脉冲压缩光栅光路调节新方法研究

介绍了一种简单而实用的大口径脉冲压缩光栅光路调节方法,有效解决了普通光路调节方法中轴向调节精度不高的问题。首先由全息透镜(光栅)成像公式出发,推导出了该光路调节的基本原理。并从光栅记录系统与光栅衍射波像差的关系,结合初级像差理论推导得出叠栅条纹像差为0.4786λ,大约是光栅衍射波像差(0.25λ)的两倍,利用此关系也可对光栅衍射波像差进行实时监测。从数值模拟结果可知,利用叠栅条纹法调节光路可将光栅波像差减至0.06λ,相应的轴向误差量为0.007 mm,可有效提高了轴向调节精度。     

数字全息中再现像分离问题的研究

详细分析了数字全息的再现像分离条件,指出数字全息和普通全息的再现像分离条件之间的区别,同时也讨论了再现条件对数字全息记录光路的要求,同时给出一种能部分避免再现像重叠的处理方法,并做出相应的实验验证.     

10瓦级双包层光纤激光器

考虑到所用大功率激光二极管的光谱特性，对光纤激光器的基本法布里-珀罗腔型稍加改变，研制出激光二极管抽运的10w级双包层光纤激光器，获得最高功率为11．8w、波长1100mm的单模激光输出。     

不同环境蔬菜中铅污染的研究

用原子吸收分光光度计石墨炉法分析了公路附近的蔬菜中铅的含量。结果表明,蔬菜中铅的含量还与其距离公路的远近有关,蔬菜与空气接触程度也有关;不同种类蔬菜中的铅污染有差异。     

Synthesis and properties of tadpole-shaped gold nanoparticles

In this communication, gold nanoparticles with a tadpole shape were synthesized by a simple aqueous-phase chemical method. The unusual three-dimensional and crystallized structures were demonstrated by TEM, AFM, and HRTEM methods. The SEM and UV-visible absorption measurements and electrophoresis experiments revealed that the tadpoles had novel optical and electrical properties. These attractive structures and properties are expected to find uses in many fields such as electrics, optics, electrochemistry, and biological sensing.     

超大孔磷酸铝分子筛的合成及性能

1988年Davis等首次报道了以二正丙胺和四丁基氢氧化铵为结构导向剂合成出一种命名为VPI-5的新型磷酸铝超大孔分子筛。它是一族具有相同三维拓朴学骨架的磷酸铝系分子筛,该结构的对称性属六方晶系,P6_3cm空间群,单位晶胞由36个TO_2组成,晶胞参数α=1.8989nm,c=0.8112nm,其主孔道由18员环构成,孔直径约为1.2-1.3nm。     

Study on the anodic reaction of Ni in an alkaline solution by transient pH detection based on scanning electrochemical microscopy (SECM)

The anodic reaction of Ni in an alkaline solution was studied by the tip–substrate voltammetry mode of scanning electrochemical microscopy (SECM) and cyclic voltammetry (CV). A platinum microdisc electrode was selected as the tip electrode, which functioned as a pH sensor with transient response capability. The pH value of the solution near the Ni electrode surface varied while the Ni substrate oxidation reaction occurred, and the pH variation could be detected by the tip faradic current. The cyclic voltammogram results showed that two types of hydroxides: i.e. α‐Ni(OH)₂ and β‐Ni(OH)₂ were formed during Ni oxidation in the lower potential region. In the proceedings of α‐Ni(OH)₂ → γ‐NiOOH and β‐Ni(OH)₂ → β‐NiOOH, the process of OH^? concentration decrease in the solution was ahead and behind of electron transfer in the solid phase, respectively. These results indicate that the OH^? adsorption process occurs as an elementary step in the former reaction and the H⁺ diffusion process from the inner to the outer layer of the solid phase occurs as a subsequent step in the latter reaction. The results also revealed that the oxide film on the Ni surface has a two‐layer structure. The real potential of the oxygen evolution reaction (OER) on the Ni surface with different cycles is also analyzed in the paper. Copyright © 2007 John Wiley & Sons, Ltd.     

溴代及胺交联聚苯醚（PPO）膜的气体透过行为

对聚苯醚(PPO)进行了苯环溴代、甲基溴代以及胺交联,发现苯环溴代可提高O_2、N_2透过率(P),而选择性(α)基本不变。甲基溴代则相反,P降低、α有明显提高。调节两者比例可得到P、α兼优的O_2、N_2分离膜。甲基溴代后进一步胺交联可得到α更高、耐溶剂的膜材料。     

甲氧羰基亚甲基三苯基胂与邻羟基芳醛,酮的反应-5,6-苯并-2-吡喃酮的合成

本文报道一种合成烃基取代5,6-苯并-2-吡喃酮的方法。甲氧羰基亚甲基三苯基胂与烃基取代的邻羟基芳醛、酮反应,首先生成α,β-不饱和酸酯,继而发生分子内环化,生成烃基取代的5,6-苯并-2-吡喃酮。     

Synthesis and modification of terrylenediimides as high-performance fluorescent dyes

Two new synthetic approaches to terrylenediimides, highly photostable fluorescent dyes, are described. For the first time terrylenediimide has been synthesised in a straightforward procedure that makes large quantities available. The second route includes an efficient cross-coupling reaction followed by a cyclodehydrogenation. Monofunctionalisation of the imide structure allows terrylenediimides now to be coupled with a variety of compounds, for example, by Suzuki cross-coupling, which can lead to an array of terrylenediimides with new functional groups such as hydroxy, amino, or carboxy groups needed to link up with other molecules. The functionalisation in the bay region is used to tune the properties of terrylenediimides and extend the range of applications, for example, by introducing water solubility. These tetrasubstituted terrylenediimides offer, depending on the substituents used, exciting features such as good solubility in common organic solvents, water solubility, or NIR absorption.