation of hydroxyl radical upon oxidation of reduced iron minerals plays an important role in the degradation and transformation of organic and inorganic pollutants. Herein, we compared the hydroxyl radical formation from various reduced iron minerals at different redox conditions. OH production was generally observed from the oxidation of reduced iron minerals, following the order: mackinawite (FeS) > reduced nontronite (iron-bearing smectite clay) > pyrite (FeS₂) > siderite (FeCO₃). Structural Fe²⁺ and dissolved O₂ play critical roles in OH production from reduced iron minerals. OH production increases with decreasing pH, and Cl^? has little effect on this process. More importantly, dissolved organic matter significantly enhances OH production, especially under O₂ purging, highlighting the importance of this process in ambient environments. This sunlight-independent pathway in which OH forms during oxidation of reduced iron minerals is helpful for understanding the degradation and transformation of various inorganic and organic pollutants in the redox-fluctuation environments.     

中学物理中有关日光灯的几个问题

日光灯在学生的生活中有普遍的应用，因此，让学生了解日光灯的发明历史，研究如何在高中物理中引入一些与日光灯有关的教师演示或学生分组实验，对于学生了解更多贴近生活的物理知识非常有用．通常，在自感现象的内容之后教材常常都会介绍日光灯、日光灯管的构造及其工作原理，作为自感现象的一个生活实例．由于它的点亮过程几乎是在瞬间完成的，我们将这种过程称为暂态过程．     

Hemin-Promoted Direct C−H Thiolation in the Synthesis of Diaryl Sulfides

Diaryl sulfides are a class of important synthetic chemical units. Herein, we report a new method for direct preparation of diphenyl sulfides using P-toluenesulfonyl chloride as an effective thiophenyl radical precursor with assistance from Hemin. Various substituted anisoles and benzenesulfonyl chlorides are well tolerated, resulting in moderate to good yields of diaryl sulfides. The potential of the proposed method is validated by good yields obtained in gram scale reactions.     

Toxic effect of triphenyltin chloride on the alga Spirulina subsalsa

A previous study on the deleterious effect of triphenyltin chloride (TPTCl) on the alga Spirulina subsalsa reported on four physiological and biochemical indices (or parameters): growth rate, chlorophyll content, phycocyanin content and nitrate reductase activity. In the present study, further research was performed to confirm the findings reported in the previous paper, using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The SEM images show significant changes in the screw‐pitch of S. subsalsa, suggesting that TPTCl may damage the inheritance characteristics of S. subsalsa. The TEM images illustrate that the external pectin theca, limiting membrane and inter photosynthetically active lamella in the S. subsalsa cell are those targets that can be easily damaged. Reversible and irreversible cell damage (cell necrosis) are also observed. Copyright © 2002 John Wiley & Sons, Ltd.     

大白鼠抑郁症模型的MRI方法研究

用核磁共振成象方法研究对比了抑郁症大白鼠与对照组正常大白鼠脑部的核磁共振信号强度的差别.从大白鼠大脑的核磁共振图象出发,经过数据分析,发现抑郁症大白鼠多个脑组织的核磁共振信号相对强度普遍比正常大白鼠高.另外,模型组大白鼠大脑的脑裂比对照组大白鼠的脑裂更深且更宽.     

由因式化L算子所构成的经典可积动力学体系

用因式化的L算子构造了一类在非周期边界条件下的可积模型.对体系的transfer矩阵取三角和标度极限情况下,得到了n维体系(n为奇数)的经典哈密顿量的具体形式.结果表明,这类可积体系与Calogero等人所发现的一系列可积体系是相类似的.     

STUDIES ON HIGH SOLID CONTENT AND STABLEEMULSIFIER-FREE EMULSION POLYMERIZATION

1.INTRODUCTIONEmulsifier-freeemulsionpolymerizationhasrecentlyreceivedmoreandmoreattentionduetoitsacademicandpracticalinterest.Latexesofmono-disperseandcleanthatwithoUtremovablesurfactantcanbeobtained.Inaddition,materialsofhigheradhesionandwaterresistancecanbeprepared.Especially,itcanavoidfromenvironmentalpollution.UPtodate,emulsifier-freeemulsionpolymeriZationismainlypreparedbyintroducingionicinitiators,*.Towhomcorrespondenceshouldbeaddressedamphiphilicoligomers,hydrophilic,nonionicori…