排序方式: 共有10条查询结果,搜索用时 15 毫秒
1
1.
在70-300K温度范围内测量了组分x为0.01和0.04的Cd1-xFexTe及CdTe的法拉第效应随入射光子能量的变化,首次获得了Cd1-xFexTe在布里渊区Γ点和L点的有效g因子及其与温度的关系。给出了Fe2+离子与载流子间的sp-d交换作用常数N0(β-α)=(-1.57±0.03)eV。 相似文献
2.
3.
Synthesis, Characterization and Magnetic Property Measurements of Zn1-xMnxO Nanoparticles via Vapour Phase Growth 下载免费PDF全文
Nanosized Mn-doped ZnO particles were synthesized using a vapour phase growth method. The x-ray analysis revea/s a wurtzite ZnO structure with small expansion of the lattice constants due to the doping of Mn in ZnO. The TEM analysis shows that the nanoparticles have an average diameter around 37 nm, and energy dispersive spectroscopy detection on single nanoparticle indicates that the manganese concentration is around 3.5at.%. Magnetization measurements under field cooling conditions reveal that the as-grown Mn-doped ZnO nanoparticles show paramagnetic behaviour. This work demonstrates that Mn can be doped into nanosized ZnO structures via vapour phase growth, which represents an important step towards the synthesis of nanosized diluted magnetic semiconductors. 相似文献
4.
A new sulfate inorganic framework, {(C2H8N)9[Nd5(SO4)12]·2H2O}n(1) templated by organic amine, has been solvothermally synthesized and characterized by TGA, PXRD and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group C2/c with a = 20.570(5), b = 35.815(8), c = 10.106(2) , C318H72N9Nd5O50S12, Mr = 2315.73, V = 6765(3) , Z = 4, Dc = 2.274 g·cm-3, μ = 4.253 mm-1, F(000) = 4520, 2.52θ25°, λ(MoKα) = 0.71073 , T = 273(2) K, the final R = 0.0401, wR = 0.1022 and S = 1.042. X-ray diffraction analysis reveals that complex 1 possesses a 3D inorganic sulfate framework with large 20-membered ring(20 MR) and 10-membered ring(10 MR) channels constructed by two kinds of SBUs. Moreover, the UV-vis and luminescent properties of complex 1 were also investigated. 相似文献
5.
开发高效、稳定的电催化剂是燃料电池走向实用的关键.为了解决催化剂因尺寸效应引起的催化活性和稳定性之间的矛盾,采用简便的一步溶剂热法设计合成了具有一维链状结构的Pt-Ni合金纳米颗粒催化剂.链状Pt-Ni纳米颗粒由平均尺寸约为10 nm的纳米颗粒和直径约为3 nm,长度为几百纳米的纳米线组装而成,该结构具有零维纳米颗粒高的比表面积和一维纳米线高的结构稳定性优势,可显著提高甲醇氧化反应的催化活性和稳定性,其质量活性和比活性分别是商业Pt/C纳米催化剂的5.7倍和7.6倍.经1000圈循环伏安测试后,该纳米材料仍保留91.2%的比活性,远高于商业Pt/C的4.4%.制备的一维链状结构很好地解决了纳米颗粒催化剂在反应中的团聚问题,为获得同时具有较高催化活性和稳定性的Pt基纳米催化剂提供了新的途径,有望实现大范围工业化应用. 相似文献
6.
Electric current-induced giant electroresistance in La_(0.36)Pr_(0.265)Ca_(0.375)MnO_3 thin films 下载免费PDF全文
The electroresistance(ER) of La_(0.36)Pr_(0.265)Ca_(0.375)MnO_3(LPCMO) epitaxial thin film was studied under various dc currents.The current effect was compared for the unpatterned film and patterned microbridge with a width of 50 μm.The value of ER in the unpatterned LPCMO film could reach 0.54 under a 1-mA current,which is much higher than ER under 1 mA for the patterned weak phase-separated La_(0.67)Ca_(0.33)MnO_3 and La_(0.85)Sr_(0.15)MnO_3 microbridges with 50-μm width.More interestingly,for the patterned LPCMO microbridge,the maximum of ER can reach 0.6 under a small current of 100 μ.A.The results were explained by considering the coexistence of ferromagnetic metallic phase with the charge-ordered phase,and the variation of the phase separation with electric current. 相似文献
7.
8.
9.
二维材料具有原子级光滑表面、纳米级厚度和超高的比表面积,是研究金属纳米颗粒与二维材料的界面相互作用,实时、原位观察金属纳米颗粒的表面原子迁移、结构演化和聚合等热力学行为的重要载体.设计和构筑金属纳米颗粒与二维材料异质结构界面,在原子尺度分析和表征界面结构,揭示材料结构和性能之间的相互关系,对于理解其相互作用和优化器件性能具有重要价值.本文总结了近年来金属纳米颗粒在二维材料表面成核、生长、结构演化及其表征的最新进展,分析了金属纳米颗粒对二维材料晶体结构、电子态、能带结构的影响,探讨了可能的界面应变、界面反应,及其对电学和光学等性质的调控,讨论了金属纳米颗粒对基于二维材料的场效应管器件和光电器件的性能提升策略.为从原子、电子层次揭示微结构、界面原子构型等影响金属纳米颗粒-二维材料异质结性能的物理机制,为金属-二维材料异质结构的研制及其在电子器件、光电器件、能源器件等领域的应用奠定了基础. 相似文献
10.
A three-dimensional(3D) barium complex with 1,3,5-benzenetricarboxylic acid(H3BTC), {[Ba1.5(BTC)(H2O)]·(H2O)}n(1), was synthesized in DMF/EtOH/H2 O mixed solution under solvothermal conditions, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric analyses, and photoluminescence measurement. In complex 1, the 2D I2O0 type inorganic layer is constructed by {Ba1O10} and {Ba2O9} polyhedra. Moreover, the solid-state fluorescence measurement reveals a fluorescence emission band at 465 nm under 344 nm excitation, assigned to a charge-transfer transition. 相似文献
1