分子水平研究不同嵌段结构苯乙烯/丁二烯共聚物的表面结构

利用具有准单分子层灵敏度的和频振动光谱(SFG)、原子力显微镜(AFM)和接触角(CA)测定技术研究链结构和溶剂对苯乙烯(S)/丁二烯(B)嵌段共聚物表面准分子层化学结构形成的影响.结果表明,两嵌段共聚物SB比三嵌段共聚物SBS更有利于聚丁二烯(PB)组分在膜表面富集.利用PB的选择性溶剂环己烷做溶剂时,SB膜表面层完全由纯的PB组分组成,而SBS表面则是聚苯乙烯(PS)与PB二组分共存.利用PS的选择性溶剂甲苯做溶剂时,SB与SBS表面都是PS与PB二组分共存,其中SBS表面PS组分的含量更高.原因是由于溶剂影响嵌段共聚物分子在溶液中的构象从而影响溶剂挥发后聚合物表面结构的形成.     

“双减”背景下初中数学新课导入优化策略初探

在倡导减轻义务教育阶段学生课业负担和校外培训负担的政策支持下,学科教学的方方面面迎来了全新的变革,体现在课堂教学思路要清晰,课后作业设置要凝练,评价方式要精准,真正将课堂教学“减负增效”落到实处.新课导入作为一节数学课的起始环节,对揭示本节课的学习内容,指明探究方向具有引领作用.“双减”背景下新课导入的设计不仅仅是生活数学化的过程,而是要寓思想和方法于情境之中,强化整章内容的统领性,注重前后章节的连贯性,为本节课教学目标的高效达成奠定基础.为此,教师备课时应着眼于学情,精准定位;钻研教材,灵活整合;启发引导,多元参与.     

利用全息法在偶氮聚合物薄膜中记录涡旋光场

利用全息技术在偶氮聚合物薄膜中记录了拓扑荷数q=–1,1,2,4的涡旋光场,并将记录的原始叉形光栅与计算全息光栅进行对比,对不同拓扑荷数涡旋光的记录速率和偶氮材料的可重复擦写性能进行了测试;记录完成后,将复现涡旋光与高斯光束干涉,并与原始涡旋光和原始叉形光栅对比,分析了记录质量.实验结果表明:高阶涡旋光场的全息叉形光栅会在记录过程中发生劈裂,轻微劈裂的涡旋光束仍维持一个稳定的环状结构;全息记录过程中不同拓扑荷数的涡旋光束记录速率较为统一,偶氮材料可经过上百次的擦写而不出现疲劳;再现涡旋光与原始涡旋光在光强分布结构上保持高度一致,再现涡旋光的干涉条纹与原始涡旋全息光栅保持高度一致,涡旋光及其携带的拓扑荷信息可被有效记录和读取.     

Reconstruction of dynamic structures of experimental setups based on measurable experimental data only

Nowadays, massive amounts of data have been accumulated in various and wide fields, it has become today one of the central issues in interdisciplinary fields to analyze existing data and extract as much useful information as possible from data. It is often that the output data of systems are measurable while dynamic structures producing these data are hidden,and thus studies to reveal system structures by analyzing available data, i.e., reconstructions of systems become one of the most important tasks of information extractions. In the past, most of the works in this respect were based on theoretical analyses and numerical verifications. Direct analyses of experimental data are very rare. In physical science, most of the analyses of experimental setups were based on the first principles of physics laws, i.e., so-called top-down analyses. In this paper, we conducted an experiment of "Boer resonant instrument for forced vibration"(BRIFV) and inferred the dynamic structure of the experimental set purely from the analysis of the measurable experimental data, i.e., by applying the bottomup strategy. Dynamics of the experimental set is strongly nonlinear and chaotic, and it's subjects to inevitable noises. We proposed to use high-order correlation computations to treat nonlinear dynamics; use two-time correlations to treat noise effects. By applying these approaches, we have successfully reconstructed the structure of the experimental setup, and the dynamic system reconstructed with the measured data reproduces good experimental results in a wide range of parameters.