极性介质中醋酸乙烯酯的辐照引发分散聚合

用钴 60γ射线引发醋酸乙烯酯的分散聚合 ,通过选择各种极性溶剂体系 ,确立了醋酸乙烯酯在极性介质中稳定的分散聚合体系 .对异丙醇 水体系 ,聚合物分子量随剂量率的降低、稳定剂含量的增加、单体浓度的增大、反应温度的升高以及醇水比的降低而增加 .运用XPS、元素分析等表征聚合物粒子 ,及通过辐射接枝理论的分析 ,可以判断稳定剂所起的稳定作用主要是以物理吸附为主     

IC卡及其应用

 当今世界信息技术的发展日新月异,一个以采集、开发、利用信息资源为特征的信息技术革命正席卷全球,信息技术已广泛地渗透到社会生活的各个领域:从电话卡到工资卡;从借书卡到售饭卡;从汽车加油卡到健康卡;从ＡＴＭ机到电子商务……无处不见ＩＣ卡的身影。什么是ＩＣ卡?它工作的基本原理是什么?安全性如何?有哪些具体应用?本文拟对此作些介绍。一、ＩＣ卡及其分类1.什么是ＩＣ卡ＩＣ卡即集成电路卡(ｉｎｔｅｇｒａｔｅｄｃｉｒｃｕｉｔｃａｒｄ)。它是将一个集成电路芯片镶嵌于塑料基片中,封装成卡片的形式。     

铷离子-铷原子混合阱飞行时间谱的拟合和仿真模拟

离子-原子混合阱是研究带电粒子-中性粒子低温反应的理想平台,直接甄别反应产物最准确的方法是带电粒子飞行时间谱,飞行时间谱峰的强度、位置(飞行时间)和宽度给出了相应带电粒子的强度和动能(温度)等信息.本文通过分析和模拟铷离子-原子混合阱中的飞行时间谱,获得了不同荷质比的离子绝对强度和温度等信息.具体说,首先使用Gumbel型极值分布函数飞行时间谱的谱峰,获得谱峰强度、位置和宽度等信息.然后对实验建模得到耦合的原子数和总带点离子的速率方程,用这些速率方程拟合实验数据,并结合实验测量到的绝对原子数,获得绝对的离子数强度.由此提供了一种标定探测器(本文使用的是微通道板)的方法.改变电离激光的波长和强度得到的标定因子是一致的,表明了这种方法的可靠性.此外,利用COMSOL Multiphysics模拟实验的飞行时间谱,仿真模拟结果表明离子动能大,谱峰宽度窄.本文对飞行时间谱的强度和宽度分析为冷原子光电离过程的离子-原子反应碰撞和带电粒子温度弛豫奠定了基础.     

Analytical solutions for a doubly driven two-level atom

We have deduced analytical solutions of an energy level diagram of the doubly driven/dressed atom for a two-level atom exposed to a strong near-resonant bichromatic laser field in a special case, i.e., the bichromatic field with frequencies ω1 and ω2, and Rabi frequencies ?1 and ?2, in which the first coupling field of ?1 acts on the bare atomic levels, and then the resulting singly dressed states are driven by the second coupling field of ?2, thus resulting in the doubly dressed atom.We have measured the probe absorption spectra of a doubly driven two-level atom. The system consists of 52S1/2, F= 2 and 5~2P_(3/2), F'= 3 states of ~(87)Rb atoms in a magneto-optical trap(MOT) as well as the cooling/trapping beams and an additional coupling field. As for the spectroscopic properties of the doubly driven two-level atom, theoretical analytical solutions are in general agreement with the experimental spectrum as a whole.     

基于冷里德堡原子电磁感应透明的微波电场测量

在磁光阱中利用冷原子温度低,多普勒展宽小的优势获得了窄线宽的里德堡电磁感应透明(EIT)谱峰,结合Autler-Townes分裂效应(EIT-AT分裂)分别测量了多个频率的微波电场强度.结果显示,EIT-AT分裂间距与微波电场强度呈很好的线性关系,EIT-AT分裂方法可测量的微波电场强度线性区的下限可达222μV/cm,这个下限比传统热原子蒸汽池中EIT-AT分裂线性区的下限5 mV/cm提高了大约22倍,这对极弱微波电场的绝对校准非常有帮助.我们进一步利用EIT共振处探测光透过率的变化测量微波电场强度,对应的最小测量值可以小于1μV/cm,相应的灵敏度可达到1μV·cm^-1.Hz^-1/2.这些结果展示了冷原子样品在微波电场测量及其绝对校准方面的优势.     

Theoretical Analysis of Ionic Autoionization Spectra of Lanthanum in the Energy Region of 90650—915—00cm^—1

Eigenquantum defects μα and transformation matrix Uiα of La are calculated from the first principles byrelativistic multichannel theory, and dipole matrix elements Dα are obtained by fitting the experimental spectra.With these parameters, ionic autoionization spectra of lanthanum via an intermediatestate (Xe)5d6d^-1 P1 of La . in the energy region of 90650-91500 cm^-1 are calculated within the framework of multichannel auantum defecttheory. Our calculated spectra are in general agreement with the experimental data.     

An all-optical phase detector by amplitude modulation of the local field in a Rydberg atom-based mixer

Recently, a Rydberg atom-based mixer was developed to measure the phase of a radio frequency (RF) field. The phase of the signal RF (SIG RF) field is down-converted directly to the phase of a beat signal created by the presence of a local RF (LO RF) field. In this study, we propose that the Rydberg atom-based mixer can be converted to an all-optical phase detector by amplitude modulation (AM) of the LO RF field; that is, the phase of the SIG RF field is related to both the amplitude and phase of the beat signal. When the AM frequency of the LO RF field is the same as the frequency of the beat signal, the beat signal will further interfere with the AM of the LO RF field inside the atom, and then the amplitude of the beat signal is related to the phase of the SIG RF field. The amplitude of the beat signal and the phase of the SIG RF field show a linear relationship within the range of 0 to π/2 when the phase of the AM is set with a difference π/4 from the phase of the LO RF field. The minimum phase resolution can be as small as 0.6° by optimizing the experimental conditions according to a simple theoretical model. This study will expand and contribute to the development of RF measurement devices based on Rydberg atoms.     

钪原子的自电离里德伯能级3d4s(~1D_2)nf~2D_(3/2),3d4s(~1D_2)nf~2F_(5/2)和3d4s(~1D_2)np~2D_(3/2)的理论研究

在多通道量子亏损理论框架下,利用相对论多通道理论,分别在冻结实近似和考虑偶极极化下计算钪原子的Jπ=(3/2)-,(5/2)-的三个收敛于[Ar]3d4s(1D2)的自电离里德伯系列的能级.对3d4s(1D2)np2D3/2和3d4s(1D2)nf2F5/2这两个系列,计算结果表明,考虑偶极极化效应后,理论计算和实验测量的量子数亏损之差普遍小于0.01.而对3d4s(1D2)nf2D3/2系列,考虑偶极极化效应后的结果和仅考虑冻结实的结果比较接近,理论计算和实验测量的量子数亏损之差普遍在0.04左右.     

Ultra-High Efficiency Magnetic Transport of SZRb Atoms in a Single Chamber Bose-Einstein Condensation Apparatus

We report the ultra-high efficiency transport of cold ST Ftb atoms using a moving magnetic quadrupole potential generated by three overlapping pairs of fixed coils. The transfer etticiency is better than 97%, which is the highest ever reported to our knowledge. The temperature increase due to heating is less than IO #K when the initial cloud temperature is llO#K. Our setup is similar to the magnetic transferring belt design [Phys. ftev. A 63 （2001）031401（R）], although it is simpler because the push coil is not required. We use it to transport atoms away from a magneto-optical trap to very close to the wall of the glass cell, facilitating future experiments employing three-dimensional optical lattices, high resolution in-situ imaging, and magnetic Feshbach resonances.     

铥原子收敛于4f~(13)(~2F~?_(7/2))6s(7/2,1/2)~?_4和4f~(13)(~2F~?7/2)6s(7/2,1/2)~?_3偶宇称里德伯系列能级的电子关联效应

本文在多通道量子亏损理论框架下,利用相对论多通道理论,计算了铥原子收敛于4f~(13)(~2F?_(7/2))6s(7/2,1/2)?_4和4f~(13)(~2F?7/2)6s(7/2,1/2)?_3的三个偶宇称里德伯系列.通过将计算结果与美国国家标准与技术研究院数据进行比较,展示了两种类型的电子关联效应:1)里德伯系列之间的相互作用,导致里德伯系列的能级出现整体偏移; 2)一个孤立的干扰态镶嵌在一个里德伯系列中,破坏了该里德伯系列能级的规则性.