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The formation and co-existence of crystallographically modulated and non-modulated regions in (Ba,Sr)2TiSi2O8 fresnoites is reviewed, particularly the dependence on local composition. It is shown that perturbations of the average fresnoite structure, determined from appreciable single crystals, are in some cases better described as nanometric domain intergrowths where departures from ideal stoichiometry are characteristics of incommensuration, while modulation is absent from volumes that are less perturbed chemically. Evidence for this differentiation is obtained from selected area electron diffraction (SAED) patterns and high-resolution transmission electron microscopy (HRTEM) images. The domains are readily distinguished by their unique contrast in bright field electron micrographs. Fourier reconstructions of HRTEM images collected from areas with darker contrast show that modulation can change within relatively small volumes. Nearby areas with lighter contrast were found by SAED to be free of structural disorder and incommensurate reflections. 相似文献
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Marcella Cadoni Giovanni Ferraris 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(11):i87-i90
The crystal structure of synthetic penkvilksite‐2O, disodium titanium tetrasilicate dihydrate, Na2TiSi4O11·2H2O, a microporous titanosilicate, confirms the major features of a previous model that had been obtained by order–disorder (OD) theory from the known structure of penkvilksite‐1M. An important difference from the previous model involves the hydrogen bonding of the water molecule which, on the basis of a Raman spectrum and the finding of only one of the two H atoms, is proposed to be disordered about a fixed O–H direction. The structure of penkvilksite‐2O is based on (100) silicate layers linked by isolated TiO6 octahedra to form a heteropolyhedral framework. The layer is strongly corrugated, based on interlaced spiral chains, and is crossed by two different channels that have an effective channel width of about 3 Å. 相似文献
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Tosi G Conti C Giorgini E Ferraris P Garavaglia MG Sabbatini S Staibano S Rubini C 《The Analyst》2010,135(12):3213-3219
Fourier transform infrared (FTIR) microspectroscopy has been employed to investigate benign (ordinary dermal and Reed nevi), dysplastic and malignant (invasive melanoma) skin lesions through the analysis of spectral changes of melanocytes as well as in the evaluation of the presence of melanin. Hierarchical cluster analysis and principal component analysis led to a satisfactory separation of malignant from dysplastic and normal melanocytes. Also, on enlarging the clustering with spectra from Reed and dermal nevi, the multivariate analysis segregated well the spectral data into discrete clusters, allowing the obtaining of reliable average spectra for analysis at the molecular level of the main groups or components responsible for the biological and biochemical changes. The most significant spectral characteristics appear to be related to differences in secondary protein structures, in nucleic acid conformation, in intra- and intermolecular bonding. In all cases, supervised and unsupervised spectral analyses resulted in satisfactory agreement with histopathological findings. 相似文献
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Giorgini E Conti C Ferraris P Sabbatini S Tosi G Rubini C Vaccari L Gioacchini G Carnevali O 《Analytical and bioanalytical chemistry》2010,398(7-8):3063-3072
The aim of this study was to verify the effects of probiotic Lactobacillus rhamnosus on zebrafish oocyte maturation using FPA (focal plane array) FTIR imaging together with specific biochemical assays (SDS-PAGE, real-time PCR and enzymatic assay). Oocyte growth is prevalently due to a vitellogenic process which consists of the hepatic synthesis of vitellogenin and its selective uptake during maturation. The administration of L. rhamnosus IMC 501 for 10 days induced chemical changes to oocyte composition, promoting the maturation process. Some interesting biochemical features, linked to protein secondary structure (amide I band) and to phospholipidic and glucidic patterns, were detailed by vibrational analysis. The spectroscopic results were supported by the early increase of the lysosomal enzyme involved in the final oocyte maturation, the cathepsin L. This enzyme increases during follicle maturation, with the highest levels in class IV oocytes. In treated females, class III oocytes showed higher cathepsin L gene expression and enzymatic activity, with levels comparable to class IV oocytes isolated from controls; this can be related to the proteolytic cleavage of the higher molecular mass yolk protein components, as evidenced by SDS-PAGE. 相似文献
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A new dialkylthio benzo[1,2-b:4,5-b']dithiophene (S-BDT) was designed and synthesized and the polymer S-PBDT was prepared by a Stille coupling reaction. A high open-circuit voltage (V(oc)) of up to 0.99 V was achieved in polymer solar cells with PCBM. 相似文献
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L. Fatibene M. Ferraris M. Francaviglia M. Godina 《General Relativity and Gravitation》1998,30(9):1371-1389
A new formulation for General Relativity is developed; it is a canonical, global and geometrically well posed formalism in which gravity is described using only variables related to spin structures. It does not require any background metric fixing and it applies to quite general manifolds, i.e. it does not need particular symmetries requirement or global frames. A global Lagrangian framework for Dirac spinors is also provided; conserved quantities and superpotentials are given. The interaction between gravity and spinors is described in a minimal coupling fashion with respect to the new variables and the Hilbert stress tensor of spinor fields is computed, providing the gravitational field generated by spinors. Finally differences and analogies between this formalism and gauge theories are discussed. 相似文献
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Summary We have studied the behaviour of photoacoustic response of implanted silicon samples in order to measure the thermal conductivity
of damaged layers; the results allow us to determine such a parameter simply by the phase difference measurement between implanted
and unimplanted regions of the sample.
Riassunto è stata studiata la risposta fotoacustica di campioni di silicio impiantato allo scopo di misurare la conducibilità termica degli strati danneggiati; i risultati permettono di determinare questa grandezza misurando semplicemente la differenza di fase tra la zona impiantata e quella cristallina del campione.
Резюме Исследуется поведение фотоакустического отклика на образцах имплантированного кремиия, чтобы измерить теплопроводность поврежденных слоев. Полученные результаты позволяют получить величину теплопроводности с помощью измерения разности фаз между имплантированной и неимплантированной областлми образца.相似文献
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