A high performance HfSiON/TaN NMOSFET fabricated using a gate-last process

A gate-last process for fabricating HfSiON/TaN n-channel metal-oxide-semiconductor-field-effect transistors(NMOSFETs)is presented.In the process,a HfSiON gate dielectric with an equivalent oxide thickness of 10 A was prepared by a simple physical vapor deposition method.Poly-Si was deposited on the HfSiON gate dielectric as a dummy gate.After the source/drain formation,the poly-Si dummy gate was removed by tetramethylammonium hydroxide(TMAH)wet-etching and replaced by a TaN metal gate.Because the metal gate was formed after the ion-implant doping activation process,the effects of the high temperature process on the metal gate were avoided.The fabricated device exhibits good electrical characteristics,including good driving ability and excellent sub-threshold characteristics.The device’s gate length is 73 nm,the driving current is 117μA/μm under power supply voltages of VGS=VDS=1.5 V and the off-state current is only 4.4 nA/μm.The lower effective work function of TaN on HfSiON gives the device a suitable threshold voltage(~0.24 V)for high performance NMOSFETs.The device’s excellent performance indicates that this novel gate-last process is practical for fabricating high performance MOSFETs.     

Improved performance of MoS2 FET by in situ NH3 doping in ALD Al2O3 dielectric

Since defects such as traps and oxygen vacancies exist in dielectrics, it is difficult to fabricate a high-performance MoS$_{2}$ field-effect transistor (FET) using atomic layer deposition (ALD) Al$_{2}$O$_{3}$ as the gate dielectric layer. In this paper, NH$_{3}$ in situ doping, a process treatment approach during ALD growth of Al$_{2}$O$_{3}$, is used to decrease these defects for better device characteristics. MoS$_{2}$ FET has been well fabricated with this technique and the effect of different NH$_{3}$ in situ doping sequences in the growth cycle has been investigated in detail. Compared with counterparts, those devices with NH$_{3}$ in situ doping demonstrate obvious performance enhancements: $I_{\rm on}/I_{\rm off}$ is improved by one order of magnitude, from $1.33\times 10^{5}$ to $3.56\times 10^{6}$, the threshold voltage shifts from $-0.74 $ V to $-0.12$ V and a small subthreshold swing of 105 mV/dec is achieved. The improved MoS$_{2}$ FET performance is attributed to nitrogen doping by the introduction of NH$_{3}$ during the Al$_{2}$O$_{3}$ ALD growth process, which leads to a reduction in the surface roughness of the dielectric layer and the repair of oxygen vacancies in the Al$_{2}$O$_{3}$ layer. Furthermore, the MoS$_{2}$ FET processed by in situ NH$_{3}$ doping after the Al and O precursor filling cycles demonstrates the best performance; this may be because the final NH$_{3}$ doping after film growth restores more oxygen vacancies to screen more charge scattering in the MoS$_{2}$ channel. The reported method provides a promising way to reduce charge scattering in carrier transport for high-performance MoS$_{2 }$ devices.